公开(公告)号：US5679738A

公开(公告)日：1997-10-21

申请号：US489889

申请日：1995-06-13

申请人： Richard Anthony Bafford ,  Ning Chen ,  Chung-Ling Mao ,  Walter Louis Renz ,  Robert Krantz Pinschmidt, Jr.

发明人： Richard Anthony Bafford ,  Ning Chen ,  Chung-Ling Mao ,  Walter Louis Renz ,  Robert Krantz Pinschmidt, Jr.

IPC分类号： B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07C233/47 ,  C08F26/00 ,  C08F26/02 ,  C08F226/02 ,  C08L39/00 ,  C08L39/02 ,  C09J137/00 ,  C09J139/02 ,  C08F114/18 ,  C08F126/00

CPC分类号： C07C233/47 ,  C08F226/02 ,  C08F26/02

摘要： This invention pertains to aqueous emulsions containing water insoluble, vinyl polymer particles containing polymerized Michael adduct units of N-vinylformamide and to emulsions of vinyl acetate polymers containing said Michael adducts. These latex dispersions are prepared by the emulsion polymerization of a Michael adduct of N-vinylformamide, optionally with other ethylenically unsaturated monomers, e.g., vinyl acetate. The Michael adducts of N-vinylformamide are represented by the formula: ##STR1## where R is H or CH.sub.3, X=CN, O=CR.sub.1, O=COR.sub.1 or other electron withdrawing group such as SO.sub.3 M, SO.sub.3 R.sub.1 and NO.sub.2 wherein R.sub.1 is a linear or branched alkyl, cycloalkyl, heterocyclic, arylalkyl, alkyloxy or aryl group containing between 1 and about 20 carbon atoms and substituted derivatives thereof and M is an ion. The preferred Michael adduct N-vinyl amide monomers are unsaturated monomers consisting of the alkl 3-N-vinylformamidopropionates and alkyl 2-methyl-3-N-vinylformamidopropionates and represented by the formula: ##STR2## where R is hydrogen or methyl, and R.sup.1 is a linear or branched alkyl, cycloalkyl, heterocyclic, arylalkyl, alkyloxy or aryl group containing between 1 and about 20 carbon atoms.

摘要翻译： 本发明涉及含有水不溶性的含有N-乙烯基甲酰胺的聚合迈克尔加合物单元的乙烯基聚合物颗粒和含有所述迈克尔加合物的乙酸乙烯酯聚合物乳液的含水乳液。 这些胶乳分散体通过N-乙烯基甲酰胺的迈克尔加成物，任选与其它烯属不饱和单体如乙酸乙烯酯的乳液聚合来制备。 N-乙烯基甲酰胺的迈克尔加成物由下式表示：其中R是H或CH 3，X = CN，O = CR 1，O = COR 1或其它吸电子基团如SO 3 M，SO 3 R 1和NO 2，其中R 1是 含有1至约20个碳原子的直链或支链烷基，环烷基，杂环，芳烷基，烷氧基或芳基及其取代衍生物，M是离子。 优选的迈克尔加合物N-乙烯基酰胺单体是由3-N-乙烯基甲酰胺丙酸烷基酯和2-甲基-3-N-乙烯基甲酰胺丙酸烷基酯组成的不饱和单体，由下式表示：其中R是氢或甲基，R1 是含有1至约20个碳原子的直链或支链烷基，环烷基，杂环，芳烷基，烷氧基或芳基。

公开(公告)号：US5536784A

公开(公告)日：1996-07-16

申请号：US319365

申请日：1994-10-06

申请人： Chung-Ling Mao ,  Ning Chen ,  Chao-Fong Tien

发明人： Chung-Ling Mao ,  Ning Chen ,  Chao-Fong Tien

IPC分类号： C08F283/00 ,  C08G18/08 ,  C08G18/10 ,  C08G18/83 ,  C09D175/14 ,  C08L61/00

CPC分类号： C09D175/14 ,  C08F283/00 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/831

