公开(公告)号：US10076773B2

公开(公告)日：2018-09-18

申请号：US13817218

申请日：2011-08-12

申请人： Shinya Takahashi ,  Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

发明人： Shinya Takahashi ,  Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

IPC分类号： B08B3/08 ,  B08B3/10 ,  B08B9/08 ,  B08B3/04 ,  C10G1/06 ,  C10G47/22 ,  C10G47/00 ,  C10G21/12 ,  C10G47/36 ,  C10G2/00 ,  B01J38/52 ,  B01J38/56

CPC分类号： B08B3/04 ,  B01J38/52 ,  B01J38/56 ,  B08B9/08 ,  C10G1/06 ,  C10G2/32 ,  C10G21/12 ,  C10G47/00 ,  C10G47/22 ,  C10G47/36 ,  C10G2300/1014 ,  C10G2300/1022 ,  C10G2300/4031 ,  C10G2300/44 ,  Y02P30/20

摘要： The method for cleaning a reactor of the present invention comprises passing a solvent through a wax-fraction hydrocracking apparatus which is charged with a catalyst and to which supply of a wax fraction is stopped, wherein the solvent comprising at least one oil selected from a group consisting of hydrocarbon and vegetable oils, and having a sulfur content of less than 5 ppm and being in a liquid state at 15° C.

公开(公告)号：US20130146088A1

公开(公告)日：2013-06-13

申请号：US13817218

申请日：2011-08-12

申请人： Shinya Takahashi ,  Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

发明人： Shinya Takahashi ,  Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

IPC分类号： B08B3/04

CPC分类号： B08B3/04 ,  B01J38/52 ,  B01J38/56 ,  B08B9/08 ,  C10G1/06 ,  C10G2/32 ,  C10G21/12 ,  C10G47/00 ,  C10G47/22 ,  C10G47/36 ,  C10G2300/1014 ,  C10G2300/1022 ,  C10G2300/4031 ,  C10G2300/44 ,  Y02P30/20

摘要： The method for cleaning a reactor of the present invention comprises passing a solvent through a wax-fraction hydrocracking apparatus which is charged with a catalyst and to which supply of a wax fraction is stopped, wherein the solvent comprising at least one oil selected from a group consisting of hydrocarbon and vegetable oils, and having a sulfur content of less than 5 ppm and being in a liquid state at 15° C.

摘要翻译： 本发明的清洁反应器的方法包括使溶剂通过装有催化剂的蜡馏分加氢裂化装置，并停止供应蜡馏分，其中所述溶剂包含至少一种选自下组的油： 由烃和植物油组成，硫含量小于5ppm，在15℃处于液态。

公开(公告)号：US20130144099A1

公开(公告)日：2013-06-06

申请号：US13817182

申请日：2011-08-12

申请人： Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

发明人： Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

IPC分类号： C10G67/00

CPC分类号： C10G67/02 ,  C10G2/00 ,  C10G2/342 ,  C10G3/56 ,  C10G31/00 ,  C10G47/00 ,  C10G65/18 ,  C10G67/00 ,  C10G67/16 ,  C10G2300/1022 ,  C10G2300/208 ,  Y02P30/20

摘要： Hydrocarbon oil obtained by Fischer-Tropsch (FT) synthesis reaction using a catalyst within a slurry bed reactor is fractionated into a distilled oil and a column bottom oil in a rectifying column, part of the column bottom oil is flowed into a first transfer line that connects a column bottom of the rectifying column to a hydrocracker, at least part of the column bottom oil is flowed into a second transfer line branched from the first transfer line and connected to the first transfer line downstream of the branching point, the amount of the catalyst fine powder to be captured is monitored while the catalyst fine powder in the column bottom oil that flows in the second transfer line are captured by a detachable filter provided in the second transfer line, and the column bottom oil is hydrocracked within the hydrocracker.

摘要翻译： 通过使用在淤浆床反应器内的催化剂的费 - 托（FT）合成反应获得的烃油被分馏成精馏塔中的蒸馏油和塔底油，部分塔底油流入第一输送管线， 将精馏塔的塔底连接到加氢裂化器，至少部分塔底油流入从第一输送管线分支并与分支点下游的第一输送管线连接的第二输送管线， 监测待捕获的催化剂细粉末，同时通过设置在第二输送管线中的可拆卸过滤器捕集在第二输送管线中流动的塔底油中的催化剂细粉末，并将塔底油在加氢裂化器内加氢裂化。

公开(公告)号：US09475036B2

公开(公告)日：2016-10-25

申请号：US14008246

申请日：2012-03-26

申请人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

发明人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

IPC分类号： C10G45/64 ,  B01J23/42 ,  C10G45/62 ,  C10G45/60 ,  C10G45/70 ,  C10G11/18 ,  B01J37/08 ,  B01J21/06 ,  B01J21/12 ,  B01J21/18 ,  B01J37/00 ,  B01J37/02

CPC分类号： B01J23/42 ,  B01J21/066 ,  B01J21/12 ,  B01J21/18 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/084 ,  B01J37/088 ,  C10G11/18 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/70 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： The hydrotreating catalyst of the present invention is a hydrotreating catalyst including a catalyst support including an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrotreating catalyst contains a carbonaceous substance including a carbon atom, and the content of the carbonaceous substance in the hydrotreating catalyst is 0.05 to 1% by mass in terms of the carbon atom.

