公开(公告)号：US5397814A

公开(公告)日：1995-03-14

申请号：US57387

申请日：1993-05-06

申请人： Shunji Aoki ,  Shinji Irifune ,  Takafumi Sakamoto

发明人： Shunji Aoki ,  Shinji Irifune ,  Takafumi Sakamoto

IPC分类号： B29C33/64 ,  C07F7/08 ,  C08F2/46 ,  C08G77/20 ,  C08K5/00 ,  C08K5/5419 ,  C08L83/04 ,  C09D4/00 ,  C09D183/06 ,  C08F130/08

CPC分类号： C09D183/06 ,  C08G77/20 ,  C09D4/00 ,  Y10T428/31663

摘要： A radiation-curable, releasing silicone composition which comprises an organopolysiloxane having methacrylic or acrylic functional groups and represented by the following general formula ##STR1## In the formula, A represents a monovalent hydrocarbon group having a methacrylic or acrylic moiety, R's independently represent an unsubstituted or substituted monovalent organic group, a is an integer of 1, 2 or 3, b is an integer of 2 or 3, and n is an integer of 1 or over. The organopolysiloxane has a viscosity of from 50 to 2,000 cps., at 25.degree. C. The composition exhibits good releasing properties with respect to self-adhesives.

摘要翻译： 一种可辐射固化的，释放的硅氧烷组合物，其包含具有甲基丙烯酸或丙烯酸官能团并由以下通式表示的有机聚硅氧烷。在该式中，A表示具有甲基丙烯酸或丙烯酸部分的一价烃基，R独立地表示未取代的 或取代的一价有机基团，a为1,2或3的整数，b为2或3的整数，n为1以上的整数。 有机聚硅氧烷在25℃下的粘度为50至2,000cps。组合物相对于自粘合剂显示出良好的脱模性能。

公开(公告)号：US08754174B2

公开(公告)日：2014-06-17

申请号：US13197962

申请日：2011-08-04

申请人： Shunji Aoki

发明人： Shunji Aoki

IPC分类号： C08G77/08

CPC分类号： C09J183/04 ,  C08G77/04 ,  C08G77/12 ,  C08G77/20 ,  C08L83/00 ,  C08L2666/52 ,  Y10T428/265

摘要： A solventless addition-curable pressure sensitive silicone adhesive composition is provided. The composition comprises (A) an alkenyl group-containing polydiorganosiloxane; (B) a condensation product of (a) a polydiorganosiloxane having hydroxyl group or an alkoxy group on opposite ends of the molecular chain and (b) a polyorganosiloxane containing R13SiO1/2 unit and SiO2 unit as critical components and also a HOSiO3/2 unit in the molecule; (C1) a polyorganohydrosiloxane having at least three SiH groups per molecule; (C2) a polydiorganohydrosiloxane having SiH group on opposite ends; and (D) a platinum group metal catalyst. Use of the present composition enables production of a pressure sensitive adhesive agent having flexibility, pressure sensitive adhesiveness, and heat resistance, and the present composition is particularly effective for use as a buffer member having pressure sensitive adhesiveness.

摘要翻译： 提供无溶剂的可加成固化的压敏硅酮粘合剂组合物。 该组合物包含（A）含烯基的聚二有机硅氧烷; （B）（a）在分子链的相对端具有羟基或烷氧基的聚二有机硅氧烷和（b）含有R 13 SiO 1/2单元和SiO 2单元的聚有机硅氧烷作为关键组分的缩合产物，以及HOSiO3 / 2单元 在分子中 （C1）每分子具有至少三个SiH基团的聚有机氢硅氧烷; （C2）在其两端具有SiH基的聚二氢代氢硅氧烷; 和（D）铂族金属催化剂。 通过使用本发明的组合物，能够制造具有柔软性，压敏粘合性和耐热性的压敏粘合剂，本发明的组合物特别有效地用作具有压敏粘合性的缓冲部件。

公开(公告)号：US20050079450A1

公开(公告)日：2005-04-14

申请号：US10926085

申请日：2004-08-26

申请人： Masayuki Yoshida ,  Junichi Sutoh ,  Shunji Aoki ,  Genichi Watanabe

发明人： Masayuki Yoshida ,  Junichi Sutoh ,  Shunji Aoki ,  Genichi Watanabe

IPC分类号： H01F41/00 ,  G03F7/00 ,  G03F7/20 ,  H01F17/00 ,  H01F41/34 ,  H01G4/12 ,  H01G4/30 ,  H01G13/00 ,  H05K1/03 ,  H05K3/00 ,  H05K3/10 ,  H05K3/12 ,  H05K3/46