摘要： This invention relates to improved water-based polymeric dispersions having suitability for coatings and other applications which are based upon polymers having a plurality of acetoacetate functional groups and a crosslinkable component comprising a plurality of aromatic aldimine. The basic acetoacetate/benzaldimine containing system comprises an aqueous polymeric dispersion wherein the polymer has a plurality of acetoacetate groups and an effective amount of a curing agent having a plurality of benzaldimine functional groups. The improvement in providing for water-stable polymeric dispersions suitable for coatings and other applications comprises an aqueous dispersion comprising a polymeric component preferably derived from a plurality of polymerizable ethylenically unsaturated monomer units having pendant araldimine or heterocyclic aldimine functionality. Acetoacetate containing monomers generally are used in forming the polymer and a preferred monomer acetoacetoxyethymethacrylate. The polymer incorporating a plurality of benzaldimine functionality generally is formed by emulsion or suspension polymerization and the adimine functionality is benzaldimine.

摘要翻译： 本发明涉及对基于具有多个乙酰乙酸酯官能团的聚合物和包含多个芳族醛亚胺的可交联组分的涂料和其它应用的适用性的改进的水基聚合物分散体。 含有乙酰乙酸酯/苯并二醛的碱性体系基本包括含水聚合物分散体，其中聚合物具有多个乙酰乙酸酯基团和有效量的具有多个苯甲酰亚胺官能团的固化剂。 提供适用于涂料和其它应用的水稳定聚合物分散体的改进包括含有聚合物组分的水分散体，其优选衍生自具有侧链芳醛亚胺或杂环醛亚胺官能团的多个可聚合的烯属不饱和单体单元。 含乙酰乙酸酯的单体通常用于形成聚合物和优选的乙酰乙酰氧基乙基甲基丙烯酸酯单体。 掺入多种苯并二氮茚官能团的聚合物通常通过乳液或悬浮聚合形成，并且亚胺官能团是苯甲酰亚胺。

公开(公告)号：US5519084A

公开(公告)日：1996-05-21

申请号：US173251

申请日：1993-12-23

申请人： Helen Pak-Harvey ,  Chung-Ling Mao

发明人： Helen Pak-Harvey ,  Chung-Ling Mao

IPC分类号： C04B24/18 ,  C04B24/24 ,  C04B24/26 ,  C04B24/38 ,  C04B40/00 ,  C08J3/12 ,  C08L29/04 ,  C09D133/06

CPC分类号： C08J3/122 ,  C04B24/2641 ,  C04B40/0042 ,  C09D133/064 ,  C08J2333/06 ,  C08L29/04

摘要： A method for preparing an acrylic polymer powder which is redispersible in water by atomizing an aqueous polymer dispersion containing a dispersing aid, the improvement which comprises employing an acrylic polymer containing 1-15 wt % olefinically unsaturated carboxylic acid comonomer and an effective amount of a dispersing aid consisting essentially of polyvinyl alcohol.

摘要翻译： 一种制备丙烯酸聚合物粉末的方法，其通过雾化含有分散助剂的聚合物水分散体水分再分散在水中，其改进包括使用含有1-15重量％烯属不饱和羧酸共聚单体的丙烯酸聚合物和有效量的分散体 助剂基本上由聚乙烯醇组成。

公开(公告)号：US4225645A

公开(公告)日：1980-09-30

申请号：US956703

申请日：1978-11-01

申请人： Chung-Ling Mao ,  Walter Nudenberg

发明人： Chung-Ling Mao ,  Walter Nudenberg

IPC分类号： C08K5/02 ,  C08K5/3492 ,  C08K13/02 ,  C08L75/04 ,  D06M11/47 ,  D06M15/564 ,  D06M17/10 ,  C08K5/34

CPC分类号： D06M17/10 ,  C08K13/02 ,  C08K5/02 ,  C08K5/34922 ,  C08L75/04 ,  D06M11/47 ,  D06M15/564 ,  Y10T442/2049 ,  Y10T442/2656 ,  Y10T442/2861

摘要： This invention relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.

