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公开(公告)号：US5204075A
公开(公告)日：1993-04-20
申请号：US710190
申请日：1991-05-30
IPC分类号： B01D53/02 , B01D53/04 , B01D53/26 , B01D53/86 , B01J2/08 , B01J23/40 , C01B21/04 , C01B23/00 , F25J3/02
CPC分类号： C01B21/0494 , B01D53/04 , C01B23/00 , F25J3/04642 , F25J3/04733 , F25J3/04739 , F25J3/08 , B01D2256/18 , B01D2257/104 , B01D2257/80 , B01D2259/40086 , B01D2259/402 , B01D2259/4146 , B01D2259/416 , C01B2210/0006 , C01B2210/0014 , C01B2210/0045 , F25J2200/02 , F25J2205/40 , F25J2205/60 , F25J2205/82 , F25J2215/30 , F25J2215/32 , F25J2215/44 , F25J2215/58 , F25J2220/44 , F25J2240/02
摘要： A process for producing a substantially oxygen-free gaseous product such as argon containing not more than one ppm by volume of oxygen is disclosed. The process comprises introducing hydrogen into a gas stream which contains oxygen and moisture, contacting the gas stream with a dessicant to remove substantially all of the moisture therefrom, contacting the substantially anhydrous gas stream with an oxidation catalyst to convert substantially all of the oxygen in the gas stream to water, and contacting the resultant gas stream with a dessicant to remove the water created in the oxidation step. The product stream may be further purified to remove residual hydrogen contained therein.
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公开(公告)号：US06761838B2
公开(公告)日：2004-07-13
申请号：US09909622
申请日：2001-07-20
IPC分类号： C07C102
CPC分类号： C07D301/22 , C01B3/36 , C01B3/386 , C01B13/0251 , C01B13/0255 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/0811 , C01B2203/0844 , C01B2203/085 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/82 , C01B2210/0046 , C07C17/154 , C07C17/156 , C07C45/33 , C07C45/34 , C07C45/35 , C07C253/24 , C07C253/26 , C07D301/04 , C07C19/045 , C07C21/06 , C07C47/22 , C07C47/06 , C07C255/08
摘要： Partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide is carried out by a cyclical process, which includes (a) contacting an oxygen ion conducting ceramic with air at a pressure between about 1 and 50 bara in a reactor, wherein oxygen from the air reacts with the ceramic, thereby producing an oxygen-enriched ceramic, and (b) contacting the hot, oxygen-enriched ceramic with hydrocarbon gas and optionally steam in the reactor. During the partial oxidation reaction phase of the process, the oxygen-enriched ceramic reacts with the hydrocarbon, thereby producing the desired gas products and regenerating the oxygen ion conducting ceramic for the next cycle of the process.
摘要翻译： 通过循环过程进行烃的部分氧化，其包括（a）在反应器中使氧离子导电陶瓷与空气在约1至50巴之间的压力下接触，其中来自空气的氧反应 与陶瓷一起生产富氧陶瓷，和（b）使热的富氧陶瓷与烃气体和任选的蒸汽在反应器中接触。 在该方法的部分氧化反应阶段期间，富氧陶瓷与烃反应，从而产生所需的气体产物并再生氧离子传导陶瓷用于下一循环过程。
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公开(公告)号：US06379586B1
公开(公告)日：2002-04-30
申请号：US09175175
申请日：1998-10-20
IPC分类号： C07C102
CPC分类号： C07D301/22 , C01B3/36 , C01B3/386 , C01B13/0251 , C01B13/0255 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/0811 , C01B2203/0844 , C01B2203/085 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/82 , C01B2210/0046 , C07C17/154 , C07C17/156 , C07C45/33 , C07C45/34 , C07C45/35 , C07C253/24 , C07C253/26 , C07D301/04 , C07C19/045 , C07C21/06 , C07C47/22 , C07C47/06 , C07C255/08
摘要： Partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide is carried out by a cyclical process which includes passing air through a perovskite ceramic substance at elevated temperature, thereby adsorbing oxygen from the air, and subsequently contacting the hot oxygen-containing ceramic substance with a hydrocarbon. During the partial oxidation reaction phase of the process, the sorbed oxygen reacts with the hydrocarbon, thereby producing the desired gas products and regenerating the adsorbent for the next cycle of the process.
