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公开(公告)号：US20180163141A1
公开(公告)日：2018-06-14
申请号：US15832805
申请日：2017-12-06
Applicant: SHELL OIL COMPANY
Inventor： Andries Quirin Maria BOON , Joseph Broun POWELL
CPC classification number: C10G1/06 , C01B3/38 , C01B2203/0233 , C01B2203/0244 , C10G3/00 , C10G3/42 , C10G2300/1011 , C10G2300/202 , C12M43/00 , C12P5/02 , C12P5/023 , G06Q30/018
Abstract: Systems and methods involving hydrocatalytic reactions that use molecular hydrogen obtained from a biogas generated from at least a portion of the hydrocatalytic reaction product. Hydrocatalytic reactions can require significant quantities of molecular hydrogen, particularly if the molecular hydrogen is being introduced under dynamic flow conditions. The present disclosure provides systems and methods that can allow for reducing the carbon footprint of the fuels formed from the hydrocatalytic reaction because at least a portion of the hydrogen used in the hydrocatalytic reaction has low carbon footprint. A fuel with low carbon footprint can qualify for certain governmental status that provides certain benefits.
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公开(公告)号：US20130118059A1
公开(公告)日：2013-05-16
申请号：US13677124
申请日：2012-11-14
Applicant: Shell Oil Company
Inventor： Jean Paul LANGE , Colin John SCHAVERIEN , Nicolaas Wilhelmus Joseph WAY , Johan Willem GOSSELINK , John William HARRIS , Andries Quirin Maria BOON , Andries Hendrik JANSSEN , Leticia ESPINOSA ALONSO
CPC classification number: C10G1/006 , C10G1/002 , C10G1/042 , C10G3/50 , C10G11/18 , C10L1/02 , Y02P30/20
Abstract: A process for conversion of a cellulosic material comprising a) a liquefaction step, comprising contacting a cellulosic material with a liquid solvent at a temperature of equal to or more than 200° C.; or contacting a cellulosic material with a liquid solvent at a temperature of equal to or more than 100° C. in the presence of a catalyst, to produce a final liquefied product; b) a catalytic cracking step, comprising contacting at least part of the final liquefied product with a fluidized catalytic cracking catalyst at a temperature of equal to or more than 400° C., to produce one or more cracked products.
Abstract translation: 一种转化纤维素材料的方法，包括a）液化步骤，包括在等于或大于200℃的温度下使纤维素材料与液体溶剂接触; 或在催化剂存在下，在等于或大于100℃的温度下将纤维素材料与液体溶剂接触，以产生最终的液化产物; b）催化裂化步骤，包括使至少部分最终液化产物与等于或大于400℃的温度下的流化催化裂化催化剂接触，以产生一种或多种裂化产物。
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公开(公告)号：US20150080626A1
公开(公告)日：2015-03-19
申请号：US14486021
申请日：2014-09-15
Applicant: SHELL OIL COMPANY
Inventor： Andries Quirin Maria BOON , Joseph Broun POWELL , Lamar Lane JOFFRION , Kimberly Ann JOHNSON , Hubert Willem SCHENCK
CPC classification number: C10G1/06 , C01B3/16 , C01B2203/0288 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/148 , C01B2210/0009 , C01B2210/001 , C01B2210/0014 , C01B2210/0025 , C10G1/002 , C10G1/08 , C10G1/083 , C10G3/42 , C10G3/52 , C10G2300/1014 , C10G2300/301 , C10G2300/302 , C10G2300/42 , C10J3/54 , C10J3/74 , C10J2300/1223 , C10J2300/1823 , C10K3/04 , C10L1/02 , C10L1/04 , C10L2200/0469 , C10L2290/02 , C10L2290/10 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: A bottom fraction of a product of a hydrocatalytic reaction is gasified to generate hydrogen for use in further hydrocatalytic reactions. In one embodiment, an overhead fraction of the hydrocatalytic reaction is further processed to generate higher molecular weight compounds. In another embodiment, a product of the further processing is separated into a bottom fraction and an overhead fraction, where the bottom fraction is also gasified to generate hydrogen for use in further hydrocatalytic reactions.
Abstract translation: 将催化反应的产物的底部馏分气化以产生氢气用于进一步的催化反应。 在一个实施方案中，进一步处理加氢催化反应的塔顶馏分以产生较高分子量的化合物。 在另一个实施方案中，将进一步处理的产物分离成塔底馏分和塔顶馏分，其中底部馏分也被气化以产生用于进一步加氢催化反应的氢。
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公开(公告)号：US20150080622A1
公开(公告)日：2015-03-19
申请号：US14485972
申请日：2014-09-15
Applicant: SHELL OIL COMPANY
Inventor： Joseph Broun POWELL , Lamar Lane JOFFRION , Kimberly Ann JOHNSON , Juben Nemchand CHHEDA , Molly GILCHREST , Andries Quirin Maria BOON
CPC classification number: C10G1/06 , B01D3/06 , C01B3/12 , C01B3/16 , C01B2203/0288 , C10G3/42 , C10G3/52 , C10G2300/301 , C10G2300/302 , C10J3/00 , C10K3/04 , Y02P20/145 , Y02P30/20
Abstract: A bottom fraction of a product of a hydrocatalytic reaction is gasified to generate hydrogen for use in further hydrocatalytic reactions. In one embodiment, one or more volatile organic compounds is also vaporized using heat generated in the gasification process. In one embodiment, an overhead fraction of the hydrocatalytic reaction is further processed to generate higher molecular weight compounds. In another embodiment, a product of the further processing is separated into a bottom fraction and an overhead fraction, where the bottom fraction is also gasified to generate hydrogen for use in further hydrocatalytic reactions.
