公开(公告)号：US09138964B2

公开(公告)日：2015-09-22

申请号：US13988450

申请日：2011-11-22

申请人： Shinichi Obata ,  Shinya Hiraoka ,  Fumiaki Hosokoshi ,  Ayumu Tateoka ,  Hideaki Matsushima ,  Koichi Miyake ,  Sakiko Tomonaga ,  Tomoyuki Maeda

发明人： Shinichi Obata ,  Shinya Hiraoka ,  Fumiaki Hosokoshi ,  Ayumu Tateoka ,  Hideaki Matsushima ,  Koichi Miyake ,  Sakiko Tomonaga ,  Tomoyuki Maeda

IPC分类号： C23C2/02 ,  B32B15/01 ,  C23C28/00 ,  C25D5/10 ,  C25D7/06 ,  H05K1/09 ,  H01B1/02 ,  C25D1/04 ,  C25D3/56 ,  C25D5/48 ,  C25D11/38

CPC分类号： B32B15/01 ,  C23C2/02 ,  C23C28/00 ,  C23C28/30 ,  C23C28/321 ,  C23C28/324 ,  C23C28/3455 ,  C25D1/04 ,  C25D3/565 ,  C25D5/10 ,  C25D5/48 ,  C25D7/0614 ,  C25D11/38 ,  H01B1/026 ,  H05K1/09 ,  H05K2201/0355 ,  Y10T428/12438 ,  Y10T428/12472 ,  Y10T428/12792

摘要： An object of the present invention is to provide a copper foil excellent in softening resistance performance which reduces decrease in tensile strength after heat treatment at about 350° C. to 400° C. In order to achieve the object, a surface-treated copper foil provided with a rust-proofing treatment layer on both surfaces of a copper foil in which a rust-proofing treatment layer is constituted by zinc alloy, and the either rust-proofing treatment layer is a zinc alloy layer having zinc amount of 20 mg/m2 to 1,000 mg/m2; and the copper foil contains one or two or more of small amount elements selected from carbon, sulfur, chlorine and nitrogen, and a sum amount thereof is 100 ppm or more is adopted.

摘要翻译： 本发明的目的是提供一种耐软化性能优异的铜箔，其在约350℃〜400℃下热处理后的抗拉强度降低。为了达到上述目的，将表面处理铜箔 在由铜合金构成的防锈处理层的铜箔的两面上设有防锈处理层，防锈处理层为锌量为20mg / m 2的锌合金层 至1,000 mg / m2; 铜箔含有一种或两种以上选自碳​​，硫，氯和氮的少量元素，其总量为100ppm以上。

公开(公告)号：US20130295407A1

公开(公告)日：2013-11-07

申请号：US13988450

申请日：2011-11-22

申请人： Shinichi Obata ,  Shinya Hiraoka ,  Fumiaki Hosokoshi ,  Ayumu Tateoka ,  Hideaki Matsushima ,  Koichi Miyake ,  Sakiko Tomonaga ,  Tomoyuki Maeda

发明人： Shinichi Obata ,  Shinya Hiraoka ,  Fumiaki Hosokoshi ,  Ayumu Tateoka ,  Hideaki Matsushima ,  Koichi Miyake ,  Sakiko Tomonaga ,  Tomoyuki Maeda

IPC分类号： H01B1/02

CPC分类号： B32B15/01 ,  C23C2/02 ,  C23C28/00 ,  C23C28/30 ,  C23C28/321 ,  C23C28/324 ,  C23C28/3455 ,  C25D1/04 ,  C25D3/565 ,  C25D5/10 ,  C25D5/48 ,  C25D7/0614 ,  C25D11/38 ,  H01B1/026 ,  H05K1/09 ,  H05K2201/0355 ,  Y10T428/12438 ,  Y10T428/12472 ,  Y10T428/12792

摘要： An object of the present invention is to provide a copper foil excellent in softening resistance performance which reduces decrease in tensile strength after heat treatment at about 350° C. to 400° C. In order to achieve the object, a surface-treated copper foil provided with a rust-proofing treatment layer on both surfaces of a copper foil in which a rust-proofing treatment layer is constituted by zinc alloy, and the either rust-proofing treatment layer is a zinc alloy layer having zinc amount of 20 mg/m2 to 1,000 mg/m2; and the copper foil contains one or two or more of small amount elements selected from carbon, sulfur, chlorine and nitrogen, and a sum amount thereof is 100 ppm or more is adopted.