摘要翻译： 本发明的加氢处理催化剂是包含催化剂载体的加氢处理催化剂，所述催化剂载体包括具有固体酸度的无定形复合金属氧化物，以及至少一种由催化剂载体担载的活性金属，并且选自周期表中第8〜10族的贵金属 表格，其中加氢处理催化剂含有包含碳原子的碳质物质，加氢处理催化剂中的碳质物质的含量相对于碳原子为0.05〜1质量％。

公开(公告)号：US09266099B2

公开(公告)日：2016-02-23

申请号：US14008149

申请日：2012-03-26

申请人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

发明人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

IPC分类号： B01J38/02 ,  B01J29/12 ,  B01J29/90 ,  B01J38/04 ,  B01J38/12 ,  B01J38/56 ,  C10G47/18

CPC分类号： B01J29/126 ,  B01J29/90 ,  B01J38/04 ,  B01J38/12 ,  B01J38/56 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/18 ,  C10G2300/1022

摘要： The regenerated hydrocracking catalyst according to the present invention is a regenerated hydrocracking catalyst prepared by regenerating a used hydrocracking catalyst including: a catalyst support containing zeolite and an amorphous composite metal oxide having solid acidity; and at least one active metal supported by the catalyst support, selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the regenerated hydrocracking catalyst contains 0.05 to 1% by mass of a carbonaceous substance in terms of carbon atoms based on the entire mass of the catalyst.

摘要翻译： 根据本发明的再生加氢裂化催化剂是通过再生使用的加氢裂化催化剂制备的再生加氢裂化催化剂，其包括：含有沸石的催化剂载体和具有固体酸度的无定形复合金属氧化物; 和至少一种由催化剂载体担载的活性金属，选自元素周期表第8〜10族的贵金属，其中再生加氢裂化催化剂含有0.05〜1质量％的以碳原子计的碳质物质，基于 整个催化剂的质量。

公开(公告)号：US20140326642A1

公开(公告)日：2014-11-06

申请号：US14008246

申请日：2012-03-26

申请人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

发明人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

IPC分类号： B01J23/42 ,  C10G45/64 ,  C10G45/62

CPC分类号： B01J23/42 ,  B01J21/066 ,  B01J21/12 ,  B01J21/18 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/084 ,  B01J37/088 ,  C10G11/18 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/70 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： The hydrotreating catalyst of the present invention is a hydrotreating catalyst including a catalyst support including an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrotreating catalyst contains a carbonaceous substance including a carbon atom, and the content of the carbonaceous substance in the hydrotreating catalyst is 0.05 to 1% by mass in terms of the carbon atom.

摘要翻译： 本发明的加氢处理催化剂是包含催化剂载体的加氢处理催化剂，所述催化剂载体包括具有固体酸度的无定形复合金属氧化物，以及至少一种由催化剂载体担载的活性金属，并且选自周期表中第8〜10族的贵金属 表格，其中加氢处理催化剂含有包含碳原子的碳质物质，加氢处理催化剂中的碳质物质的含量相对于碳原子为0.05〜1质量％。

公开(公告)号：US20140076782A1

公开(公告)日：2014-03-20

申请号：US14008172

申请日：2012-03-26

申请人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

发明人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

IPC分类号： C10G47/14 ,  B01J23/42

CPC分类号： C10G47/14 ,  B01J23/42 ,  B01J23/96 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0063 ,  B01J38/02 ,  B01J38/04 ,  B01J38/12 ,  C10G11/18 ,  C10G45/60 ,  C10G45/70 ,  C10G47/18 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： The regenerated hydrotreating catalyst of the present invention is a regenerated hydrotreating catalyst prepared by regenerating a used hydrotreating catalyst comprising a catalyst support including an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the regenerated hydrotreating catalyst contains 0.05 to 1% by mass of a carbonaceous substance in terms of a carbon atom based on the entire mass of the catalyst.

摘要翻译： 本发明的再生加氢处理催化剂是一种再生加氢处理催化剂，其是通过再生含有催化剂载体的加氢处理催化剂制备的，所述催化剂载体包括具有固体酸度的非晶形复合金属氧化物，以及至少一种由催化剂载体担载的活性金属，并选自贵金属 的第8〜第10组，其中再生加氢精制催化剂以碳原子计含有0.05〜1质量％的碳质，基于催化剂的总质量。

公开(公告)号：US20130143971A1

公开(公告)日：2013-06-06

申请号：US13817247

申请日：2011-08-12

申请人： Marie Iwama ,  Kazuhiko Tasaka ,  Yuichi Tanaka

发明人： Marie Iwama ,  Kazuhiko Tasaka ,  Yuichi Tanaka

IPC分类号： C07C1/04

CPC分类号： B01D3/009 ,  B01J8/007 ,  B01J8/22 ,  C07C1/04 ,  C10G2/00 ,  C10G2/342 ,  C10G31/00 ,  C10G47/00 ,  C10G2300/208

