摘要:
To reduce the number of particles in an exhaust gas (A), in particular in the exhaust gas (A) from an internal-combustion engine, sulfur dioxide SO2 which is contained in the exhaust gas (A) is at least partially catalytically oxidized, in the presence of ammonia NH3 in a catalytic converter system having a catalytic activity which increases in the direction of flow, to form sulfur trioxide SO3. The simultaneous presence of sulfur trioxide SO3 and ammonia NH3 in the exhaust-gas stream which is brought about in this way results in an agglomeration of the small and very small particles and reduction in the number thereof.
摘要:
A process for producing a catalyst body includes providing titanium dioxide, tungsten trioxide, vanadium pentoxide, aluminum oxide, and/or silicon oxide for the catalyst body. A kneadable and/or shapable compound is processed to form a shaped body by extrusion or by coating of a support body. The shaped body is dried and is calcined to form an active compound. The calcined shaped body is artificially aged by a final heat treatment at a temperature higher than the calcination temperature to produce a catalyst body having a high resistance to deactivation at high temperatures. The starting materials include from 65 to 95% by weight of titanium dioxide, 2 to 30% by weight of tungsten trioxide, 0 to 2% by weight of vanadium pentoxide, preferably, less than 1.5%, 0.1 to 10% by weight of aluminum oxide, and 0.1 to 10% by weight of silicon dioxide. The final heat treatment is done is at 660 to 700° C., drying is at 20 to 100° C. prior to calcination, and calcination is at 400° C. to less than 700° C.
摘要:
The invention relates to a catalytic converter and a method for cleaning the exhaust gas from an internal combustion engine which is operated with excess air. The catalytic converter has an active material made from the oxides TiO2, V2O5, CaO and SiO2, as well as WO3 and/or MoO3. An active material of this type has the property of using the SCR method to reduce to equal extents the levels of nitrogen oxides and hydrocarbons. The CO oxidation activity of a material of this type can be increased by metering in elements selected from the group consisting of Pt, Pd, Rh, Ru and Ir in any desired inorganic form.
摘要:
A process for regenerating a catalyst, in particular a plate-type or honeycomb catalyst, which has been at least partially deactivated by catalyst poisons, is described. The catalyst is treated with a gaseous reducing agent and with a polyfunctional complex-forming agent, so that the catalyst poisons are removed.
摘要:
A device for simultaneously filling a container serving as a fuel tank and a container serving as a reducing-agent container with a single pump nozzle is used for environmentally friendly internal combustion engines with exhaust-gas purification systems requiring both tanks which are to be refilled repeatedly. Filler necks of the containers as well as outlet pipes disposed in the pump nozzle and assigned to the filler necks, are combined. A method for filling the containers is also provided.
摘要:
Nitrogen oxides emitted by an internal-combustion engine operated with excess air are normally converted by the method of selective catalytic reduction by bringing the nitrogen oxides, together with ammonia, into contact with a selective catalyst. Due to the dangers associated with the use of ammonia, in a motor vehicle ammonia should only be carried in the form of a substance which liberates ammonia, generally an aqueous urea solution. A method and a device for introducing liquid into an exhaust-gas purification system according to the invention avoids frost damage to sections of the system during shutdown times and permits operation of the system at temperatures below the freezing point of the reducing agent solution being used. The method and device include a (thermally insulated) reservoir for the reducing agent liquid and a liquid supply line which is connected thereto and terminates in an outlet opening for the liquid. The reservoir and the liquid supply line can be heated. Furthermore, a heater is provided for liquefying a starting volume which is small as compared with the volume of the reservoir. The liquid supply line may also have a back-flush valve to which a gas that is under pressure can be applied. The supply line can consequently be blown free.
摘要:
A method for cleaning diesel engine exhaust gas is described. The exhaust gas is passed over a catalytic converter with an active material which contains (% by weight) 70-95% TiO2, 2-10% WO3 and/or MoO3, 0.1-5% V2O5, 0.1-8% CaO, 0.1-8% Al2O3, 0.1-5% B2O3 and 0.1-10% SiO2. A reducing agent for a reduction of nitrogen oxides is metered into the exhaust-gas stream upstream of the catalytic converter.
摘要翻译:描述了一种用于清洁柴油发动机废气的方法。 废气通过含有(重量%)70-95%TiO 2,2-10%WO 3和/或MoO 3,0.1-5%V 2 O 5,0.1-8%CaO,0.1- 8%Al2O3,0.1-5%B2O3和0.1-10%SiO2。 将用于还原氮氧化物的还原剂计量到催化转化器上游的排气流中。
摘要:
An SCR catalyst containing titanium, molybdenum and vanadium has the particular characteristic that its catalytic activity is significantly less than that of a tungsten-containing catalyst. That disadvantage has been compensated for in the past by using a comparatively large volume of catalyst. In contrast to the conventional practice of using a molybdenum oxide proportion of about 10 to 12% by weight, the invention proposes that the molybdenum proportion of the catalyst, in the form of molybdenum trioxide MoO.sub.3, is about 0.01 to 5% by weight, preferably 1.5 to 4% by weight, relative to the weight of the catalyst mass. A catalyst containing this amount of molybdenum thus has an activity comparable to that of a tungsten-containing catalyst. The invention is applicable to all deNO.sub.x catalytic converters which call for the simultaneous presence of a reducing agent, in particular plate-type and honeycomb-type catalytic converters.
摘要:
A method is provided in which the reducing agent, during the starting phase of the internal-combustion engine and during operation with decreasing and, if appropriate, virtually constant exhaust gas temperature, is fed superstoichiometrically in relation to the nitrogen oxide concentration, while taking into account the temperature-dependent storage capacity of a denitration catalytic converter for the reducing agent. The reducing agent is otherwise fed substoichiometrically. In this manner, the catalytic converter is kept at all times at a preferred charge level, so that on one hand it is possible to provide sufficient stored reducing agent for the catalytic conversion and on the other hand it is possible to still have a reducing agent buffer available which avoids slip of the reducing agent. The invention can be used in all internal-combustion engines operated with air excess, such as diesel engines and lean-burn engines.
摘要:
A process is provided for the catalytic removal of polycyclic aromatic nitro, nitroso and/or amino compounds from the exhaust gas of a combustion system, in particular a diesel engine. The exhaust gas is brought into contact with a catalytic converter which includes a catalytically active material that contains titanium dioxide, at a temperature of from 150 to 600° C. The polycyclic aromatic compounds are oxidized at the catalytic converter through the use of oxygen to form nitrogen oxides, carbon dioxide and water.