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公开(公告)号：US6002019A
公开(公告)日：1999-12-14
申请号：US975269
申请日：1997-11-21
IPC分类号： C07D307/60 , C07C17/152 , C07C45/33 , C07C45/34 , C07C51/215 , C07D301/32 , C07C253/24 , C07C253/26 , C07D307/34
CPC分类号： C07C45/33 , C07C17/152 , C07C45/34 , C07C51/215 , C07D301/32
摘要： Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical product is removed from the product gas stream, and part or all of the remaining gas stream is passed through a bed of hydrophobic adsorbent, which adsorbs mainly the unreacted hydrocarbon from the gas stream without adsorbing water vapor. The adsorbed hydrocarbon is purged from the bed with air, and the air-hydrocarbon mixture is recycled to the partial oxidation reactor.
摘要翻译： 在合适的催化剂存在下，通过烃与空气的气相反应来生产石化产品。 石油化学产品从产物气流中除去，部分或全部剩余的气流通过疏水性吸附剂床，其主要从气流中吸附未反应的烃，而不吸附水蒸气。 将吸附的烃与空气一起从床中清除，并将空气 - 烃混合物再循环至部分氧化反应器。
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2.发明授权Monolith based catalytic partial oxidation process for syngas production 失效用于合成气生产的基于Monolith的催化部分氧化方法公开(公告)号：US07090826B2
公开(公告)日：2006-08-15
申请号：US10657610
申请日：2003-09-08
申请人： Weibin Jiang , Seungdoo Park , Mark S. Tomczak , Divyanshu R. Acharya , Satish S. Tamhankar , Ramakrishnan Ramachandran
发明人： Weibin Jiang , Seungdoo Park , Mark S. Tomczak , Divyanshu R. Acharya , Satish S. Tamhankar , Ramakrishnan Ramachandran
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0877 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276 , C01B2203/146 , C01B2203/148 , C01B2203/1604 , C01B2203/1609 , Y02P20/52
摘要： An improved process for the catalytic partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide and less than ˜2% carbon dioxide is disclosed. The process further permits the reaction to be initiated at room temperature, and utilizes a metal catalyst deposited on a ceria-coated zirconia monolith support, which exhibits high conversions of hydrocarbons to synthesis gas (hydrogen and carbon monoxide).
摘要翻译： 公开了一种用于烃的催化部分氧化以产生氢气和一氧化碳和小于2％二氧化碳的改进方法。 该方法进一步允许反应在室温下开始，并且利用沉积在二氧化铈涂覆的氧化锆整料载体上的金属催化剂，其表现出高的烃转化为合成气（氢气和一氧化碳）。
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公开(公告)号：US5646304A
公开(公告)日：1997-07-08
申请号：US494293
申请日：1995-06-23
IPC分类号： C07B33/00 , C07B41/00 , C07C17/152 , C07C45/33 , C07C45/34 , C07C51/215 , C07C253/24 , C07D307/60
CPC分类号： C07B33/00 , C07B41/00 , C07C17/152 , C07C45/33 , C07C45/34 , C07C51/215
摘要： A petrochemical is produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical is removed from the reactor effluent, and part or all of the remaining petrochemical-free gas stream is passed through a hydrocarbon-selective adsorbent, which adsorbs hydrocarbon from the gas stream, leaving a hydrocarbon-depleted waste gas. Hydrocarbon is purged from the adsorbent with air, and the air-hydrocarbon mixture is recycled to the partial oxidation reactor. The purge air, and preferably both the purge air and the petrochemical-free gas stream are dried by passage through beds of zeolite 3A prior to being introduced into the hydrocarbon-selective adsorbent, and the beds of zeolite 3A are regenerated by passing heated hydrocarbon-depleted waste gas therethrough.
