Cap liners, closures and gaskets from multi-block polymers
    1.
    发明授权
    Cap liners, closures and gaskets from multi-block polymers 有权
    多层聚合物的盖衬,封闭件和垫圈

    公开(公告)号:US07671106B2

    公开(公告)日:2010-03-02

    申请号:US11377007

    申请日:2006-03-15

    IPC分类号: C08F210/00 C08J9/00 C08G85/00

    摘要: A polymer composition comprises at least an ethylene/α-olefin interpolymer and at least one other polymer. The other polymer can be selected from a second ethylene/α-olefin interpolymer, an elastomer, a polyolefin, a polar polymer, and an ethylene/carboxylic acid interpolymer or ionomer thereof. The ethylene/α-olefin interpolymer is a block copolymer having at least a hard block and at least a soft block. The soft block comprises a higher amount of comonomers than the hard block. The block interpolymer has a number of unique characteristics disclosed here. Also provided are gaskets, bottle cap liners, and closures that comprise or obtained from a compositon comprising at least one ethylene/α-olefin interpolymer and at least one polyolefin. The gaskets are capable of compression sealing various containers, without contaminating the contents. Liquid containers particularly benefit from the use of the novel gasket materials disclosed herein.

    摘要翻译: 聚合物组合物包含至少一种乙烯/α-烯烃互聚物和至少一种其它聚合物。 另一种聚合物可以选自第二乙烯/α-烯烃互聚物,弹性体,聚烯烃,极性聚合物和乙烯/羧酸互聚物或其离聚物。 乙烯/α-烯烃互聚物是至少具有硬嵌段和至少一个软嵌段的嵌段共聚物。 软块包含比硬块更高量的共聚单体。 嵌段互聚物具有这里公开的许多独特特征。 还提供了包含或由包含至少一种乙烯/α-烯烃互聚物和至少一种聚烯烃的组合物获得的垫圈,瓶盖衬垫和闭合件。 垫圈能够压缩各种容器,而不会污染内容物。 液体容器特别受益于使用本文公开的新型垫片材料。

    High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices
    5.
    发明授权
    High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices 有权
    高密度聚乙烯组合物,其制造方法,由其制成的封闭装置以及制造这种闭合装置的方法

    公开(公告)号:US09056970B2

    公开(公告)日:2015-06-16

    申请号:US13144465

    申请日:2010-01-27

    摘要: The instant invention is a high-density polyethylene composition, method of producing the same, closure devices made therefrom, and method of making such closure devices. The high-density polyethylene composition according to the present invention comprises (a) a first component comprising a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.927 to 0.938 g/cm3, and a melt flow rate (I21) in the range of 4 to 10 g/10 minutes, and (b) a second component comprising a low molecular weight ethylene polymer having a density in the range of 0.960 to 0.975 g/cm3, and a melt index (I2) in the range of 100 to 1200 g/10 minutes; and wherein the high-density polyethylene composition has a melt index (I2) in the range of from 2 to 10 g/10 minutes, a density in the range of from 0.950 to 0.960 g/cm3, and a flow direction shrinkage to cross flow direction shrinkage ratio in the range of from 2 to 3.2, and an environmental stress crack resistance (ESCR) (F50) according to ASTM D-1693, condition B at 50° C., and using 10 percent Branched Octylphenoxy Poly(Ethyleneoxy) Ethanol, in the range of equal to or greater than 50 hours.

    摘要翻译: 本发明是高密度聚乙烯组合物,其制造方法,由其制成的封闭装置,以及制造这种闭合装置的方法。 根据本发明的高密度聚乙烯组合物包含(a)包含密度在0.927至0.938g / cm 3范围内的高分子量乙烯α-烯烃共聚物和熔体流动速率(I21)的第一组分, 在4至10g / 10分钟的范围内,和(b)包含密度在0.960至0.975g / cm 3范围内的低分子量乙烯聚合物的第二组分和在该范围内的熔体指数(I 2) 为100〜1200g / 10分钟; 并且其中所述高密度聚乙烯组合物具有在2至10g / 10分钟范围内的熔体指数(I 2),在0.950至0.960g / cm 3范围内的密度和横向流动方向收缩 方向收缩率在2至3.2范围内,以及根据ASTM D-1693,条件B在50℃下的环境应力开裂抗力(ESCR)(F50),并使用10%支链辛基苯氧基聚(乙烯氧基)乙醇 在等于或大于50小时的范围内。

