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1.发明授权公开(公告)号：US06268075B1
公开(公告)日：2001-07-31
申请号：US09212289
申请日：1998-12-16
IPC分类号： C01B302
CPC分类号： H01M8/0631 , B60L11/1885 , B60L2240/36 , C01B3/323 , C01B3/384 , C01B3/501 , C01B2203/0405 , C01B2203/047 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , H01M8/0612 , H01M2250/20 , Y02P20/128 , Y02T90/32 , Y02T90/34
摘要： The invention relates to a process for operating a system for the water vapor reforming of a hydrocarbon, having an evaporator, a reforming reactor, a membrane module connected behind, and a catalytic burner device. According to the invention, a first part of the catalytic burner device is in thermal contact with the reforming reactor, and a second part of the burner device is in thermal contact with the evaporator. According to the process, a heating operation is carried out during the cold start of the system, in which, in a first operating phase, at least the evaporator and the reforming reactor are heated by the catalytic burner device, and in a second operating phase, a hydrocarbon/water vapor mixture is prepared in the evaporator at a water/hydrocarbon ratio which is higher than in the normal operation and is fed to the reactor, the substance mixture emerging from the reactor being fed by way of the membrane module to the catalytic burner device.
摘要翻译： 本发明涉及一种用于操作具有蒸发器，重整反应器，后面连接的膜组件和催化燃烧器装置的烃的水汽重整系统的方法。 根据本发明，催化燃烧器装置的第一部分与重整反应器热接触，并且燃烧器装置的第二部分与蒸发器热接触。 根据该过程，在系统的冷启动期间进行加热操作，其中在第一操作阶段中，至少蒸发器和重整反应器由催化燃烧器装置加热，并且在第二操作阶段 在蒸发器中以比正常操作高的水/烃比制备烃/水蒸气混合物并将其进料到反应器中，从反应器中排出的物质混合物通过膜组件进料至 催化燃烧装置。
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2.发明授权公开(公告)号：US06231831B1
公开(公告)日：2001-05-15
申请号：US09210894
申请日：1998-12-16
IPC分类号： B01D5322
CPC分类号： H01M8/0631 , B01B1/005 , B01J8/009 , B01J8/0285 , B01J19/2475 , B01J2208/00309 , B01J2208/00327 , B01J2208/00504 , B01J2208/00716 , C01B3/323 , C01B3/384 , C01B3/386 , C01B3/501 , C01B2203/0233 , C01B2203/0261 , C01B2203/041 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/085 , C01B2203/0866 , C01B2203/1223 , C01B2203/1276 , C01B2203/1288 , C01B2203/1604 , H01M8/04007 , H01M8/0612 , H01M2250/20 , Y02P20/128 , Y02T90/32
摘要： A membrane for separating hydrogen from a gas mixture is provided on at least one side with a catalyst layer for a specific catalytic combustion process. A methanol reformation system so equipped can be brought rapidly to operating temperature, with the hydrogen-separating membrane being heated directly by performing the catalytic combustion process.
摘要翻译： 在至少一侧上提供用于从气体混合物中分离氢的膜，其具有用于特定催化燃烧过程的催化剂层。 通过进行催化燃烧过程，直接加热氢分离膜，可迅速将甲醇改性体系快速地运行到工作温度。
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公开(公告)号：US6086839A
公开(公告)日：2000-07-11
申请号：US206380
申请日：1998-12-07
申请人： Rainer Autenrieth , Stefan Boneberg , Dietmar Heil , Martin Schuessler , Barbara Strobel , Steffen Wieland , Detlef zur Megede
发明人： Rainer Autenrieth , Stefan Boneberg , Dietmar Heil , Martin Schuessler , Barbara Strobel , Steffen Wieland , Detlef zur Megede
CPC分类号： H01M8/0631 , B01B1/005 , C01B3/382 , C01B3/48 , C01B3/583 , H01M8/0612 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0838 , C01B2203/0844 , C01B2203/0866 , C01B2203/1223 , C01B2203/1288 , C01B2203/143 , C01B2203/1604 , C01B2203/1685 , C01B2203/169 , C01B2203/82 , Y02P20/128
摘要： A system for the water vapor reforming of a hydrocarbon includes an evaporator, a prereforming unit, a main reformer, a CO removal unit and at least one catalytic burner unit. A first burner unit is in a thermal contact with the evaporator and a second burner unit is in a thermal contact with the main reformer, and the prereforming unit is in a thermal contact with the CO removal unit by way of one heat conducting separating medium. In addition, the outlet of the CO removal unit is connected with the inlet of the at least one burner unit. During a cold start, a heating-up operation is carried out during which first the two burner units are activated with an external feeding of hydrogen or hydrocarbon, and the reforming operation is started with a hydrocarbon fraction that is lower than in the normal operation. The resulting reformate gas, instead of the externally fed hydrogen or hydrocarbon, is introduced as fuel into the burner units.