CPC分类号： H05K3/1258 ,  G03F7/20 ,  H05K1/0306 ,  H05K3/0023 ,  H05K3/0082 ,  H05K3/107 ,  H05K3/4614 ,  H05K3/4629 ,  H05K2201/0108 ,  H05K2201/09036 ,  H05K2203/016 ,  H05K2203/0514

摘要： There is provided a sheet used for manufacturing multilayer electronic parts in which accuracy in shape and formation position and uniformity in thickness of a complex configuration with recesses and projections of an insulating layer or the like are assured. A layer made of a photosensitive material containing a powder having a specific electric characteristic is formed on a light transmissive base member. A mask having a plurality of patterns with different transmittances for ultraviolet light is disposed on the back side of the base member. The photosensitive material is subjected to an exposure process in which it is irradiated with ultraviolet light or the like through the mask. The photosensitive material is subjected to development process after the exposure process.

摘要翻译： 提供了用于制造多层电子部件的片材，其中确保了具有绝缘层等的凹凸的复杂构造的形状和形成位置的精度以及厚度的均匀性。 在透光性基材上形成由含有电特性的粉末的感光材料构成的层。 具有多个紫外线透射率的图案的掩模设置在基底部件的背面上。 对感光材料进行通过掩模用紫外线等照射的曝光处理。 感光材料在曝光处理后进行显影处理。

公开(公告)号：US5405928A

公开(公告)日：1995-04-11

申请号：US205470

申请日：1994-03-04

申请人： Shunji Aoki

发明人： Shunji Aoki

IPC分类号： B01J31/08 ,  C07B61/00 ,  C07F7/08 ,  C07F7/21 ,  C08F30/08 ,  C08G77/08 ,  C08G77/20

CPC分类号： C07F7/0874 ,  C07F7/21 ,  C08G77/08 ,  C08G77/20

摘要： A method of preparing (meth)acryl group-containing organosiloxanes, wherein only the alkoxy group(s) of a (meth)acryl group-containing alkoxysilane compound is(are) selectively hydrolyzed using a cation exchange resin as acid catalyst.

摘要翻译： 一种制备（甲基）丙烯酰基的有机硅氧烷的方法，其中仅使用阳离子交换树脂作为酸催化剂选择性地水解含（甲基）丙烯酰基的烷氧基硅烷化合物的烷氧基。

公开(公告)号：US5190988A

公开(公告)日：1993-03-02

申请号：US706706

申请日：1991-05-29

申请人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara

发明人： Shunji Aoki ,  Toshio Ohba ,  Yasuaki Hara

IPC分类号： C08K5/42 ,  C08F2/50 ,  C08F4/08 ,  C08F290/00 ,  C08F299/08 ,  C08L83/04 ,  C08L83/06 ,  C08L83/07 ,  C09D183/06 ,  C09J183/00 ,  C09J183/07

CPC分类号： C09D183/06

摘要： The invention provides a high-sensitivity ultraviolet-curable organopolysiloxane composition suitable for use as a surface-release treatment of various substrate such as release-paper sheets and the like. The composition comprises, as the essential ingredients, (a) an organopolysiloxane having a viscosity in the range from 50 to 3000 centipoise at 25.degree. C. and containing, in a molecule, at least one (meth)acryloxy-substituted monovalent hydrocarbon group or at least one epoxy- or glycidyloxy-substituted monovalent hydrocarbon group, and (b) a sulfonate compound such as 2-hydroxy-3-oxy-2,3-diphenylpropyl methanesulfonate as the photopolymerization initiator. The sensitivity of the composition to photopolymerization can be further increased by the addition of a specific salt such as sodium hexafluoroantimonate and sodium hexafluorophosphate.