    High-Density Polyethylene Compositions, Method of Making the Same, Articles Made Therefrom, and Method of Making Such Articles

    公开(公告)号:US20080221273A1

    公开(公告)日:2008-09-11

    申请号:US12067832

    申请日:2007-05-02

    摘要: The instant invention is a high-density polyethylene compositions, and method of making the same. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of equal or greater than 1. The method of producing a high-density polyethylene composition include the following steps: (1) introducing ethylene, and an alpha-olefin comonomer into a first reactor; (2) copolymerizing the ethylene with the alpha-olefin comonomer in the first reactor thereby producing a first component, wherein the first component being a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21) in the range of 0.5 to 10 g/10 minutes; (3) introducing the first component and additional ethylene into a second reactor; (4) polymerizing the additional ethylene in the second reactor thereby producing a second component, wherein the second component being a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes; and (5) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of equal or greater than 1.

    HIGH-DENSITY POLYETHYLENE COMPOSITIONS, METHOD OF PRODUCING THE SAME, CLOSURE DEVICES MADE THEREFROM, AND METHOD OF MAKING SUCH CLOSURE DEVICES
    8.
    发明申请
    HIGH-DENSITY POLYETHYLENE COMPOSITIONS, METHOD OF PRODUCING THE SAME, CLOSURE DEVICES MADE THEREFROM, AND METHOD OF MAKING SUCH CLOSURE DEVICES 有权
    高密度聚乙烯组合物,其制造方法,其制造的闭合装置以及制造这种封闭装置的方法

    公开(公告)号:US20120022214A1

    公开(公告)日:2012-01-26

    申请号:US13144465

    申请日:2010-01-27

    IPC分类号: C08L23/08

    摘要: The instant invention is a high-density polyethylene composition, method of producing the same, closure devices made therefrom, and method of making such closure devices. The high-density polyethylene composition according to the present invention comprises (a) a first component comprising a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.927 to 0.938 g/cm3, and a melt flow rate (I21) in the range of 4 to 10 g/10 minutes, and (b) a second component comprising a low molecular weight ethylene polymer having a density in the range of 0.960 to 0.975 g/cm3, and a melt index (I2) in the range of 100 to 1200 g/10 minutes; and wherein the high-density polyethylene composition has a melt index (I2) in the range of from 2 to 10 g/10 minutes, a density in the range of from 0.950 to 0.960 g/cm3, and a flow direction shrinkage to cross flow direction shrinkage ratio in the range of from 2 to 3.2, and an environmental stress crack resistance (ESCR) (F50) according to ASTM D-1693, condition B at 50° C., and using 10 percent Branched Octylphenoxy Poly (Ethyleneoxy) Ethanol, in the range of equal to or greater than 50 hours.

    摘要翻译: 本发明是高密度聚乙烯组合物,其制造方法,由其制成的封闭装置,以及制造这种闭合装置的方法。 根据本发明的高密度聚乙烯组合物包含(a)包含密度在0.927至0.938g / cm 3范围内的高分子量乙烯α-烯烃共聚物和熔体流动速率(I21)的第一组分, 在4至10g / 10分钟的范围内,和(b)包含密度在0.960至0.975g / cm 3范围内的低分子量乙烯聚合物的第二组分和在该范围内的熔体指数(I 2) 为100〜1200g / 10分钟; 并且其中所述高密度聚乙烯组合物具有在2至10g / 10分钟范围内的熔体指数(I 2),在0.950至0.960g / cm 3范围内的密度和横向流动方向收缩 方向收缩率在2至3.2范围内,以及根据ASTM D-1693,条件B在50℃下的环境应力开裂抗力(ESCR)(F50),并使用10%的支链辛基苯氧基聚(乙烯氧基)乙醇 在等于或大于50小时的范围内。