摘要翻译： 碳氢化合物部分氧化产生氢气和一氧化碳是通过循环过程进行的，其包括使空气在升高的温度下通过钙钛矿陶瓷物质，从而从空气中吸附氧气，然后使热氧含量的陶瓷物质与烃接触 。 在该方法的部分氧化反应阶段期间，吸附的氧气与烃反应，从而产生所需的气体产物并在下一循环过程中再生吸附剂。
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公开(公告)号：US20140332405A1
公开(公告)日：2014-11-13
申请号：US13889730
申请日：2013-05-08
CPC分类号： C01B3/50 , C01B3/56 , C01B2203/0205 , C01B2203/04 , C01B2203/043 , C01B2203/146 , C25B1/02
摘要： A method for producing hydrogen by performing the steps of feeding a synthesis gas mixture to a pressure swing adsorption unit; producing hydrogen from the synthesis gas mixture in the pressure swing adsorption unit; feeding the remainder of the synthesis gas mixture at low pressure to an electrochemical cell wherein hydrogen is separated from the remainder of the synthesis gas mixture and is simultaneously pressurized; feeding the pressurized hydrogen from the electrochemical cell to join with the hydrogen generated in the pressure swing adsorption unit and recovering the combined hydrogen product. The synthesis gas mixture may be from a reformation unit and it may be subject to a water gas shift reaction. In addition to the production of hydrogen, the separation of hydrogen in the electrochemical cell increases the concentration of carbon dioxide in the residual waste gas and enables carbon dioxide recovery.
摘要翻译： 一种通过以下步骤制造氢的方法：将合成气混合物供给到变压吸附单元; 在变压吸附单元中从合成气体混合物产生氢气; 将其余的合成气混合物在低压下供给到电化学电池，其中氢与合成气混合物的其余部分分离并同时加压; 将来自电化学电池的加压氢供给到在变压吸附单元中产生的氢气并回收组合的氢气产物。 合成气混合物可以来自重整单元，并且它可能经历水煤气变换反应。 除了生产氢气之外，电化学电池中的氢气分离会增加残余废气中的二氧化碳浓度，并能使二氧化碳回收。
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公开(公告)号：US08128736B2
公开(公告)日：2012-03-06
申请号：US12539117
申请日：2009-08-11
摘要： A method for producing carbon dioxide by the steps of feeding a CO2-rich feed stream containing fuel gas to an oxygenated oxygen-selective ceramic bed to produce a product stream of carbon dioxide, water, and residual oxygen; adding oxygen to this product stream and feeding to an oxygen-depleted oxygen-selective ceramic bed and recovering carbon dioxide substantially free of oxygen and fuel gas. In an additional embodiment, nitrogen oxides are also removed from the fuel gas.
摘要翻译： 通过以下步骤生产二氧化碳的方法：将含有燃料气体的富CO 2进料流供给到氧化氧选择性陶瓷床中以产生二氧化碳，水和残留氧的产物流; 向该产物流中加入氧气并进料至贫氧氧选择性陶瓷床并回收基本上不含氧气和燃料气体的二氧化碳。 在另外的实施方案中，氮氧化物也从燃料气体中除去。
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公开(公告)号：US07624770B2
公开(公告)日：2009-12-01
申请号：US11234431
申请日：2005-09-23
申请人： Robert Walter Boyd , David Grant Wardle , Kelly R. Leitch , Satish S. Tamhankar , Gary Peter Lomas
发明人： Robert Walter Boyd , David Grant Wardle , Kelly R. Leitch , Satish S. Tamhankar , Gary Peter Lomas
CPC分类号： F17C5/007 , F17C2205/0142 , F17C2221/012 , F17C2223/0123 , F17C2223/035 , F17C2223/036 , F17C2225/0123 , F17C2225/036 , F17C2227/0157 , F17C2227/043 , F17C2250/032 , F17C2250/034 , F17C2270/0139 , F17C2270/0178 , Y02E60/321
摘要： Multi compressor systems and apparatuses for the manufacture, storage and dispensing of manufactured hydrogen fuel to hydrogen vehicle tanks or remote mobile refuelers are disclosed.
