摘要:
Structured layers of heat-resistant polycondensates are prepared by a process wherein ethylenically unsaturated tetracarboxylates or adducts or salts of tetracarboxylates, which still contain at least one unesterified carboxylic acid group, with ethylenically unsaturated amines, amides or onium compounds mixed with compounds which contain amino, isocyanate or blocked isocyanate groups and can be subjected to polycondensation with the tetracarboxylates are applied as a layer to a substrate, this layer is exposed through a negative, the unexposed, soluble parts are then removed and the insoluble parts are converted into the final polycondensate form at elevated temperatures.
摘要:
Solutions of polycondensates which have N-containing heterocyclic ring systems as structural units, or solutions of intermediates of these polycondensates, in inorganic solvents, contain from 0.1 to 20% by weight, based on the polycondensates or the intermediates thereof, of one or more azidosilanes of the general formulaN.sub.3 --R.sup.3 --Si--R.sup.1.sub.n (OR.sup.2).sub.3-n Iwhere R.sup.1 is C.sub.1 -C.sub.3 -alkyl, phenyl, benzyl or toluyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkoxyalkyl, phenyl or benzyl, R.sup.3 is C.sub.1 -C.sub.8 -alkylene which may be interrupted by an oxygen atom, a sulfur atom or a --(N--R.sup.4) -group, where R.sup.4 is hydrogen, methyl, ethyl or phenyl, and n is 0, 1 or 2.
摘要:
Aqueous slurries of finely divided fillers which are at least partly coated with polymers and which are obtainable by treating aqueous slurries of finely divided fillers with at least one water-soluble amphoteric copolymer whose structures are identified in the specification are used as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining of the paper stock.
摘要:
Use of a mixture of from 5 to 95% by weight of an azidosilane of the formulaN.sub.3 --R.sup.3 --Si--R.sup.1.sub.n (OR.sup.2).sub.3-n Iwhere R.sup.1 is C.sub.1 -C.sub.3 -alkyl, phenyl, benzyl or tolyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkoxyalkyl, phenyl or benzyl, R.sup.3 is C.sub.1 -C.sub.8 -alkylene, which may be interrupted by oxygen, sulfur or --(N--R.sup.4)-- in which R.sup.4 is hydrogen, methyl, ethyl or phenyl, and n is 0, 1 or 2, and from 5 to 95% by weight of an aminoalkoxysilane of the formulaH.sub.2 N--R.sup.5 --Si--R.sup.6.sub.m (OR.sup.7).sub.3-m (II)where R.sup.5 is C.sub.1 -C.sub.6 -alkylene, C.sub.5 -C.sub.6 -cycloalkylene or C.sub.5 -C.sub.6 -arylene, each of which may be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and R.sup.6 and R.sup.7, independently of one another, are C.sub.1 -C.sub.6 -alkyl or C.sub.5 -C.sub.6 -cycloalkyl, each of which may likewise be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and m may be 0, 1 or 2, as an adhesion promoter between polycondensates containing, as structural units, heterocyclic ring systems containing nitrogen atoms, or precursors of these polycondensates, and inorganic substrates.
摘要:
Process for the production of paper, board and cardboard having high dry strength by addition of at least one water-soluble (a) polymer comprising vinylamine units and at least one (b) polymer comprising ethylenimine units and at least one water-soluble polymeric anionic compound to a paper stock, draining of the paper stock with sheet formation and drying of the paper products, the water-soluble cationic polymers (a) and (b) being metered in any sequence or as a mixture into a paper stock, and papers which are obtainable by this process.
摘要:
The present invention relates to an aqueous composition comprising at least one finely divided filler and at least one water-soluble amphoteric copolymer, a process for the preparation of such a composition and its use as an additive in the production of paper, cardboard and board.
摘要:
A radiation-crosslinkable mixture which contains a carboxyl-containing precursor of a heterocyclic polymer, a copolymerizable ethylenically unsaturated ternary sulfonium salt, a photoinitiator and a polar aprotic organic solvent.
摘要:
Process for the production of paper, board and cardboard having high dry strength by addition of at least one water-soluble (a) polymer comprising vinylamine units and at least one (b) polymer comprising ethylenimine units and at least one water-soluble polymeric anionic compound to a paper stock, draining of the paper stock with sheet formation and drying of the paper products, the water-soluble cationic polymers (a) and (b) being metered in any sequence or as a mixture into a paper stock, and papers which are obtainable by this process.
摘要:
Aqueous slurries of finely divided fillers which are at least partly coated with polymers and which are obtainable by treating aqueous slurries of finely divided fillers with at least one water-soluble amphoteric copolymer which is obtainable by copolymerization of (a) at least one N-vinylcarboxamide of the formula where R1 and R2 are H or C1- to C6-alkyl, (b) at least one monoethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms in the molecule and/or the alkali metal, alkaline earth metal or ammonium salts thereof and, if required, (c) other monoethylenically unsaturated monomers which are free of nitrile groups and, if required, (d) compounds which have at least two ethylenically unsaturated double bonds in the molecule and subsequent partial or complete elimination of the groups —CO—R1 from the monomers III incorporated in the form of polymerized units in the copolymer are used as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining of the paper stock.
摘要:
Use of a mixture of from 5 to 95% by weight of an azidosilane of the formulaN.sub.3 --R.sup.3 --Si--R.sup.1.sub.n (OR.sup.2).sub.3-n Iwhere R.sup.1 is C.sub.1 -C.sub.3 -alkyl, phenyl, benzyl or tolyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkoxyalkyl, phenyl or benzyl, R.sup.3 is C.sub.1 -C.sub.8 -alkylene, which may be interrupted by oxygen, sulfur or --(N--R.sup.4)-- in which R.sup.4 is hydrogen, methyl, ethyl or phenyl, and n is 0, 1 or 2, and from 5 to 95% by weight of an aminoalkoxysilane of the formulaH.sub.2 N--R.sup.5 --Si--R.sup.6.sub.m (OR.sup.7).sub.3-m IIwhere R.sup.5 is C.sub.1 -C.sub.6 -alkylene, C.sub.5 -C.sub.6 -cycloalkylene or C.sub.5 -C.sub.6 -arylene, each of which may be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and R.sup.6 and R.sup.7, independently of one another, are C.sub.1 -C.sub.6 -alkyl or C.sub.5 -C.sub.6 -cycloalkyl, each of which may likewise be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and m may be 0, 1 or 2, as an adhesion promoter between polycondensates containing, as structural units, heterocyclic ring systems containing nitrogen atoms, or precursors of these polycondensates, and inorganic substrates.