摘要翻译： 本发明涉及由弹性体聚氨酯预聚物获得的阻燃交联弹性体组合物; 含有氯和/或溴的有机阻燃添加剂; 锑的化合物; 和六烷氧基甲基三聚氰胺。 这些新的组合物是自熄的以及不滴水的。

公开(公告)号：US4049636A

公开(公告)日：1977-09-20

申请号：US661212

申请日：1976-02-25

申请人： Chung-Ling Mao ,  Francis X. O'Shea

发明人： Chung-Ling Mao ,  Francis X. O'Shea

IPC分类号： C08G18/00 ,  C08G18/12 ,  C08G18/40 ,  C08G18/63 ,  C08G18/65 ,  C08G18/04

CPC分类号： C08G18/6564 ,  C08G18/12 ,  C08G18/4072 ,  C08G18/632 ,  Y10S528/906

摘要： Flexible automobile exterior body parts are molded from a polyurethane elastomer prepared from a reaction mixture comprising:A. a poly(oxypropylene)-poly(oxyethylene) glycol of molecular weight of from about 1500 to about 4000 containing 15 to 50% by weight oxyethylene groups;B. a "graft" polyol of molecular weight from about 2500 to about 4500, prepared by the in situ polymerization of one or more ethylenically unsaturated monomers in a poly(oxypropylene) and/or poly(oxypropylene)-poly(oxyethylene) glycol containing less than 15% by weight oxyethylene groups;C. methylenebis(4-phenylisocyanate);D. 1,4-butanediol.The invention also relates to this polyurethane elastomer.

摘要翻译： 柔性汽车外部身体部件由由反应混合物制备的聚氨酯弹性体成型，包括：

公开(公告)号：US4041105A

公开(公告)日：1977-08-09

申请号：US661595

申请日：1976-02-26

申请人： Francis X. O'Shea ,  Chung-Ling Mao

发明人： Francis X. O'Shea ,  Chung-Ling Mao

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/63 ,  C08G18/65

CPC分类号： C08G18/6564 ,  C08G18/10 ,  C08G18/632 ,  C08G2120/00

摘要： Flexible automobile exterior body parts are molded from a polyurethane elastomer prepared from a reaction mixture comprising:A. a "graft" polyol prepared by the in situ polymerization of one or more ethylenically unsaturated monomers in a poly(oxypropylene)-poly(oxyethylene) glycol of molecular weight from about 1750 to about 4000 and containing from 15 to 50% oxyethylene groups by weight,B. methylenebis(4-phenylisocyanate),C. 1,4-butanediol.

摘要翻译： 柔性汽车外部身体部件由由反应混合物制备的聚氨酯弹性体模制成，包括：

公开(公告)号：US06426151B1

公开(公告)日：2002-07-30

申请号：US09243776

申请日：1999-02-03

申请人： Chung-Ling Mao ,  Kenneth Merle Kem

发明人： Chung-Ling Mao ,  Kenneth Merle Kem

IPC分类号： B32B2708

CPC分类号： C08F220/18 ,  C08F218/10 ,  C08F220/06 ,  C08F220/12 ,  C08F220/14 ,  C09J133/06 ,  C09J133/062 ,  C09J2201/606 ,  Y10T156/10 ,  Y10T428/31928

摘要： The present invention is directed to improved flexibilized, plasticized polyvinyl chloride films bonded with a substrate by means of an aqueous based pressure sensitive acrylic adhesive emulsion polymers. Conventional emulsion based pressure sensitive adhesives were comprised of a copolymer comprised of polymerized units of acrylic esters and ethylenically unsaturated monomers, the copolymer having a Tg of from −15 to −70° C. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in the incorporation of polymerized units of a vinyl C8-13 ester of a neo-acid into the adhesive. The vinyl ester is formed from a mixture of propylene oligomers and such vinyl ester is represented by the chemical formula: C8-13H7-27CO2CH═CH2. Preferably, the adhesive includes units of methyl methacrylate, butyl acrylate of 2-ethylhexyl acrylate and a carboxylic acid selected from acrylic acid or methacrylic acid.