摘要翻译： 公开了用于制造，储存和分配制氢氢燃料到氢气车辆罐或远程移动加油机的多压缩机系统和装置。
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公开(公告)号：US5626033A
公开(公告)日：1997-05-06
申请号：US678921
申请日：1996-07-12
IPC分类号： B01D53/04 , B01D53/047 , F25J3/00
CPC分类号： B01D53/04 , B01D2253/308 , B01D2256/10 , B01D2257/206 , B01D53/02 , B01D53/0462 , B01D53/047 , Y10S62/908 , Y10S62/918
摘要： A process for recovering a given component from a first gas stream in which the given component is intermittently present by PSA or TSA using an adsorbent which more strongly adsorbs the given component by introducing into the first gas stream, prior to PSA or TSA treatment, a second gas stream that is enriched in the given component. The second gas stream may be introduced into the first gas stream only during periods when the concentration of given component in the first gas stream is below its maximum concentration or it may be continuously introduced into the first gas stream at a level which is greater than the maximum concentration of given component originally present in the first gas stream.
摘要翻译： 一种从第一气流中回收给定组分的方法，其中给定组分通过PSA或TSA间歇地存在，使用吸附剂，其通过在PSA或TSA处理之前引入第一气流中更强烈地吸附给定组分， 在给定组分中富集的第二气流。 第二气流可以仅在第一气流中的给定组分的浓度低于其最大浓度的时段内引入第一气流中，或者可以以大于第一气流的水平连续引入第一气流 最初存在于第一气流中的给定组分的最大浓度。
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公开(公告)号：US4888037A
公开(公告)日：1989-12-19
申请号：US229588
申请日：1988-08-08
IPC分类号： C03C27/02
CPC分类号： C03C27/02
摘要： A single-step process is disclosed for hermetically sealing a glass to a metal having similar coefficients of thermal expansion without carrying out the conventional pretreatment steps of decarburization and oxidization by heating to at least the melting point of the glass in an atmosphere containing from about 0.5 to 2.5 volume percent of water vapor, 0 to about 5 volume percent of hydrogen gas and the balance an inert gas, such as nitrogen.
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公开(公告)号：US20180148330A1
公开(公告)日：2018-05-31
申请号：US15364883
申请日：2016-11-30
IPC分类号： C01B3/40 , C01B3/38 , B01J23/755 , B01J23/46 , B01J21/04 , B01J23/745 , B01J35/00 , B01J35/04 , B01J37/02
CPC分类号： C01B3/40 , B01J23/462 , B01J23/755 , B01J35/04 , B01J37/0217 , B01J37/0225 , B01J37/0242 , C01B3/384 , C01B2203/0233 , C01B2203/0283 , C01B2203/043 , C01B2203/0811 , C01B2203/085 , C01B2203/1023 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , C01B2203/1614 , Y02P20/52
摘要： A method for producing hydrogen in a steam methane reformer is disclosed. The method provides for the steps of feeding a mixture of fuel and air to a steam methane reformer; feeding a mixture of steam and hydrocarbons to the steam methane reformer; contacting the steam and hydrocarbons with a metal monolith supported catalyst; providing an electric current to the metal monolith supported catalyst; and recovering the hydrogen. The electric current applied to the metal monolith supported catalyst will encounter electrical resistance which will create heat. This heat can supplement that provided for by the reaction of the fuel and air allowing for a reduction in fueling costs as well as treatment costs of the resultant flue gas.
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公开(公告)号：US20140311917A1
公开(公告)日：2014-10-23
申请号：US13866173
申请日：2013-04-19
申请人： Satish S. Tamhankar
发明人： Satish S. Tamhankar
CPC分类号： C25B1/02 , C01B3/34 , C01B3/36 , C01B3/38 , C01B3/382 , C01B3/48 , C01B3/501 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/025 , C01B2203/0283 , C01B2203/0405
摘要： A method is disclosed for producing high purity, high pressure hydrogen from a low pressure synthesis gas production process. The low pressure synthesis gas is produced from steam or carbon dioxide reforming of hydrocarbons, autothermal reforming of hydrocarbons or partial oxidation of hydrocarbons. The resulting low pressure synthesis gas mixture is fed to an electro-chemical cell wherein hydrogen is separated from the low pressure synthesis gas mixture and subjected to compression and high pressure; high purity hydrogen is recovered from the electro-chemical cell.
摘要翻译： 公开了一种从低压合成气生产过程生产高纯度，高压氢的方法。 低压合成气由碳氢化合物的蒸汽或二氧化碳重整，烃的自热重整或烃的部分氧化产生。 将所得的低压合成气混合物供给到电化学池，其中将氢从低压合成气混合物中分离出来并进行压缩和高压; 从电化学电池回收高纯度氢。
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