摘要:
The invention relates to a method for the production of polymers, comprising one or more of the recurring structural units of formula (1), where R1 is hydrogen, methyl, or ethyl, A is C1-C8-alkylene, Q+ is H+, NH4+, Na+, K+, ½ Mg++, ½ Ca++, or ½ Zn++, and where Q+ has a different meaning than H+ or NH4+ in 50 to 100 mol % of the structural units of formula (1), and one or more structural units derived from one or more further monomers, characterized in that the corresponding salts of said polymers are suspended in an organic suspension, where however the cations Q+ in the structural units of the formula (1) are NH4+ and optionally also H+, and an ion exchange is carried out by adding one or more bases comprising Na+, K+, Mg++, Ca++, or Zn++ ions.
摘要:
Polymers are described comprising a) one or more of the recurring structural units of the formula (1) where R1 is hydrogen, methyl or ethyl and A is C1-C8 alkylene, and Q+ is H+, NH4+, Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++ or ⅓ Al+++, and the neutralization degree of the structural units of formula (1) is 50 to 100 mol-%, and b) one or more of the recurring structural units of the formula (2) where R1 and A are R1 and A from formula (1) and X+ is [HNR5R6R7]+, where R5, R6 and R7 can independently from each other be hydrogen, a linear or branched alkyl group with 1 to 22 carbon atoms, a linear or branched, simple or polyunsaturated alkenylene group with 2 to 22 carbon atoms, a C6-C22-alkylamidopropyl group, a linear monohydroxyalkyl group with 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group with 3 to 10 carbon atoms, and wherein at least one of the groups R5, R6 and R7 is not hydrogen.
摘要翻译:描述了包含a)一种或多种式(1)的重复结构单元的聚合物,其中R 1是氢,甲基或乙基,A是C 1 -C 8亚烷基,Q +是H +,NH 4 +,Li +,Na +,K +,½ Ca ++,½Mg ++,½Zn ++或1/3 Al +++,式(1)的结构单元的中和度为50〜100mol%,b)一种或多种式(2)的重复结构单元 )其中R 1和A分别是R 1和A,并且X +是[HNR 5 R 6 R 7] +,其中R 5,R 6和R 7可以彼此独立地是氢,具有1至22个碳原子的直链或支链烷基, 具有2至22个碳原子的直链或支链,简单或多不饱和亚烯基,C 6 -C 22烷基酰胺基丙基,具有2至10个碳原子的直链单羟基烷基或具有3至10个碳原子的直链或支链二羟烷基,其中 基团R5,R6和R7中的至少一个不是氢。
摘要:
Polymers are described comprising a) one or more of the recurring structural units of the formula (1) where R1 is hydrogen, methyl or ethyl and A is C1-C8 alkylene, and Q+ is H+, NH4+, Li+, Na+, K+, ½Ca++, ½ Mg++, ½ Zn++ or ⅓ Al+++, and the neutralization degree of the structural units of formula (1) is 50 to 100 mol-%, and b) one or more of the recurring structural units of the formula (2) where R1 and A are R1 and A from formula (1) and X+ is [HNR5R6R7]+, where R5, R6 and R7 can independently from each other be hydrogen, a linear or branched alkyl group with 1 to 22 carbon atoms, a linear or branched, simple or polyunsaturated alkenylene group with 2 to 22 carbon atoms, a C6-C22-alkylamidopropyl group, a linear monohydroxyalkyl group with 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group with 3 to 10 carbon atoms, and wherein at least one of the groups R5, R6 and R7 is not hydrogen, with the proviso that the molar ratio of the structural units of formula (1), where Q+ is NH4+, Li+, Na+, K+, Ca++, Mg++, Zn++ or Al+++, to the structural units of formula (2) is 97:3 to 55:45 and the formation concentration (CMC)
摘要:
Copolymers are described, containing a) 20.0-99.9% by weight of one or more structural units resulting from polymerizable substances of the following structural formula (I) in which R2 is a linear or branched saturated alkyl radical having 6 to 200 carbon atoms or a linear or branched, mono- or, polyunsaturated alkenyl radical having 6 to 200 carbon atoms, and R1, Y, n and m are each as defined in claim 1, b) 0.1-20.0% by weight of one or more structural units resulting from polymerizable quaternary ammonium compounds, and c) 0-60.0% by weight of one or more nonionic structural units resulting from one or more further polymerizable substances. The copolymers are advantageously suitable, for example, for the production of cosmetic, dermatological or pharmaceutical formulations.
