DISENTANGLED ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE GRAFT CO-POLYMERS AND A PROCESS FOR PREPARATION THEREOF
    4.
    发明申请
    DISENTANGLED ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE GRAFT CO-POLYMERS AND A PROCESS FOR PREPARATION THEREOF 有权
    分散超高分子量聚乙烯共聚物聚合物及其制备方法

    公开(公告)号:US20150240017A1

    公开(公告)日:2015-08-27

    申请号:US14427263

    申请日:2013-09-10

    CPC classification number: C08F255/10 C08F255/02 C08F255/08 C08F10/02 C08F2/36

    Abstract: In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117° C. to 121° C. and improved decomposition temperature (T100) that ranges between 460° C. to 480° C.

    Abstract translation: 根据本公开内容,提供了一种用于制备解缠结的超高分子量聚乙烯接枝共聚物的固态接枝共聚方法,其中将解开的超高分子量聚乙烯与至少一种官能单体和自由基引发剂混合以获得 混合物; 将由此获得的混合物进行固态聚合,得到解开的超高分子量聚乙烯的接枝共聚物。 分离的超高分子量聚乙烯的接枝共聚物显示出在117℃至121℃之间更好的结晶温度和在460℃至480℃之间改进的分解温度(T100)。

    Immobilization of single site catalyst on inorganic oxide support for preparation of UHMWPE
    8.
    发明授权
    Immobilization of single site catalyst on inorganic oxide support for preparation of UHMWPE 有权
    固定单位催化剂对无机氧化物载体的制备UHMWPE

    公开(公告)号:US09260538B2

    公开(公告)日:2016-02-16

    申请号:US14376554

    申请日:2013-01-08

    Abstract: There is provided a chemically immobilized heterogeneous single site polymerization catalyst represented by Formula I. wherein, M is a Group IV transition metal; R1 is or a functionalized inorganic oxide support selected from the group consisting of such that R8 is a molecule having a carboxylic or sulphonic acid group; R2-R5, are independently, H or a hydrocarbon; R6 is t-butyl; R7 is a functionalized inorganic oxide support selected from the group consisting of such that R8 is a molecule having a carboxylic or sulphonic acid group; and X1 and X2 are independently F, Cl, Br or I. There is also provided a method for the preparation of the chemically immobilized heterogeneous single site polymerization catalyst as represented by Formula I.

    Abstract translation: 提供由式I表示的化学固定的异质单位聚合催化剂,其中M是IV族过渡金属; R1是选自由以下组成的组的官能化无机氧化物载体:R8是具有羧酸或磺酸基团的分子; R2-R5独立地为H或烃; R6是叔丁基; R7是选自由以下组成的组的官能化无机氧化物载体:R8是具有羧酸或磺酸基团的分子; X1和X2独立地为F,Cl,Br或I.还提供了制备式I表示的化学固定的异质单位聚合催化剂的方法。

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