Method for the production of isocyanatoorganosilanes
    5.
    发明申请
    Method for the production of isocyanatoorganosilanes 有权
    制备异氰酸酯基有机硅烷的方法

    公开(公告)号:US20070066784A1

    公开(公告)日:2007-03-22

    申请号:US10595174

    申请日:2004-12-02

    IPC分类号: C08G77/00

    CPC分类号: C07F7/1892

    摘要: A process for preparing isocyanoatoorganosilanes by thermolysis of carbamatoorganosilanes in the presence of microwave radiation, optionally employing homogeneous or heterogeneous catalysis, provides isocyanatoorganosilane product in higher yield than prior art thermolyses, and with fewer byproducts. A continuous process is thus possible.

    摘要翻译: 在微波辐射的存在下,任选地使用均相或非均相催化的氨基甲酰硅氧烷热解制备异氰酰基有机硅烷的方法提供了比现有技术的热分解产物更高产率的异氰酸酯基有机硅烷产物,并且具有较少的副产物。 因此,连续的过程是可能的。

    Method for the production of isocyanatoorganosilanes
    7.
    发明授权
    Method for the production of isocyanatoorganosilanes 有权
    制备异氰酸酯基有机硅烷的方法

    公开(公告)号:US07576228B2

    公开(公告)日:2009-08-18

    申请号:US10595174

    申请日:2004-12-02

    IPC分类号: C07F7/04

    CPC分类号: C07F7/1892

    摘要: A process for preparing isocyanoatoorganosilanes by thermolysis of carbamatoorganosilanes in the presence of microwave radiation, optionally employing homogeneous or heterogeneous catalysis, provides isocyanatoorganosilane product in higher yield than prior art thermolyses, and with fewer byproducts. A continuous process is thus possible.

    摘要翻译: 在微波辐射的存在下,任选地使用均相或非均相催化的氨基甲酰硅氧烷热解制备异氰酰基有机硅烷的方法提供了比现有技术的热分解产物更高产率的异氰酸酯基有机硅烷产物,并且具有较少的副产物。 因此,连续的过程是可能的。

    Ru complexes, production and use thereof
    9.
    发明授权
    Ru complexes, production and use thereof 有权
    Ru配合物,生产和使用

    公开(公告)号:US08124711B2

    公开(公告)日:2012-02-28

    申请号:US12296370

    申请日:2007-03-28

    IPC分类号: C08G77/08

    CPC分类号: C07F17/02

    摘要: Ruthenium compounds which have, in their ligand sphere, at least one η6-bonded arene ligand and a silyl ligand; ruthenium complexes which have, in their ligand sphere, at least one η6-bonded arene ligand to which is bonded a silyl or siloxy radical directly or via a spacer, and ruthenium complexes which have, in their ligand sphere, at least one η6-bonded arene ligand and at least one further ligand to which is bonded a silyl or siloxy radical directly or via a spacer are useful as hydrosilylation catalysts.

    摘要翻译: 在其配位体中具有至少一个6键合的芳烃配体和甲硅烷基配体的钌化合物; 钌络合物在其配体球体中具有至少一个与键合甲硅烷基或甲硅烷氧基直接或经由间隔基键合的六键结合的芳烃配体,以及钌络合物,其配位体至少具有一个 ; 6-键合的芳烃配体和至少一个直接或通过间隔基与甲硅烷基或甲硅烷氧基结合的其它配体可用作氢化硅烷化催化剂。

    Organosilicon compounds containing alkenyl groups
    10.
    发明授权
    Organosilicon compounds containing alkenyl groups 失效
    含有烯基的有机硅化合物

    公开(公告)号:US06252101B1

    公开(公告)日:2001-06-26

    申请号:US09261823

    申请日:1999-03-03

    IPC分类号: C07F708

    摘要: The invention describes new organosilicon compounds containing alkenyl groups, comprising units of the formula A a ⁢ R b ⁡ ( R 1 ⁢ O ) c ⁢ SiO 4 - ( a + b + c ) 2 , ( I ) where R are identical or different and are each a monovalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds, has from 1 to 20 carbon atom(s) per radical and may contain from 1 to 4 oxygen atom(s), R1 are identical or different and are each a monovalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds and has from 1 to 8 carbon atom(s) per radical, a is 0 or 1, b is 0, 1, 2 or 3, c is 0, 1, 2 or 3, preferably 0, where the sum a+b+c≦3, A is a radical of the formula —(R2)d—Y(—CH═CHR3)2 where R2 is a divalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds and has from 1 to 6 carbon atom(s), R3 are identical or different and are each a hydrogen atom or are as defined for R, Y is a trivalent hydrocarbon radical which has from 2 to 20 carbon atoms and may contain from 1 to 4 oxygen atom(s) and d is 0 or 1, with the proviso that the organosilicon compounds have at least two units of the formula (I) and at least one radical A per molecule.

    摘要翻译: 本发明描述了含有烯基的新的有机硅化合物,其包含式R的单元相同或不同,并且各自为不含脂族碳 - 碳多键的单价烃基,每个基团具有1-20个碳原子 并且可以含有1至4个氧原子,R 1相同或不同,并且各自为不含脂族碳 - 碳多重键并且每个基团具有1至8个碳原子的单价烃基, 是0或1,b为0,1,2或3,c为0,1,2或3,优选为0,其中和a + b + c = 3,A为式R 2的基团为 不含脂族碳 - 碳多重键且具有1至6个碳原子的二价烃基,R 3相同或不同,各自为氢原子或如对R所定义,Y为三价烃基,其中 具有2至20个碳原子并且可以含有1至4个氧原子,d为0或1,条件是 有机硅化合物具有至少两个式(I)单元和每个分子至少一个基团A.