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公开(公告)号：US20170166502A1
公开(公告)日：2017-06-15
申请号：US15378099
申请日：2016-12-14
Applicant: SHELL OIL COMPANY
Inventor： Andries Quirin Maria BOON , Joseph Broun POWELL
IPC: C07C29/145
CPC classification number: C07C29/145 , B01J23/755 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/047 , B01J37/20 , C10G1/065 , C10G3/00 , C10G3/46 , C10G3/52 , C10G2300/42 , Y02P30/20
Abstract: A method of extending the catalyst life of a hydrogenolysis catalyst activity in the presence of biomass and aqueous solution is described. Lignocellulosic biomass solids and aqueous solution is provided to in a hydrothermal digestion unit in the presence of a digestive solvent, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a solid metal oxide support. The lignocellulosic biomass solids in the hydrothermal digestion unit is heated to a temperature in the range of 180° C. to less than 300° C. in the presence of digestive solvent, hydrogen, and in the range of 0.15 wt. % to 12.5 wt. %, based on catalyst, of H2S or H2S source at least partially soluble in aqueous solution, and the supported hydrogenolysis catalyst forming a product solution containing plurality of oxygenated hydrocarbons, the hydrothermal digestion unit maintaining protective sulfur concentration.
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Patent Agency Ranking
公开(公告)号：US20170037072A1
公开(公告)日：2017-02-09
申请号：US15227990
申请日：2016-08-04
Applicant: SHELL OIL COMPANY
Inventor： Joseph Broun POWELL , Andries Quirin Maria BOON , Ye-Mon CHEN , Glenn Charles KOMPLIN
CPC classification number: C07H1/00 , C10G3/49 , C10G2300/202 , C10G2400/02 , C10G2400/04 , C10G2400/30 , Y02P30/20
Abstract: A method comprises introducing biomass solids to a digester comprising a reactor, a circulation system including a first injector; providing a catalyst-containing digestion medium and an organic solvent layer floating thereon; circulating the medium through the circulation system; flowing gas through the medium; keeping the medium hot enough to digest the solids; and operating the digester such a headspace exists above the solvent. The digester includes a first eductor having an inlet in the headspace, a second eductor having an inlet in the organic layer, and a downdraft tube having an inlet in the digestion medium. A motive fluid flowing from the first injector draws gas from the headspace into the first eductor, a motive fluid flowing from the first eductor draws fluid from the organic layer into the second eductor, and a motive fluid flowing from the second eductor draws fluid from the digestion medium into the downdraft tube.
Abstract translation: 一种方法包括将生物质固体引入包括反应器的消化器，包括第一注射器的循环系统; 提供含催化剂的消化介质和浮在其上的有机溶剂层; 使介质循环通过循环系统; 流过气体通过介质; 保持培养基足够热量消化固体; 并且操作蒸煮器这样的顶部空间存在于溶剂上方。 蒸煮器包括在顶部空间中具有入口的第一喷射器，在有机层中具有入口的第二喷射器和在消化介质中具有入口的向下流动管。 从第一喷射器流动的运动流体将气体从顶部空间吸入第一喷射器，从第一喷射器流动的运动流体将流体从有机层吸入第二喷射器，并且从第二喷射器流出的运动流体从 消化介质进入下降管。
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公开(公告)号：US20180163142A1
公开(公告)日：2018-06-14
申请号：US15832819
申请日：2017-12-06
Applicant: SHELL OIL COMPANY
Inventor： Andries Quirin Maria BOON , Joseph Broun POWELL , James William YAEGER
CPC classification number: C10G1/06 , C10B53/00 , C10B55/00 , C10B57/045 , C10G3/00 , C10G3/42 , C10G3/50 , C10G7/00 , C10G2300/1011 , C10G2300/1014 , C10G2300/201 , C10G2300/4056 , G06Q30/0207 , G06Q50/06 , Y02P30/20
Abstract: Systems and methods involving hydrocatalytic reactions that thermal energy obtained from combustion of coke generated by coking of at least a portion of the hydrocatalytic reaction product. Hydrocatalytic reactions can require substantial amounts of thermal energy. The present disclosure provides systems and methods that can allow for reducing the carbon footprint of the fuels formed from the hydrocatalytic reaction because at least a portion of the thermal energy used in the hydrocatalytic reaction has low carbon footprint. A fuel with low carbon footprint can qualify for certain governmental status that provides certain benefits.