摘要:
A wafer suitable for epitaxial growth of gallium nitride (GaN) in a Metal Oxide Chemical Vapor Deposition (MOCVD) process. The wafer includes a silicon substrate having a front side and a back side and an edge extending between the front side and the back side, the edge including a front bevel surface connected to the front side and a back bevel surface connected to the back side, wherein the silicon substrate comprises an oxygen denuded silicon layer surrounding a core. The wafer further includes a protection layer being a thermally grown silicon oxide (SiO2) layer substantially covering the front bevel surface and the back bevel surface of the edge, while leaving at least a central region of the front side of the silicon substrate exposed, for preventing meltback during the MOCVD process.
摘要:
The invention relates to water-soluble or water-swellable polymers the repeating structural units of which consist of a) 90.0 to 99.99 mole-% of one or more repeating structural units originating from special monomers with sulfonic acid groups or the salts thereof such as for example 2-acrylamido-2-methyl-propanesulfonic acid or the salts thereof and b) 0.01 to 10.0 mole-% of one or more repeating structural units originating from special cross-linking agents with at least three polymerizable double bonds. The polymers for example have an advantageous sensory property profile and are highly suitable as thickening agents even in salt-containing compositions. They are furthermore advantageously suitable for producing cosmetic, dermatological or pharmaceutical compositions.
摘要:
The invention relates to water-soluble or water-swellable polymers that contain a) 20.0 to 98.97 mole-% of one or more repeating structural units originating from special monomers with sulfonic acid groups or the salts thereof such as e.g. 2-acrylamido-2-methyl-propanesulfonic acid or the salts thereof, b) 1.0 to 60.0 mole-% of one or more repeating structural units containing an amide group and d) 0.01 to 8.0 mole-% of one or more repeating structural units originating from special crosslinking agents with at least three polymerizable double bonds. The polymers for example have an advantageous sensory property profile and are highly suitable as thickening agents even in salt-containing compositions. They are furthermore advantageously suitable for producing cosmetic, dermatological or pharmaceutical compositions.
摘要:
A method for depositing a seed layer for a controllable electric pathway on a substrate includes selectively dispensing a seed material from an inkjet material dispenser onto said substrate.
摘要:
A variator for ratio adjustment of a continuously variable chain drive transmission having one variator shaft (1) and one variator pulley (2) supported upon the variator shaft (1) and axially movable by pressurizing a variator pressure chamber (31). The variator shaft (1) has on one end an axial hole (10) through which the variator pressure chamber (31) and a second pressure chamber (8) can be loaded with pressure independent of each other. The pressure is supplied to the variator pressure chamber (31) via a first section (13) of the axial hole (10) and the pressure is supplied to the second pressure chamber (8) via a non-rotating pipe (7) and a second section (15) of the axial hole (10), the pipe (7) is situated within the first hole section (13). It is proposed that the pipe (7) has two axially adjacently disposed sealing rings (73) for reciprocal dynamic sealing of the pressure supplies to the variator pressure chamber (31) and to the second pressure chamber (8) and that the variator shaft (1) has a vent hole (9) discharging, on one side between the two sealing rings (73) and on the other side in a transmission inner space (94).
摘要:
Water-soluble or water-swellable polymers are described, containing a) 20.0 to 98.99 mole percent of one or more independently recurring structural units of the formula (1) and b) 1.0 to 79.99 mole percent of one or more independently recurring structural units of the formula (2), and c) 0.01 to 8.0 mole percent of one or more independently recurring cross-linking structural units, which are obtained from one or more monomers having at least two olefinic double bonds. The polymers are suitable, for example, as thickeners or yield point formers, in particular in cosmetic, dermatological or pharmaceutical compositions.