摘要翻译： 在合适的催化剂存在下，通过烃与空气的气相反应产生石化产物。 将石油化学品从反应器流出物中除去，并且部分或全部剩余的不含石油化物的气流通过烃选择性吸附剂，其从气流中吸附烃，留下不含烃的废气。 用空气从吸附剂中清除烃，并将空气 - 烃混合物再循环至部分氧化反应器。 吹扫空气，优选吹扫空气和无石油化学气体气流在引入烃选择性吸附剂之前通过沸石3A的床进行干燥，并且沸石3A的床通过加热的烃 - 贫化的废气通过其中。
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公开(公告)号：US5672196A
公开(公告)日：1997-09-30
申请号：US510115
申请日：1995-08-01
IPC分类号： B01D53/04 , B01D53/047
CPC分类号： B01D53/0462 , B01D53/0407 , B01D53/047 , B01D2256/24 , B01D2259/40003 , B01D2259/40056 , B01D2259/41 , B01D53/053
摘要： Hydrocarbon gas is separated from a gas mixture by concentration swing adsorption in a system consisting of a pair of adjacent adsorption beds that are contained in a cylindrical vessel and separated by a flat partition wall. The system is operated with the beds out of phase, such that one bed is in adsorption service while the other bed is regenerated by purging the bed with air. The pressure and temperature in the bed undergoing adsorption does not differ from the pressure and temperature, respectively in the bed being regenerated sufficiently to create significant stresses in the partition separating the beds. In a modified version, the gas mixture and purge air are dried by simultaneously passing these gases through one pair of adjacent adsorption beds that are contained in a cylindrical vessel and separated by a flat partition wall with the respective pressures and temperatures in the two beds being substantially equal, while a substantially identical pair of adjacent adsorption beds are being regenerated by passing heated nonadsorbed gas from the hydrocarbon adsorption system through the beds at a substantially constant temperature and pressure.
摘要翻译： 通过在由一对相邻的吸附床组成的系统中通过浓缩变化吸附将气体与气体混合物分离，该吸附床包含在圆柱形容器中并由平坦的分隔壁分隔开。 该系统与床不同步地操作，使得一个床处于吸附作业，而另一个床通过用空气清洗床再生。 进行吸附的床中的压力和温度分别与再生的床中的压力和温度分别不同，以在分隔床的隔板中产生显着的应力。 在改进的方案中，气体混合物和吹扫空气通过同时通过这些气体通过一对相邻的吸附床而被干燥，所述邻近的吸附床包含在圆柱形容器中并由平坦分隔壁隔开，两个床中的相应压力和温度是 基本相同，而基本上相同的一对相邻吸附床是通过使加热的非吸附气体从烃吸附系统通过床在基本恒定的温度和压力下再生的。
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公开(公告)号：US07303606B2
公开(公告)日：2007-12-04
申请号：US11092345
申请日：2005-03-29
申请人： Yongxian Zeng , Divyanshu R. Acharya , Satish S. Tamhankar , Narayanan Ramprasad , Ramakrishnan Ramachandran , Frank R. Fitch , Donald L. MacLean , Jerry Y. S. Lin , Richard H. Clarke
发明人： Yongxian Zeng , Divyanshu R. Acharya , Satish S. Tamhankar , Narayanan Ramprasad , Ramakrishnan Ramachandran , Frank R. Fitch , Donald L. MacLean , Jerry Y. S. Lin , Richard H. Clarke
IPC分类号： B01D53/04
CPC分类号： B01D53/04 , B01D53/047 , B01D2253/10 , B01D2256/12 , B01D2257/102 , B01D2259/40001 , C01B13/0259 , C01B2210/0046 , F23C9/00 , F23C2202/30 , F23L7/007 , F23L2900/07001 , Y02E20/322 , Y02E20/344 , Y02P20/124 , Y10S502/525
摘要： Production of oxygen-enriched gas streams is disclosed herein. Air streams contact an oxygen-selective mixed conductor particularly a perovskite material whereby oxygen is retained or adsorbed on the perovskite and can be employed in a variety of processes such as in combusting a fuel gas, heat recovery and boiler related operations.
