公开(公告)号：US20170028386A1

公开(公告)日：2017-02-02

申请号：US15291786

申请日：2016-10-12

Applicant: Rennovia Inc.

Inventor： Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

IPC: B01J23/52 ,  B01J21/06 ,  C07C51/235 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18 ,  B01J21/08 ,  B01J29/06

CPC classification number: B01J23/52 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/18 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.

Abstract translation: 公开了由铂和金组成的催化剂。 催化剂通常可用于选择性氧化由伯醇基团和至少一个仲醇基团组成的组合物，其中至少伯醇基团转化为羧基。 更具体地说，催化剂是负载催化剂，包括包含金的颗粒和包含铂的颗粒，其中铂与金的摩尔比在约100:1至约1:4的范围内，铂基本上以Pt（0）的形式存在， 并且含铂颗粒的尺寸在约2至约50nm的范围内。 还公开了将碳水化合物转化为羧酸或其衍生物的氧化化学催化转化的方法。 此外，公开了使用包含铂和金的催化剂将葡萄糖选择性氧化成葡糖二酸或其衍生物的方法。 此外，公开了用于生产这种催化剂的方法。

公开(公告)号：US09216937B2

公开(公告)日：2015-12-22

申请号：US13691588

申请日：2012-11-30

Applicant: Rennovia, Inc.

Inventor： Raymond Archer ,  Gary M. Diamond ,  Eric L. Dias ,  Vincent J. Murphy ,  Miroslav Petro ,  John D. Super

IPC: C07C55/12 ,  C07C51/377 ,  C07C69/42 ,  C07C51/347 ,  C07C51/09 ,  C07C209/00 ,  C07C51/41

CPC classification number: C07C51/347 ,  C07C51/09 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C55/14 ,  C07C211/12

Abstract: The present disclosure relates generally to water concentration reduction processes within an adipic acid process. The present invention also includes process for converting a glucose-containing feed derived from a carbohydrate source to an adipic acid product wherein the process includes the steps of: converting glucose in the feed to a reaction product including a hydrodeoxygenation substrate and a first concentration of water; reducing the concentration of water in the reaction product to produce a feedstock including the hydrodeoxygenation substrate and second concentration of water, wherein the second concentration of water is less than the first concentration of water; and converting at least a portion of the hydrodeoxygenation substrate in the feedstock to an adipic acid product. Processes are also disclosed for producing hexamethylene diamine and caprolactam from the adipic acid product.

Abstract translation: 本公开一般涉及己二酸方法中的水浓缩还原方法。 本发明还包括将衍生自碳水化合物源的含葡萄糖的饲料转化为己二酸产物的方法，其中该方法包括以下步骤：将饲料中的葡萄糖转化为包括加氢脱氧底物和第一浓度的水的反应产物 ; 降低反应产物中的水浓度以产生包括加氢脱氧底物和第二浓度的水的原料，其中第二浓度的水小于第一浓度的水; 并将原料中的至少一部分加氢脱氧底物转化为己二酸产物。 还公开了从己二酸产物制备己二胺和己内酰胺的方法。

公开(公告)号：US20170158593A1

公开(公告)日：2017-06-08

申请号：US15232285

申请日：2016-08-09

Applicant: Rennovia Inc.

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/377 ,  C07C51/31

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

公开(公告)号：US09487465B2

公开(公告)日：2016-11-08

申请号：US13691611

申请日：2012-11-30

Applicant: Rennovia, Inc.

Inventor： Raymond Archer ,  Gary M. Diamond ,  Eric L. Dias ,  Vincent J. Murphy ,  Miroslav Petro ,  John D. Super

IPC: C07C51/47 ,  C07C51/377 ,  B01D15/36 ,  B01D15/18 ,  B01D15/16

CPC classification number: C07C51/377 ,  B01D15/16 ,  B01D15/1821 ,  B01D15/185 ,  B01D15/363 ,  C07C51/47 ,  C07C53/08 ,  C07C59/285

Abstract: The present disclosure relates to processes for the separation of at least one di-carboxylic acid compound and/or at least one mono-carboxylic acid compound from a mixture. The separation processes involve contacting the mixture with an ion exchange medium to cause at least one of the mono- and/or di-carboxylic acid compounds to be retained by the medium, eluting at least one of the mono-carboxylic acid compound or the di-carboxylic acid compound using an eluent to form an eluate, wherein the eluate is enriched in at least one of the mono-carboxylic acid compound or di-carboxylic acid relative to the concentration of such eluted acid in the mixture having contacted the medium and wherein the eluent comprises an organic acid. The process has particular utility in the production of di-carboxylic acid compounds from glucose.