摘要翻译： 用于烃的水蒸气重整的系统包括蒸发器，预成型单元，主重整器，CO去除单元和至少一个催化燃烧器单元。 第一燃烧器单元与蒸发器热接触，并且第二燃烧器单元与主重整器热接触，并且预成形单元通过一个导热分离介质与CO去除单元热接触。 此外，CO去除单元的出口与至少一个燃烧器单元的入口连接。 在冷启动期间，进行加热操作，其中首先通过外部进料氢气或烃来激活两个燃烧器单元，并且重整操作以低于正常操作的烃馏分开始。 所得到的重整气体代替外部供给的氢气或烃，作为燃料引入燃烧器单元。
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公开(公告)号：US06447736B1
公开(公告)日：2002-09-10
申请号：US09206379
申请日：1998-12-07
申请人： Rainer Autenrieth , Stefan Boneberg , Andreas Christen , Dietmar Heil , Barbara Strobel , Steffen Wieland , Detlef zur Megede
发明人： Rainer Autenrieth , Stefan Boneberg , Andreas Christen , Dietmar Heil , Barbara Strobel , Steffen Wieland , Detlef zur Megede
IPC分类号： B01J800
CPC分类号： H01M8/0631 , B01B1/005 , B01J19/249 , B01J2219/0002 , B01J2219/2453 , B01J2219/2462 , B01J2219/2492 , C01B3/323 , C01B3/382 , C01B3/48 , C01B3/583 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0838 , C01B2203/0844 , C01B2203/0866 , C01B2203/1223 , C01B2203/1288 , C01B2203/143 , C01B2203/1604 , C01B2203/82
摘要： A system for the water vapor reforming of a hydrocarbon includes a modular reactor unit of the plate stack and/or tube bundle type that, in an integrated manner, contains an evaporator, a prereforming unit, a main reformer, a CO removal unit and a catalytic burner unit. The evaporator and the main reformer are in a thermal contact with the catalytic burner unit and, the prereforming unit is in a thermal contact with the CO removal unit.
摘要翻译： 用于烃的水蒸气重整的系统包括板堆叠和/或管束型的模块化反应器单元，其以整体方式包含蒸发器，预成型单元，主重整器，CO去除单元和 催化燃烧器单元。 蒸发器和主重整器与催化燃烧器单元热接触，并且预成型单元与CO去除单元热接触。
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5.发明授权Process for operating a water vapor reforming system, a reforming system operable thereby and a fuel cell system operating process 有权用于操作水蒸气重整系统的方法，可操作的重整系统和燃料电池系统操作过程公开(公告)号：US06294149B1
公开(公告)日：2001-09-25
申请号：US09212290
申请日：1998-12-16
IPC分类号： C01B302
CPC分类号： H01M8/0631 , B01B1/005 , B01J8/009 , B01J2208/00327 , B01J2208/00504 , C01B3/323 , C01B3/384 , C01B3/386 , C01B3/501 , C01B2203/0233 , C01B2203/0261 , C01B2203/0405 , C01B2203/041 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/085 , C01B2203/0866 , C01B2203/1223 , C01B2203/1276 , C01B2203/1288 , C01B2203/1604 , H01M8/04007 , H01M8/0612 , H01M2250/20 , Y02P20/128 , Y02T90/32
摘要： The invention relates to a process for operating a system for the water vapor reforming of a hydrocarbon. The system includes a reactor which is suitable for POX operation as well as for a reforming operation, an evaporator, a hydrogen separating stage, and a catalytic burner device. A first part of the catalytic burner device is in thermal contact with the reforming reactor, and a second part of the burner device is in thermal contact with the evaporator. An air/hydrocarbon intermediate feeding pipe for the reactor and a pressure maintaining valve are provided for changing the reactor between the POX operation and the reforming operation. According to the process, during cold start of the system, a heating operation is carried out during which the reactor is first used in the POX operation at a lower pressure and subsequently is used for the reforming operation and simultaneously the pressure is increased to the normal operating pressure. The invention is particularly useful for the water vapor reforming of methanol for obtaining hydrogen for a fuel-cell-operated motor vehicle.