摘要翻译： 本发明提供一种适用于各种基材如脱模纸等的表面剥离处理的高灵敏度紫外线固化型有机基聚硅氧烷组合物。 该组合物包含作为必要成分的（a）在25℃下粘度为50-3000厘泊的有机聚硅氧烷，并且在一分子中含有至少一个（甲基）丙烯酰氧基取代的一价烃基或 至少一个环氧基或缩水甘油氧基取代的一价烃基，和（b）磺酸酯化合物如2-羟基-3-氧基-2,3-二苯基丙基甲磺酸酯作为光聚合引发剂。 通过加入特定的盐如六氟锑酸钠和六氟磷酸钠可以进一步提高组合物对光聚合的敏感性。

公开(公告)号：US09365746B2

公开(公告)日：2016-06-14

申请号：US13102193

申请日：2011-05-06

申请人： Kenji Yamamoto ,  Shunji Aoki

发明人： Kenji Yamamoto ,  Shunji Aoki

IPC分类号： C09D183/04 ,  C09J7/02 ,  C08G77/12 ,  C08G77/20

CPC分类号： C09J7/0228 ,  C08G77/12 ,  C08G77/20 ,  C09D183/04 ,  C09J7/401 ,  C09J2400/283 ,  C09J2483/005 ,  Y10T428/31663 ,  C08L83/00

摘要： An addition curing silicone composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an adhesion promoter, (C) an organohydrogenpolysiloxane, and (D) a platinum catalyst is suited for use in release paper or film. The adhesion promoter is a compound which contains per molecule at least one substituent group having a functional group capable of radical reaction upon exposure to heat and/or UV, and at least one substituent group having a group capable of reaction with alkenyl and/or SiH group.

摘要翻译： 一种加成固化硅氧烷组合物，其包含（A）含有至少两个烯基的有机聚硅氧烷，（B）粘合促进剂，（C）有机氢聚硅氧烷和（D）铂催化剂适用于剥离纸或膜。 粘合促进剂是每分子含有至少一个具有能够在暴露于热和/或UV时能够自由基反应的官能团的取代基的化合物，以及至少一个具有能够与烯基和/或SiH反应的基团的取代基 组。

公开(公告)号：US08206831B2

公开(公告)日：2012-06-26

申请号：US12477206

申请日：2009-06-03

申请人： Shunji Aoki

发明人： Shunji Aoki

IPC分类号： B32B7/12 ,  B32B9/04 ,  C08F283/12 ,  C08G77/12 ,  C08G77/20 ,  C08G77/04 ,  C08G77/16 ,  C08G77/398 ,  C08L83/04 ,  C08L83/05 ,  C08L83/06 ,  C08L83/07

CPC分类号： C09J183/04 ,  C08L83/00 ,  C08L2666/28 ,  C09J7/22 ,  C09J7/38 ,  C09J2483/00 ,  Y10T428/2852 ,  Y10T428/2857 ,  Y10T428/31663

摘要： This invention relates to a silicone pressure-sensitive adhesive composition including: (A) a polydiorganosiloxane composed of a linear polydiorganosiloxane (A1) having two or more alkenyl groups within each molecule and a linear polydiorganosiloxane (A2) having SiOH groups at terminals thereof and no alkenyl groups, which is represented by the formula R22(HO)SiO—(R22SiO)d—SiR22(OH), wherein d represents an integer satisfying 500≦d≦20,000; (B) a polyorganosiloxane including R33SiO1/2 units, SiO2 units and Si atom-bonded hydroxyl group-containing units; (C) a polyorganohydrogensiloxane having three or more SiH groups within each molecule; (D) a reaction retarder; (E) a platinum group metal-based catalyst; and (F) a metal compound represented by formula MYx, wherein the polyorganosiloxane (B) is condensed with the linear polydiorganosiloxane (A2). The composition exhibits powerful adhesive strength to silicone rubbers and is useful for, by example, producing a pressure-sensitive tape.

摘要翻译： 本发明涉及一种硅氧烷压敏粘合剂组合物，其包含：（A）由在每个分子内具有两个或更多个烯基的直链聚二有机硅氧烷（A1）组成的聚二有机硅氧烷和在其末端具有SiOH基团的直链聚二有机基硅氧烷（A2） 链烯基，其由式R22（HO）SiO-（R22SiO）d-SiR22（OH）表示，其中d表示满足500＆nlE的整数; d＆nlE; 20,000; （B）包含R33SiO1 / 2单元，SiO2单元和含Si原子键合的含羟基单元的聚有机硅氧烷; （C）在每个分子内具有三个或更多个SiH基团的聚有机氢硅氧烷; （D）反应缓凝剂; （E）铂族金属类催化剂; 和（F）由式MYx表示的金属化合物，其中聚有机硅氧烷（B）与线性聚二有机硅氧烷（A2）缩合。 该组合物对硅橡胶具有强大的粘合强度，并且例如可用于生产压敏胶带。