摘要翻译： 本发明的目的是提供一种耐软化性能优异的铜箔，其在约350℃〜400℃下热处理后的抗拉强度降低。为了达到上述目的，将表面处理铜箔 在由铜合金构成的防锈处理层的铜箔的两面上设有防锈处理层，防锈处理层为锌量为20mg / m 2的锌合金层 至1,000 mg / m2; 铜箔含有一种或两种以上选自碳​​，硫，氯和氮的少量元素，其总量为100ppm以上。

公开(公告)号：US20130302635A1

公开(公告)日：2013-11-14

申请号：US13988236

申请日：2011-11-22

申请人： Shinichi Obata ,  Shinya Hiraoka ,  Fumiaki Hosokoshi ,  Ayumu Tateoka ,  Hideaki Matsushima ,  Koichi Miyake ,  Sakiko Tomonaga ,  Tomoyuki Maeda

发明人： Shinichi Obata ,  Shinya Hiraoka ,  Fumiaki Hosokoshi ,  Ayumu Tateoka ,  Hideaki Matsushima ,  Koichi Miyake ,  Sakiko Tomonaga ,  Tomoyuki Maeda

IPC分类号： B32B15/01

CPC分类号： B32B15/01 ,  C23C2/02 ,  C23C28/00 ,  C23C28/30 ,  C23C28/321 ,  C23C28/324 ,  C23C28/3455 ,  C25D1/04 ,  C25D3/565 ,  C25D5/10 ,  C25D5/48 ,  C25D7/0614 ,  C25D11/38 ,  H01B1/026 ,  H05K1/09 ,  H05K2201/0355 ,  Y10T428/12438 ,  Y10T428/12472 ,  Y10T428/12792

摘要： An object of the present invention is to provide a copper foil excellent in softening resistance performance which reduces decrease in tensile strength after heat treatment at about 350° C. to 400° C. In order to achieve the object, a surface-treated copper foil provided with a rust-proofing treatment layer on both surfaces of a copper foil in which a rust-proofing treatment layer is constituted by zinc, and the either rust-proofing treatment layer is a zinc layer having zinc amount of 20 mg/m2 to 1,000 mg/m2; and the copper foil contains one or two or more of small amount elements selected from carbon, sulfur, chlorine and nitrogen, and a sum amount thereof is 100 ppm or more is adopted.

摘要翻译： 本发明的目的是提供一种耐软化性能优异的铜箔，其在约350℃〜400℃下热处理后的抗拉强度降低。为了达到上述目的，将表面处理铜箔 在由铜构成的防锈处理层的铜箔的两面上设有防锈处理层，任一防锈处理层为锌量为20mg / m 2〜1000的锌层 mg / m2; 铜箔含有一种或两种以上选自碳​​，硫，氯和氮的少量元素，其总量为100ppm以上。

公开(公告)号：US20130288122A1

公开(公告)日：2013-10-31

申请号：US13885540

申请日：2011-11-08

申请人： Hideaki Matsushima ,  Sakiko Tomonaga ,  Koichi Miyake

发明人： Hideaki Matsushima ,  Sakiko Tomonaga ,  Koichi Miyake

IPC分类号： H01M4/66 ,  H01M4/04

CPC分类号： H01M4/661 ,  H01M4/04 ,  H01M4/13 ,  H01M10/0525 ,  Y10T29/49108

摘要： A copper foil for a negative electrode current collector of a lithium ion secondary battery enables prevention of deformation of the current collector even if the charge/discharge operation is repeatedly carried out. In a copper foil for a negative electrode current collector of a lithium ion secondary battery, a 10 mm wide test specimen composed of the copper foil is subjected to a tensile test, a maximum strain loaded on the copper foil is 30 N or higher in a region where “Value L” represented by the following expression is 0.8 or more in a strain-stress curve obtained in the tensile test where O is the starting point of the curve, PQ is the load at a point Q on the curve and EQ is an elongation at a point Q on the curve Value   L = ( area   of   triangle   OQE Q ) ( area   of   region   OQE Q )   …  ( 1 )