Abstract translation: 本公开涉及从混合物中分离至少一种二羧酸化合物和/或至少一种单羧酸化合物的方法。 分离过程包括使混合物与离子交换介质接触以使至少一种单羧酸化合物和/或二羧酸化合物由介质保留，至少一种单羧酸化合物或二 - 羧酸化合物，使用洗脱液形成洗脱液，其中洗脱液相对于接触培养基的混合物中这种洗脱酸的浓度富含至少一种单羧酸化合物或二羧酸，并且其中 洗脱液含有机酸。 该方法在从葡萄糖生产二羧酸化合物中具有特殊的用途。

公开(公告)号：US20140256982A1

公开(公告)日：2014-09-11

申请号：US14153248

申请日：2014-01-13

Applicant: Rennovia, Inc.

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/31 ,  C07C51/377

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

Abstract translation: 本发明一般涉及将葡萄糖源化学转化为己二酸产物的方法。 本发明包括通过葡糖二酸或其衍生物将葡萄糖转化成己二酸产物的方法。 本发明还包括将葡萄糖催化氧化成葡糖二酸或其衍生物的方法和包括将葡糖二酸或其衍生物催化加氢脱氧至己二酸产物的方法。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。

公开(公告)号：US20180086688A1

公开(公告)日：2018-03-29

申请号：US15722454

申请日：2017-10-02

Applicant: Rennovia Inc.

Inventor： Gary M. Diamond ,  Eric L. Dias ,  Raymond Archer ,  Vincent J. Murphy ,  Thomas R. Boussie

IPC: C07C51/47 ,  C07C51/23 ,  B01D15/36 ,  B01D15/18

CPC classification number: C07C51/47 ,  B01D15/1821 ,  B01D15/363 ,  C07C51/16 ,  C07C51/23 ,  C07C51/27

Abstract: Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.

公开(公告)号：US09808790B2

公开(公告)日：2017-11-07

申请号：US15291786

申请日：2016-10-12

Applicant: Rennovia Inc.

Inventor： Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

IPC: B01J23/52 ,  B01J23/42 ,  C07C51/235 ,  C07C51/377 ,  C07C51/41 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  B01J21/06 ,  B01J21/08 ,  B01J29/06 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18

CPC classification number: B01J23/52 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/18 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.

公开(公告)号：US20160090346A1

公开(公告)日：2016-03-31

申请号：US14869237

申请日：2015-09-29

Applicant: Rennovia Inc.

Inventor： Gary M. Diamond ,  Eric L. Dias ,  Raymond Archer ,  Vincent J. Murphy ,  Thomas R. Boussie

IPC: C07C51/47 ,  C07C51/23

CPC classification number: C07C51/47 ,  B01D15/1821 ,  B01D15/363 ,  C07C51/16 ,  C07C51/23 ,  C07C51/27

Abstract: Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.

Abstract translation: 提供了从含有二羧酸或其盐和一种或多种其它组分的混合物中分离二羧酸或其盐的方法。 还提供了用于这些分离方法的分离介质。 特别地，描述了制备阿拉德酸的方法，例如葡萄糖的葡糖二酸，其包括从反应产物中分离出醛酸。 另外，还描述了各种葡糖二酸产物。

公开(公告)号：US09156766B2

公开(公告)日：2015-10-13

申请号：US14153248

申请日：2014-01-13

Applicant: Rennovia, Inc.

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/36 ,  C07C51/31 ,  B01J23/40 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/652 ,  B01J23/656 ,  B01J23/89 ,  B01J35/00 ,  B01J37/02 ,  C07C51/235 ,  C07C51/377 ,  C07C51/41 ,  C07C209/00 ,  C07C253/00 ,  C07C201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  B01J21/06 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

Abstract translation: 本发明一般涉及将葡萄糖源化学转化为己二酸产物的方法。 本发明包括通过葡糖二酸或其衍生物将葡萄糖转化成己二酸产物的方法。 本发明还包括将葡萄糖催化氧化成葡糖二酸或其衍生物的方法和包括将葡糖二酸或其衍生物催化加氢脱氧至己二酸产物的方法。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。

公开(公告)号：US09776945B2

公开(公告)日：2017-10-03

申请号：US14869237

申请日：2015-09-29

Applicant: Rennovia Inc.

Inventor： Gary M. Diamond ,  Eric L. Dias ,  Raymond Archer ,  Vincent J. Murphy ,  Thomas R. Boussie

IPC: C07C51/47 ,  C07C51/23 ,  B01D15/36 ,  B01D15/18

CPC classification number: C07C51/47 ,  B01D15/1821 ,  B01D15/363 ,  C07C51/16 ,  C07C51/23 ,  C07C51/27

Abstract: Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.