公开(公告)号：US07540931B2

公开(公告)日：2009-06-02

申请号：US10543710

申请日：2004-01-30

申请人： Masayuki Yoshida ,  Junichi Suto ,  Shunji Aoki ,  Genichi Watanabe

发明人： Masayuki Yoshida ,  Junichi Suto ,  Shunji Aoki ,  Genichi Watanabe

IPC分类号： C03B29/00 ,  G03F1/00

CPC分类号： H01L21/481 ,  H01F17/0006 ,  H01F41/127 ,  H01G4/12 ,  H01L21/4867 ,  H05K1/0306 ,  H05K3/0023 ,  H05K3/20 ,  H05K3/4629

摘要： An object of the invention is to provide a flat ceramic sheet including an internal electrode used for manufacturing a multilayer ceramic electronic part. Specifically, an electrode portion is formed on a surface of a transparent base member, and a photosensitive slurry containing dielectric powder is applied thereon. The photosensitive slurry is exposed from the backside of the base member up to a predetermined thickness, and then it is subjected to development. After that, the base member is removed. Thus, a ceramic green sheet is obtained.

摘要翻译： 本发明的目的是提供一种包括用于制造多层陶瓷电子部件的内部电极的平坦陶瓷片。 具体而言，在透明基材的表面上形成电极部，在其上涂布含有电介质粉末的感光性浆料。 感光性浆料从基材的背面露出达预定厚度，然后进行显影。 之后，移去基座部件。 由此得到陶瓷生片。

公开(公告)号：US20060213602A1

公开(公告)日：2006-09-28

申请号：US10543710

申请日：2004-01-30

申请人： Masayuki Yoshida ,  Junichi Suto ,  Shunji Aoki ,  Genichi Watanabe

发明人： Masayuki Yoshida ,  Junichi Suto ,  Shunji Aoki ,  Genichi Watanabe

IPC分类号： H01G4/12 ,  C03B29/00 ,  G03C5/00 ,  H01F41/04 ,  B28B1/30

CPC分类号： H01L21/481 ,  H01F17/0006 ,  H01F41/127 ,  H01G4/12 ,  H01L21/4867 ,  H05K1/0306 ,  H05K3/0023 ,  H05K3/20 ,  H05K3/4629

摘要： An object of the invention is to provide a flat ceramic sheet including an internal electrode used for manufacturing a multilayer ceramic electronic part. Specifically, an electrode portion is formed on a surface of a transparent base member, and a photosensitive slurry containing dielectric powder is applied thereon. The photosensitive slurry is exposed from the backside of the base member up to a predetermined thickness, and then it is subjected to development. After that, the base member is removed. Thus, a ceramic green sheet is obtained.

公开(公告)号：US07728080B2

公开(公告)日：2010-06-01

申请号：US12057595

申请日：2008-03-28

申请人： Shunji Aoki

发明人： Shunji Aoki

IPC分类号： C08L83/05 ,  C08L83/07 ,  C08G77/00 ,  C08G77/38

CPC分类号： C09J183/04 ,  C08G2170/40 ,  C08L83/00 ,  C08L2666/52

摘要： A solventless silicone pressure-sensitive adhesive composition is provided. The composition includes (A) a polyorganosiloxane with a polymerization degree of 300 to 2,000 and having at least two alkenyl group-containing organic groups, (B) a polyorganohydrosiloxane having at least three silicon-bonded hydrogen atoms, (C) a polydiorganosiloxane having alkenyl groups at both terminals, (D) a polydiorganosiloxane having SiH groups at both terminals, (E) a polyorganosiloxane composed of R23SiO1/2 units and SiO2 units (R2 is a monovalent hydrocarbon group), and (F) a platinum-based catalyst. The composition enables the prevention of problems caused by residual or volatilized organic substances, such as the absorption of ultraviolet radiation or the like, and also enables ready removal of the composition without deforming or damaging the adherend.

摘要翻译： 提供无溶剂的硅氧烷压敏粘合剂组合物。 所述组合物包含（A）聚合度为300〜2,000且具有至少2个含烯基的有机基团的聚有机硅氧烷，（B）具有至少三个与硅键合的氢原子的聚有机氢硅氧烷，（C）具有烯基的聚二有机硅氧烷 （D）在两端具有SiH基的聚二有机硅氧烷，（E）由R23SiO1 / 2单元组成的聚有机硅氧烷和SiO 2单元（R2是一价烃基），和（F）铂系催化剂。 该组合物能够防止由残留或挥发的有机物质引起的问题，例如紫外线辐射等的吸收，并且还能够使组合物的即时去除而不会使被粘物变形或损坏。