摘要翻译： 即使重复执行充放电操作，锂离子二次电池的负极集电体用铜箔也能够防止集电体的变形。 在锂离子二次电池的负极集电体用铜箔中，将由铜箔构成的10mm宽的试验片进行拉伸试验，在铜箔上载入的最大应变为30N以上 在拉伸试验中得到的应变应变曲线中，由下式表示的“值L”为0.8以上的区域，其中O为曲线起始点，PQ为曲线上点Q的载荷，EQ为 曲线上的点Q处的伸长值L ofQ Q Q Q Q Q Q Q（（（（（（（（（1）

公开(公告)号：US08419920B2

公开(公告)日：2013-04-16

申请号：US12444020

申请日：2007-10-02

申请人： Sakiko Tomonaga ,  Makoto Dobashi ,  Junshi Yoshioka ,  Ayumu Tateoka ,  Mitsuyoshi Matsuda ,  Hisao Sakai

发明人： Sakiko Tomonaga ,  Makoto Dobashi ,  Junshi Yoshioka ,  Ayumu Tateoka ,  Mitsuyoshi Matsuda ,  Hisao Sakai

IPC分类号： C25D3/38

CPC分类号： C25D3/38

摘要： An object of the present invention is to provide a method for preparing a sulfuric acid base copper electrolytic solution used for formation of an electro-deposited copper film comprising a surface excellent in smoothness and gloss when formed by using the solution just after preparation and is prepared by using mono-sulfides. To achieve the object, a sulfuric acid base copper electrolytic solution is made to contain a sulfonated active sulfur compound, the bis(3-sulfopropyl)disulfide which is recommended for formation of a glossy electro-deposited copper film. And the bis(3-sulfopropyl)disulfide contained is obtained by converting a 3-mercapto-1-propanesulfonic acid into the bis(3-sulfopropyl)disulfide in an aqueous solution of the 3-mercapto-1-propanesulfonic acid by an oxidation reaction. In the oxidation reaction, an air bubbling method is preferably used to prevent oxidative decomposition of the 3-mercapto-1-propanesulfonic acid.

摘要翻译： 本发明的目的是提供一种制备用于形成电沉积铜膜的硫酸基铜电解液的方法，该方法包括当刚制备后使用溶液形成时制备的平滑度和光泽度优异的表面，并且被制备 通过使用单硫化物。 为了实现该目的，制备硫酸基铜电解液以含有磺化活性硫化合物，推荐用于形成光滑电沉积铜膜的双（3-磺丙基）二硫化物。 通过氧化反应在3-巯基-1-丙磺酸的水溶液中将3-巯基-1-丙磺酸转化成双（3-磺丙基）二硫化物，得到所含的双（3-磺丙基）二硫化物 。 在氧化反应中，优选使用空气鼓泡法来防止3-巯基-1-丙磺酸的氧化分解。

公开(公告)号：US20100089758A1

公开(公告)日：2010-04-15

申请号：US12444020

申请日：2007-10-02

申请人： Sakiko Tomonaga ,  Makoto Dobashi ,  Junshi Yoshioka ,  Ayumu Tateoka ,  Mitsuyoshi Matsuda ,  Hisao Sakai

发明人： Sakiko Tomonaga ,  Makoto Dobashi ,  Junshi Yoshioka ,  Ayumu Tateoka ,  Mitsuyoshi Matsuda ,  Hisao Sakai

IPC分类号： C25D3/38 ,  C25D7/00

CPC分类号： C25D3/38

摘要： An object of the present invention is to provide a method for preparing a sulfuric acid base copper electrolytic solution used for formation of an electro-deposited copper film comprising a surface excellent in smoothness and gloss when formed by using the solution just after preparation and is prepared by using mono-sulfides. To achieve the object, a sulfuric acid base copper electrolytic solution is made to contain a sulfonated active sulfur compound, the bis(3-sulfopropyl)disulfide which is recommended for formation of a glossy electro-deposited copper film. And the bis(3-sulfopropyl)disulfide contained is obtained by converting a 3-mercapto-1-propanesulfonic acid into the bis(3-sulfopropyl)disulfide in an aqueous solution of the 3-mercapto-1-propanesulfonic acid by an oxidation reaction. In the oxidation reaction, an air bubbling method is preferably used to prevent oxidative decomposition of the 3-mercapto-1-propanesulfonic acid.