摘要翻译： 本发明涉及一种操作烃类水汽重整系统的方法。 该系统包括适用于POX操作以及重整操作的反应器，蒸发器，氢分离级和催化燃烧器装置。 催化燃烧器装置的第一部分与重整反应器热接触，并且燃烧器装置的第二部分与蒸发器热接触。 提供了用于反应器的空气/烃中间进料管和保压阀，用于在POX操作和重整操作之间改变反应器。 根据该方法，在系统的冷启动期间，进行加压操作，在该加热操作期间，在较低压力下POX操作中首先使用反应器，随后用于重整操作，同时将压力提高到正常 运营压力。 本发明对于用于获得用于燃料电池操作的机动车辆的氢的甲醇的水蒸汽重整特别有用。
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公开(公告)号：US06423435B1
公开(公告)日：2002-07-23
申请号：US09517527
申请日：2000-03-02
IPC分类号： H01M804
CPC分类号： C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0844 , C01B2203/0883 , C01B2203/1247 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/147 , C01B2203/148 , C01B2203/16 , C01B2203/82 , H01M8/04029 , H01M8/04097 , H01M8/04156 , H01M8/0612 , H01M8/0662 , H01M2300/0082
摘要： A fuel cell system has at least one fuel cell and a hydrogen generating arrangement for feeding the fuel cell anode with a hydrogen-containing product gas from a conversion reaction of a hydrocarbon starting substance or hydrocarbon derivative with of water fed supplied by way of a water feeding system. Water recovery devices are provided for condensing water out of the process gas supplied by the hydrogen generating arrangement, and/or out of the cathode waste gas carried away from the fuel cell cathode, and returning the condensed-out water into the water feeding system.
摘要翻译： 燃料电池系统具有至少一个燃料电池和氢生成装置，用于从烃起始物质或烃衍生物与通过水供给的水的转化反应将含有氢的产物气体供给燃料电池阳极 喂养系统。 提供水回收装置，用于将由氢气发生装置供应的工艺气体中的水和/或从燃料电池阴极携带的阴极废气中的水冷凝，并将冷凝的水返回给水系统。
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公开(公告)号：US5922291A
公开(公告)日：1999-07-13
申请号：US873772
申请日：1997-06-12
IPC分类号： B01J8/00 , B01J8/02 , C01B3/32 , H01M8/0612
CPC分类号： H01M8/0631 , B01J8/006 , B01J8/0085 , B01J8/02 , C01B3/323 , B01J2208/00495 , B01J2219/182
摘要： A reforming reactor system for water vapor reforming of methanol in fuel-cell operated motor vehicles has a reactor unit with a catalyst-filled reaction space and a particle filter which is arranged in a reformate gas pipe downstream of the reactor unit. The catalyst material is carried in the reaction space by a sieve below which a metallic nonwoven for catching sieved-out fragments and dust particles of the catalyst fill is situated. The particle filter contains a spun steel wool netting and/or several filter steps serially connected behind one another. The particle filter may be arranged to be exchangeable without interrupting the operation of the system. Specifically, a particle filter which has a filter body which can be changed in a gas-tight manner transversely to the gas flow and/or a cyclone filter can be used which has a closing device for the purpose of an emptying of a particle collecting pot which does not interrupt the operation.