摘要翻译： 本发明涉及通过基于水性的压敏丙烯酸粘合剂乳液聚合物与基材结合的改进的柔性增塑的聚氯乙烯膜。 常规的基于乳液的压敏粘合剂由包含丙烯酸酯和烯键式不饱和单体的聚合单元的共聚物组成，共聚物的Tg为-15至-70℃。水性乳液聚合压敏粘合剂的改进 存在于将新酸的乙烯基C8-13酯的聚合单元并入粘合剂中。 乙烯基酯由丙烯低聚物的混合物形成，这种乙烯基酯由下列化学式表示：C8-13H7-27CO2CH = CH2。 优选地，粘合剂包括甲基丙烯酸甲酯，丙烯酸2-乙基己酯的丙烯酸丁酯和选自丙烯酸或甲基丙烯酸的羧酸的单元。

公开(公告)号：US4698384A

公开(公告)日：1987-10-06

申请号：US831015

申请日：1986-02-19

申请人： Chung-Ling Mao

发明人： Chung-Ling Mao

IPC分类号： C08F2/16 ,  C08F218/08

CPC分类号： C08F218/08

摘要： A copolymer emulsion for bonding nonwoven products comprising an aqueous medium having colloidally dispersed therein a copolymer consisting essentially of vinyl acetate, 5-35 wt % ethylene and 2 to 10 wt % of an amide functional crosslinking comonomer which is N-methylolacrylamide or a compound of the formula R--NH--(CH.sub.2).sub.n --CH(OR').sub.2 where R is (meth)acryloyl, R' is a C.sub.1 -C.sub.4 alkyl group and n is 3 or 4, the copolymer emulsion prepared in the presence of 0.1 to 1 wt % polyvinyl pyrrolidone, based on vinyl acetate in the copolymer. Such emulsion binder copolymers demonstrate improved solvent resistance.

摘要翻译： 一种用于粘合非织造产品的共聚物乳液，其包含胶体分散在其中的水性介质，所述共聚物乳液基本上由乙酸乙烯酯，5-35重量％乙烯和2-10重量％的作为N-羟甲基丙烯酰胺的酰胺官能交联共聚单体组成的共聚物或 式R-NH-（CH2）n-CH（OR'）2其中R是（甲基）丙烯酰基，R'是C1-C4烷基，n是3或4，在0.1的存在下制备的共聚物乳液 至1重量％的聚乙烯吡咯烷酮，基于共聚物中的乙酸乙烯酯。 这种乳液粘合剂共聚物显示出改善的耐溶剂性。

公开(公告)号：US4147678A

公开(公告)日：1979-04-03

申请号：US796585

申请日：1977-05-13

申请人： Chung-Ling Mao ,  Walter Nudenberg

发明人： Chung-Ling Mao ,  Walter Nudenberg

IPC分类号： C08G18/00 ,  C08K5/02 ,  C08K5/34 ,  C08K13/02 ,  C08L75/00 ,  C08L75/04 ,  C08K3/38

CPC分类号： C08L75/04 ,  C08K13/02 ,  C08K5/02 ,  Y10S521/906

摘要： This inventon relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.

摘要翻译： 本发明涉及由弹性体聚氨酯预聚物获得的阻燃交联弹性体组合物; 含有氯和/或溴的有机阻燃添加剂; 锑的化合物; 和六烷氧基甲基三聚氰胺。 这些新的组合物是自熄的以及不滴水的。

公开(公告)号：US4108868A

公开(公告)日：1978-08-22

申请号：US552497

申请日：1975-02-24

申请人： Chung-Ling Mao

发明人： Chung-Ling Mao

IPC分类号： C07D333/48 ,  C07D333/66 ,  C08G18/10 ,  C08G18/38 ,  C08K5/05

CPC分类号： C07D333/48 ,  C07D333/66 ,  C08G18/10 ,  C08G18/3874

摘要： Chain extended polyurethanes are prepared, using certain 3-(hydroxyhydrocarbylsecondaryamino)thiophene 1,1-dioxides, some of which are new chemicals. E.g., 3-(2-hydroxypropylamino)tetrahydrothiophene 1,1-dioxide is especially useful as a chain extender for high resiliency, flexible polyurethane foams.

摘要翻译： 使用某些3-（羟基烃基二仲氨基）噻吩1,1-二氧化物制备扩链聚氨酯，其中一些是新的化学物质。 例如，3-（2-羟基丙基氨基）四氢噻吩1,1-二氧化物特别可用作高弹性的增链剂，柔性聚氨酯泡沫。