摘要翻译： 本发明的目的是提供一种制备用于形成电沉积铜膜的硫酸基铜电解液的方法，该方法包括当刚制备后使用溶液形成时制备的平滑度和光泽度优异的表面，并且被制备 通过使用单硫化物。 为了实现该目的，制备硫酸基铜电解液以含有磺化活性硫化合物，推荐用于形成光滑电沉积铜膜的双（3-磺丙基）二硫化物。 通过氧化反应在3-巯基-1-丙磺酸的水溶液中将3-巯基-1-丙磺酸转化成双（3-磺丙基）二硫化物，得到所含的双（3-磺丙基）二硫化物 。 在氧化反应中，优选使用空气鼓泡法来防止3-巯基-1-丙磺酸的氧化分解。

公开(公告)号：US20090166213A1

公开(公告)日：2009-07-02

申请号：US12089671

申请日：2006-10-31

申请人： Makoto Dobashi ,  Mitsuyoshi Matsuda ,  Sakiko Tomonaga ,  Hisao Sakai ,  Tomohiro Sakata ,  Ayumu Tateoka ,  Hiroshi Hata ,  Satoshi Mogi ,  Takeo Taguchi ,  Junshi Yoshioka

发明人： Makoto Dobashi ,  Mitsuyoshi Matsuda ,  Sakiko Tomonaga ,  Hisao Sakai ,  Tomohiro Sakata ,  Ayumu Tateoka ,  Hiroshi Hata ,  Satoshi Mogi ,  Takeo Taguchi ,  Junshi Yoshioka

IPC分类号： C25D3/38 ,  B32B15/04

CPC分类号： C25D3/38 ,  C25D1/04 ,  H05K1/09

摘要： An object of the present invention is to provide a production method which enables efficient production of an electro-deposited copper foil with further lower profile when compared to the low-profile electro-deposited copper foils which have been supplied to the market and is excellent in mechanical strength. For the purpose of achieving the object, a production method adopted obtains the electro-deposited copper foil by electrolyzing a sulfuric acid based copper electrolytic solution which contains a quaternary ammonium salt polymer having cyclic structure and chlorine, wherein for the quaternary ammonium salt polymer contained in the sulfuric acid based copper electrolytic solution, a DDAC dimer or higher polymer is used. For the quaternary ammonium salt polymer, a diallyl dimethyl ammonium chloride polymer having a number average molecular weight of 300 to 10000 is preferably used. The sulfuric acid based copper electrolytic solution preferably contains bis(3-sulfopropyl) disulfide or 3-mercapto-1-propanesulfonic acid that is a compound having a mercapto group.

摘要翻译： 本发明的一个目的是提供一种制造方法，该方法能够与已经供应到市场上的薄型电镀铜箔相比具有更低的轮廓的电解铜箔的有效生产 机械强度。 为了实现该目的，所采用的制造方法是通过电解含有具有环状结构和氯的季铵盐聚合物的硫酸系铜电解液得到电解铜箔，其中，对于 使用硫酸类铜电解液，DDAC二聚体或更高级聚合物。 对于季铵盐聚合物，优选使用数均分子量为300〜10000的二烯丙基二甲基氯化铵聚合物。 硫酸系铜电解液优选含有作为具有巯基的化合物的双（3-磺丙基）二硫化物或3-巯基-1-丙磺酸。

公开(公告)号：US20140170489A1

公开(公告)日：2014-06-19

申请号：US14236689

申请日：2012-08-03

申请人： Hideaki Matsushima ,  Sakiko Tomonaga

发明人： Hideaki Matsushima ,  Sakiko Tomonaga

IPC分类号： H01M4/1395

CPC分类号： H01M4/1395 ,  H01M4/0404 ,  H01M4/133 ,  H01M4/134 ,  H01M4/1393 ,  H01M4/364 ,  H01M4/386 ,  H01M4/387 ,  H01M4/587 ,  H01M4/661 ,  H01M4/662 ,  H01M4/667 ,  H01M10/052 ,  H01M2004/027