摘要翻译： 本文公开了富氧气流的生产。 空气流接触氧选择性混合导体，特别是钙钛矿材料，由此氧气保留或吸附在钙钛矿上，可用于燃烧燃气，热回收和锅炉相关操作等各种工艺。
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公开(公告)号：US07070752B2
公开(公告)日：2006-07-04
申请号：US11038610
申请日：2005-01-19
申请人： Yongxian Zeng , Rudolph J. Wolf , Frank R. Fitch , Martin Bülow , Satish S. Tamhankar , Divyanshu R. Acharya
发明人： Yongxian Zeng , Rudolph J. Wolf , Frank R. Fitch , Martin Bülow , Satish S. Tamhankar , Divyanshu R. Acharya
CPC分类号： C01B3/40 , B01D53/02 , B01D53/0462 , B01D53/053 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/25 , B01D2253/304 , B01D2253/306 , B01D2253/308 , B01D2253/342 , B01J20/0207 , B01J20/0225 , B01J20/0233 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/28004 , B01J20/28019 , B01J20/28042 , B01J20/28045 , B01J20/28057 , B01J20/3007 , B01J20/3021 , B01J20/3042 , B01J20/305 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3289 , B01J23/002 , B01J23/83 , B01J37/0009 , B01J37/03 , B01J2220/42 , B01J2523/00 , C01B3/382 , C01B3/386 , C01B2203/0205 , C01B2203/0244 , C01B2203/043 , C01B2203/0844 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1088 , C01B2203/1241 , C01B2203/142 , C01B2203/82 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： Supported perovskite-type oxides are described. The perovskite-type oxides have the general formula of AxA′x′ByB′y′O3−δ, wherein A is an ion of a metal of Group IIIa or IIIb of the periodic table of elements or mixtures thereof; A′ is an ion of a metal of Groups Ia or IIa of the periodic table or mixtures thereof; B and B′ are ions of a d-block transition metal of the periodic table or mixtures thereof; x, x′, y and y′ vary from 0 to 1; 0.95
摘要翻译： 描述了支承的钙钛矿型氧化物。 钙钛矿型氧化物具有以下通式：A A x B x Y B'y' 其中A是元素周期表IIIa或IIIb族金属的离子或其混合物; A'是周期表的Ia或IIa族金属的离子或其混合物; B和B'是周期表的d-块过渡金属的离子或其混合物; x，x'，y和y'从0变化到1; 0.95
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公开(公告)号：US20140332405A1
公开(公告)日：2014-11-13
申请号：US13889730
申请日：2013-05-08
CPC分类号： C01B3/50 , C01B3/56 , C01B2203/0205 , C01B2203/04 , C01B2203/043 , C01B2203/146 , C25B1/02
摘要： A method for producing hydrogen by performing the steps of feeding a synthesis gas mixture to a pressure swing adsorption unit; producing hydrogen from the synthesis gas mixture in the pressure swing adsorption unit; feeding the remainder of the synthesis gas mixture at low pressure to an electrochemical cell wherein hydrogen is separated from the remainder of the synthesis gas mixture and is simultaneously pressurized; feeding the pressurized hydrogen from the electrochemical cell to join with the hydrogen generated in the pressure swing adsorption unit and recovering the combined hydrogen product. The synthesis gas mixture may be from a reformation unit and it may be subject to a water gas shift reaction. In addition to the production of hydrogen, the separation of hydrogen in the electrochemical cell increases the concentration of carbon dioxide in the residual waste gas and enables carbon dioxide recovery.