摘要： Hydrocarbon oil obtained by Fischer-Tropsch synthesis reaction using a slurry bed reactor holding a slurry of a liquid hydrocarbon in which a catalyst is suspended; the hydrocarbon oil is fractionated into a distilled oil and a column bottom oil containing the catalyst fine powder by a rectifying column; at least part of the column bottom oil is transferred to a storage tank, and the catalyst fine powder is sedimented to the bottom of the storage tank to capture the catalyst fine powder; a residue of the column bottom oil is transferred from the rectifying column to a hydrocracker, and/or the supernatant of the column bottom oil from which the catalyst fine powder is captured by the storage tank is transferred from the storage tank to the hydrocracker; and using the hydrocracker, the residue of the column bottom oil and/or the supernatant of the column bottom oil is hydrocracked.

摘要翻译： 通过费托合成反应获得的烃油，其使用保持催化剂悬浮的液态烃的淤浆的淤浆床反应器; 将烃油通过精馏塔分馏成蒸馏油和含有催化剂细粉末的塔底油; 将塔底油的至少一部分转移到储罐中，并将催化剂细粉沉淀到储罐的底部以捕获催化剂细粉; 柱底油的残渣从精馏塔转移至加氢裂化器，和/或由储罐捕获催化剂细粉末的塔底油的上清液从储罐转移至加氢裂化器; 并使用加氢裂化器，将柱底油的残余物和/或塔底油的上清液加氢裂化。

公开(公告)号：US20120168349A1

公开(公告)日：2012-07-05

申请号：US13395264

申请日：2010-09-14

申请人： Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

发明人： Kazuhiko Tasaka ,  Yuichi Tanaka ,  Marie Iwama

IPC分类号： C10G49/22

CPC分类号： C10G47/36 ,  C10G2/30 ,  C10G2/32 ,  C10G7/00 ,  C10G2300/1022 ,  C10G2300/301

摘要： A hydrocracking process that includes a wax fraction hydrocracking step of hydrocracking the wax fraction contained within a Fischer-Tropsch synthetic oil to obtain a hydrocracked product, a gas-liquid separation step of using a multi-stage gas-liquid separator to separate the hydrocracked product into a gas component, a heavy oil component and a light oil component, a specific component content estimation step of determining the flow rate ratio between the heavy oil component and the light oil component, and using this flow rate ratio to determine an estimated value for the content of a specific hydrocarbon component contained within the hydrocracked product, and a control step of controlling the operation of the wax fraction hydrocracking step on the basis of this estimated value, so that the content of the specific hydrocarbon component falls within a predetermined range.

摘要翻译： 一种加氢裂化方法，其包括将费 - 托合成油中所含的蜡馏分加氢裂解以获得加氢裂化产物的蜡馏分加氢裂化步骤，使用多级气 - 液分离器分离加氢裂化产物的气液分离步骤 进入气体成分，重油成分和轻油成分，确定重油成分与轻油成分之间的流量比的特定成分含量估计步骤，使用该流量比确定估计值 加氢裂化产物中所含的特定烃成分的含量，以及基于该估计值控制蜡馏分加氢裂化工序的操作的控制工序，使特定烃成分的含量在规定范围内。

公开(公告)号：US09186658B2

公开(公告)日：2015-11-17

申请号：US14008164

申请日：2012-03-26

申请人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

发明人： Yuichi Tanaka ,  Takuya Niitsuma ,  Kazuhiko Tasaka ,  Marie Iwama

IPC分类号： B01J29/12 ,  C10G47/18 ,  C10G45/60 ,  C10G45/70 ,  C10G11/18 ,  B01J35/02 ,  B01J37/00 ,  C10G45/62 ,  C10G45/64

CPC分类号： B01J29/126 ,  B01J29/12 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0018 ,  B01J2229/24 ,  C10G11/18 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/70 ,  C10G47/18 ,  C10G2300/1048 ,  C10G2300/301 ,  C10G2400/30

摘要： The hydrocracking catalyst of the present invention is a hydrocracking catalyst comprising a catalyst support comprising a zeolite and an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrocracking catalyst contains a carbonaceous substance comprising a carbon atom, and the content of the carbonaceous substance in the hydrocracking catalyst is 0.05 to 1% by mass in terms of the carbon atom.

摘要翻译： 本发明的加氢裂化催化剂是包含催化剂载体的加氢裂化催化剂，该催化剂载体包含沸石和具有固体酸度的无定形复合金属氧化物，以及至少一种由催化剂载体负载的活性金属，并选自第8〜10族的贵金属 在周期表中，其中加氢裂化催化剂含有碳原子的碳质物质，加氢裂化催化剂中的碳质物质的含量相对于碳原子为0.05〜1质量％。