摘要翻译： 用于在燃料电池操作的机动车辆中进行甲醇水汽重整的重整反应器系统具有反应器单元，其具有填充有催化剂的反应空间和颗粒过滤器，其被布置在反应器单元下游的重整气体管道中。 催化剂材料通过一个筛子在反应空间中载置，在该筛下方，放置用于捕获筛分碎片的金属非织造物和催化剂填充物的粉尘颗粒。 颗粒过滤器包含纺丝钢丝网和/或彼此串联连接的几个过滤器步骤。 颗粒过滤器可以被布置为可以交换而不中断系统的操作。 具体而言，可以使用具有能够以气密方式与气流横向变化的过滤体的粒子过滤器和/或旋风过滤器，其具有用于排空颗粒收集罐的关闭装置 这不会中断操作。
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8.发明授权
公开(公告)号：US5935277A
公开(公告)日：1999-08-10
申请号：US876390
申请日：1997-06-16
申请人： Rainer Autenrieth , Dietmar Heil , Wolfgang Weger , Uwe Benz
发明人： Rainer Autenrieth , Dietmar Heil , Wolfgang Weger , Uwe Benz
IPC分类号： B01J8/00 , B01J8/06 , C01B3/32 , C01B3/38 , H01M8/0612
CPC分类号： H01M8/0631 , B01J8/002 , B01J8/008 , B01J8/06 , C01B3/323 , C01B3/38 , B01J2208/00132 , B01J2208/0069 , B01J2208/00884 , C01B2203/0233 , C01B2203/066 , C01B2203/0833 , C01B2203/1011 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223
摘要： In a reforming reactor suitable particularly for the water vapor reforming of methanol in mobile applications such as vehicles, a reaction space is filled with a catalyst pellet fill and has a movable reaction space wall which exerts a position-fixing pressure onto the catalyst pellet fill. According to the invention, a filling device is provided through which catalyst material can be filled from the outside into the reaction space through a passage opening formed in one of the reaction space walls.
摘要翻译： 在适用于诸如车辆的移动应用中特别适用于甲醇的水汽重整的重整反应器中，反应空间填充有催化剂颗粒填充物，并且具有向催化剂颗粒填充物施加位置固定压力的可移动的反应空间壁。 根据本发明，提供一种填充装置，催化剂材料可以通过该填充装置通过形成在反应空间壁之一中的通道开口从外部填充到反应空间中。
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公开(公告)号：US06264856B1
公开(公告)日：2001-07-24
申请号：US09475275
申请日：1999-12-30
IPC分类号： C01B302
CPC分类号： H01M8/0631 , B01J8/0285 , B01J8/067 , B01J2208/00132 , C01B3/323 , C01B3/38
摘要： A reforming reactor, particularly for the water vapor reforming of methanol, with three serially arranged reactor steps, each of which is charged with a catalyst pellet fill. According to the invention, the center reactor step is maintained at a temperature which is suitable for the reforming reaction, while the two other reactor steps remain unheated. The present invention may be used as a reforming reactor for the water vapor reforming of methanol for the purpose of producing hydrogen in a fuel-cell operated motor vehicle.
摘要翻译： 一种重整反应器，特别是用于甲醇的水蒸气重整，具有三个连续排列的反应器步骤，每个反应器装有催化剂颗粒填料。 根据本发明，中心反应器步骤保持在适于重整反应的温度，而另外两个反应器步骤保持不加热。 本发明可以用作用于在燃料电池操作的机动车辆中产生氢气的甲醇的水蒸气重整的重整反应器。
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公开(公告)号：US6090499A
公开(公告)日：2000-07-18
申请号：US64762
申请日：1998-04-23
申请人： Rainer Autenrieth , Dietmar Heil
发明人： Rainer Autenrieth , Dietmar Heil
CPC分类号： H01M8/0631 , B01J8/008 , B01J8/0085 , B01J8/02 , B01J8/0278 , C01B3/323 , C01B3/382 , C01B3/48 , B01J2208/00699 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/0833 , C01B2203/0844 , C01B2203/0866 , C01B2203/1011 , C01B2203/1223 , C01B2203/1258 , C01B2203/1288 , C01B2203/142 , C01B2203/82
摘要： A reforming reactor system, suitable in particular for water vapor reforming of methanol, has a reforming reactor in which a reforming catalyst material is situated. A drop catching element is assigned to the inlet side of the reforming reactor, in order to catch drops which may be contained in the gas/vapor mixture, and thus prevent their damaging contact with the catalyst material.
摘要翻译： 特别适用于甲醇的水蒸气重整的重整反应器系统具有其中设置有重整催化剂材料的重整反应器。 为了捕获可能包含在气体/蒸气混合物中的液滴，并且因此防止其与催化剂材料的破坏性接触，将分液捕获元件分配到重整反应器的入口侧。
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