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公开(公告)号：US20170175018A1
公开(公告)日：2017-06-22
申请号：US15386069
申请日：2016-12-21
Applicant: SHELL OIL COMPANY
Inventor： Jean Paul Andre Marie Joseph Ghislain LANGE , Joseph Broun POWELL , Andries Quirin Maria BOON
IPC: C10L1/02
CPC classification number: C10L1/02 , C10G1/065 , C10G1/083 , C10G2300/1014 , C10G2300/4012 , C10G2300/44 , C10L2200/0469 , Y02P30/20
Abstract: A process for the high temperature conversion of a cellulosic material into a bio-oil, wherein, under hydrogen atmosphere and in the presence of a catalyst, the cellulosic material is contacted in a reaction vessel with a liquid solvent, wherein water is present from 5% up to 80 wt %, based on the total amount of cellulosic material and liquid solvent present in the vessel, at an a controlled operating pressure of from equal to or more than 2.0 MPa to equal to or less than 13.0 MPa, wherein the partial hydrogen pressure contributes from equal to or more than 1.0 MPa to equal to or less than 6.0 MPa, and the total vapour pressure being lower than the autogenous pressure at the operating temperature and contributing in the range of from equal to or more than 1.0 MPa to equal to or less than 7.0 MPa, to produce a product mixture comprising bio-oil.
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公开(公告)号：US20150094201A1
公开(公告)日：2015-04-02
申请号：US14563479
申请日：2014-12-08
Applicant: SHELL OIL COMPANY
Inventor： Andries Hendrik JANSSEN , Andries Quirin Maria BOON , John William HARRIS , Nicolaas Wilhelmus Joseph WAY , Colin John SCHAVERIEN , Johan Willem GOSSELINK
CPC classification number: B01J38/40 , B01J29/90 , B01J38/12 , B01J38/14 , B01J38/30 , C10B49/22 , C10B53/02 , C10G1/08 , C10G1/083 , C10G3/57 , C10G11/18 , C10G2300/1011 , C10G2300/708 , Y02E50/14 , Y02P20/145 , Y02P30/20 , Y02P30/446
Abstract: A process for regenerating a coked catalytic cracking catalyst which the carbon-containing deposits on the catalyst contains at least 1 wt % bio-carbon, based on the total weight of carbon present in the carbon-containing deposits is provided. Such coked catalytic cracking catalyst is contacted with an oxygen containing gas at a temperature of equal to or more than 550° C. in a regenerator to produce a regenerated catalytic cracking catalyst, heat and carbon dioxide.
Abstract translation: 提供了一种基于存在于含碳沉积物中的碳的总重量，使催化剂上的含碳沉积物含有至少1重量％生物碳的再结晶催化裂化催化剂的方法。 这样的焦化催化裂化催化剂在再生器中在等于或高于550℃的温度下与含氧气体接触，以产生再生的催化裂化催化剂，热和二氧化碳。
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10.发明申请公开(公告)号：US20150080620A1
公开(公告)日：2015-03-19
申请号：US14485838
申请日：2014-09-15
Applicant: SHELL OIL COMPANY
Inventor： Andries Quirin Maria BOON , Joseph Broun POWELL , Kimberly Ann JOHNSON , Lamar Lane JOFFRION
CPC classification number: C10G1/06 , C01B3/16 , C01B3/36 , C01B2203/0255 , C01B2203/0288 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/046 , C01B2203/0485 , C01B2203/065 , C01B2203/146 , C10G3/42 , C10G3/52 , C10G2300/1014 , C10G2300/301 , C10G2300/302 , C10G2300/42 , C10J3/22 , C10J3/36 , C10J3/54 , C10J3/74 , C10J2300/0959 , C10J2300/0976 , C10J2300/1223 , C10J2300/1823 , C10K3/04 , Y02P20/145 , Y02P30/20
Abstract: Systems and methods for supplying hydrogen to a hydrocatalytic reaction of a biomass feedstock by gasification of a biomass material. In a preferred embodiment, the biomass material comprises hog fuel. In one embodiment, an overhead fraction of the hydrocatalytic reaction is further processed to generate higher molecular weight compounds, which can be used to produce a fuel product. In one embodiment, the biomass material comprises an outer bark layer of wood logs used as part of the biomass feedstock subject to the hydrocatalytic reaction.
Abstract translation: 通过生物质材料的气化将氢气供应给生物质原料的催化反应的系统和方法。 在优选实施例中，生物质材料包括猪油。 在一个实施方案中，进一步处理加氢催化反应的塔顶馏分以产生较高分子量的化合物，其可用于生产燃料产物。 在一个实施方案中，生物质材料包括用作经受水催化反应的生物质原料的一部分的木材的外部树皮层。
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