摘要翻译： 一种通过以下步骤制造氢的方法：将合成气混合物供给到变压吸附单元; 在变压吸附单元中从合成气体混合物产生氢气; 将其余的合成气混合物在低压下供给到电化学电池，其中氢与合成气混合物的其余部分分离并同时加压; 将来自电化学电池的加压氢供给到在变压吸附单元中产生的氢气并回收组合的氢气产物。 合成气混合物可以来自重整单元，并且它可能经历水煤气变换反应。 除了生产氢气之外，电化学电池中的氢气分离会增加残余废气中的二氧化碳浓度，并能使二氧化碳回收。
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公开(公告)号：US08128736B2
公开(公告)日：2012-03-06
申请号：US12539117
申请日：2009-08-11
摘要： A method for producing carbon dioxide by the steps of feeding a CO2-rich feed stream containing fuel gas to an oxygenated oxygen-selective ceramic bed to produce a product stream of carbon dioxide, water, and residual oxygen; adding oxygen to this product stream and feeding to an oxygen-depleted oxygen-selective ceramic bed and recovering carbon dioxide substantially free of oxygen and fuel gas. In an additional embodiment, nitrogen oxides are also removed from the fuel gas.
摘要翻译： 通过以下步骤生产二氧化碳的方法：将含有燃料气体的富CO 2进料流供给到氧化氧选择性陶瓷床中以产生二氧化碳，水和残留氧的产物流; 向该产物流中加入氧气并进料至贫氧氧选择性陶瓷床并回收基本上不含氧气和燃料气体的二氧化碳。 在另外的实施方案中，氮氧化物也从燃料气体中除去。
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公开(公告)号：US06761838B2
公开(公告)日：2004-07-13
申请号：US09909622
申请日：2001-07-20
IPC分类号： C07C102
CPC分类号： C07D301/22 , C01B3/36 , C01B3/386 , C01B13/0251 , C01B13/0255 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/0811 , C01B2203/0844 , C01B2203/085 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/82 , C01B2210/0046 , C07C17/154 , C07C17/156 , C07C45/33 , C07C45/34 , C07C45/35 , C07C253/24 , C07C253/26 , C07D301/04 , C07C19/045 , C07C21/06 , C07C47/22 , C07C47/06 , C07C255/08
摘要： Partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide is carried out by a cyclical process, which includes (a) contacting an oxygen ion conducting ceramic with air at a pressure between about 1 and 50 bara in a reactor, wherein oxygen from the air reacts with the ceramic, thereby producing an oxygen-enriched ceramic, and (b) contacting the hot, oxygen-enriched ceramic with hydrocarbon gas and optionally steam in the reactor. During the partial oxidation reaction phase of the process, the oxygen-enriched ceramic reacts with the hydrocarbon, thereby producing the desired gas products and regenerating the oxygen ion conducting ceramic for the next cycle of the process.
摘要翻译： 通过循环过程进行烃的部分氧化，其包括（a）在反应器中使氧离子导电陶瓷与空气在约1至50巴之间的压力下接触，其中来自空气的氧反应 与陶瓷一起生产富氧陶瓷，和（b）使热的富氧陶瓷与烃气体和任选的蒸汽在反应器中接触。 在该方法的部分氧化反应阶段期间，富氧陶瓷与烃反应，从而产生所需的气体产物并再生氧离子传导陶瓷用于下一循环过程。
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公开(公告)号：US07624770B2
公开(公告)日：2009-12-01
申请号：US11234431
申请日：2005-09-23
申请人： Robert Walter Boyd , David Grant Wardle , Kelly R. Leitch , Satish S. Tamhankar , Gary Peter Lomas
发明人： Robert Walter Boyd , David Grant Wardle , Kelly R. Leitch , Satish S. Tamhankar , Gary Peter Lomas
CPC分类号： F17C5/007 , F17C2205/0142 , F17C2221/012 , F17C2223/0123 , F17C2223/035 , F17C2223/036 , F17C2225/0123 , F17C2225/036 , F17C2227/0157 , F17C2227/043 , F17C2250/032 , F17C2250/034 , F17C2270/0139 , F17C2270/0178 , Y02E60/321
摘要： Multi compressor systems and apparatuses for the manufacture, storage and dispensing of manufactured hydrogen fuel to hydrogen vehicle tanks or remote mobile refuelers are disclosed.
摘要翻译： 公开了用于制造，储存和分配制氢氢燃料到氢气车辆罐或远程移动加油机的多压缩机系统和装置。
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