摘要： In manufacturing of a negative electrode material of a lithium ion secondary battery provided with a negative electrode mixture layer including a negative electrode active substance on a surface of a negative electrode current collector, one or mixture selected from granular materials alloyable with lithium and carbon materials for storing and releasing lithium is used as the negative electrode active substance; manufacturing method of a negative electrode material for a lithium ion secondary battery employed is characterized in that an electro-deposited copper foil in which a surface roughness (Ra) is 0.20 μm

摘要翻译： 在负极集电体的表面具有负极活性物质的负极混合层的锂离子二次电池的负极材料的制造中，选自与锂和碳材料合金化的粒状材料中的一种或混合物， 锂的存储和释放被用作负极活性物质; 所用的锂离子二次电池用负极材料的制造方法的特征在于，表面粗糙度（Ra）为0.20μm

公开(公告)号：US20140127569A1

公开(公告)日：2014-05-08

申请号：US14110778

申请日：2012-04-10

申请人： Tomoyuki Maeda ,  Sakiko Tomonaga ,  Yasunori Tabira

发明人： Tomoyuki Maeda ,  Sakiko Tomonaga ,  Yasunori Tabira

IPC分类号： H01M4/66

CPC分类号： H01M4/665 ,  C23C22/24 ,  C25D1/04 ,  C25D9/08 ,  C25D11/38 ,  H01M4/13 ,  H01M4/661 ,  H01M4/667 ,  H01M10/0525

摘要： An object of the present invention is to eliminate deviation in the quality of a chromate film provided on a copper foil for a negative electrode current collector to eliminate fluctuation of electric capacity in a lithium ion secondary battery.To achieve the object, as the copper foil for a negative electrode current collector of a lithium ion secondary battery, a copper foil provided with a chromate film for a negative electrode current collector in which Cr(OH)3 constitutes 85 area % or more of the chromate film is employed. Further, the copper foil provided with a chromate film for a negative electrode current collector according to the present application is preferable to be that the apparent orientation number N of oxygen closest to chrome in the chromate film is 4.5 or more.

摘要翻译： 本发明的目的是消除设置在负极集电体的铜箔上的铬酸盐膜的质量偏差，以消除锂离子二次电池中的电容的波动。 为了实现该目的，作为锂离子二次电池的负极集电体用铜箔，设置有负极集电体用铬酸盐膜的铜箔，其中Cr（OH）3的面积％以上为85面积％以上 使用铬酸盐膜。 此外，根据本申请的设置有负极集电体的铬酸盐膜的铜箔优选为铬酸盐膜中最接近铬的氧的表观取向数N为4.5以上。

公开(公告)号：US20130306486A1

公开(公告)日：2013-11-21

申请号：US13807091

申请日：2011-06-29

申请人： Tomoyuki Maeda ,  Satoshi Torikai ,  Tetsuya Kaneko ,  Yusuke Ozaki ,  Sakiko Tomonaga

发明人： Tomoyuki Maeda ,  Satoshi Torikai ,  Tetsuya Kaneko ,  Yusuke Ozaki ,  Sakiko Tomonaga

IPC分类号： H01M4/04

CPC分类号： H01M4/0452 ,  C23C22/24 ,  C23C22/68 ,  C25D1/04 ,  C25D7/0614 ,  C25D9/08 ,  H01M4/661 ,  H01M4/667 ,  H01M10/0525

摘要： An object of the present invention is to provide a method for manufacturing a copper foil for a negative electrode current collector (specifically, copper foil for a negative electrode current collector of a lithium ion secondary battery) more excellent in discoloration resistance to improve charge/discharge cycle life of a secondary battery. To achieve the object, a method for manufacturing a copper foil for a negative electrode current collector of a secondary battery subjecting the copper foil to rust-proofing treatment, the method characterized in that the copper foil is rust-proofing treated with a chromate-treatment solution having pH in the range from 3.5 to 7.0 to form a chromate film on the surface of the copper foil is employed.

摘要翻译： 本发明的目的是提供一种用于制造耐变色性优异的负极集电体（特别是锂离子二次电池用负极集电体用铜箔）的铜箔的制造方法，以提高充放电性 二次电池的循环寿命。 为了实现该目的，提供了一种用于制造用于对铜箔进行防锈处理的二次电池的负极集电体的铜箔的方法，其特征在于，所述铜箔用铬酸盐处理进行防锈处理 使用pH为3.5〜7.0的溶液，在铜箔的表面形成铬酸盐膜。