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    Method for pretreating and regenerating catalysts used in a process for making fluoroiodoalkanes
    1.
    发明授权
    Method for pretreating and regenerating catalysts used in a process for making fluoroiodoalkanes 有权
    用于制备氟碘代烷烃的方法中用于预处理和再生催化剂的方法

    公开(公告)号：US08722945B2

    公开(公告)日：2014-05-13

    申请号：US12264635

    申请日：2008-11-04

    申请人： Shuwu Yang ,  Hsueh Sung Tung

    发明人： Shuwu Yang ,  Hsueh Sung Tung

    IPC分类号： C07C261/00

    CPC分类号： C07C17/093 ,  B01J21/18 ,  B01J23/04 ,  B01J23/10 ,  B01J23/63 ,  B01J23/92 ,  B01J23/96 ,  B01J27/1806 ,  B01J27/285 ,  B01J38/14 ,  C07C17/10 ,  C07C17/202 ,  C07C17/204 ,  C07C17/206 ,  Y02P20/584 ,  C07C19/16

    摘要： A process for the preparation of a fluoroiodoalkane represented by the structural formula CF3(CF2)n—I, wherein n is 0 or 1. The process has the step of reacting a source of iodine with a compound represented by the structural formula CF3(CF2)n—Y, wherein Y is selected from H, Cl, Br and COOH and wherein n is 0 or 1. The reaction is carried out at a temperature from about 100° C. to about 750° C. and at a pressure from about 0.001 to about 100 atm for a contact time from about 0.001 second to about 300 hours in the presence a catalyst. The catalyst is subject to one or both of the following: (a) treating the catalyst prior to the reaction via contact with a gas selected from the group consisting of hydrogen fluoride, trifluoromethane, hydrogen, hydrogen iodide, iodine, fluorine, and oxygen, wherein the contact is carried out at a temperature and for a contact time sufficient to reduce the length of the induction period of the catalyst; and (b) treating the catalyst after the reaction via contact with a gas selected from the group consisting of hydrogen fluoride, hydrogen, fluorine, oxygen, or air at a temperature and for a contact time sufficient to regenerate the catalyst.

    摘要翻译： 制备由结构式CF 3（CF 2）n-1表示的氟代碘代烷烃的方法，其中n为0或1.该方法具有使碘源与由结构式CF 3（CF 2） ）n-Y，其中Y选自H，Cl，Br和COOH，并且其中n为0或1.反应在约100℃至约750℃的温度下进行， 在约0.001至约100大气压下，在催化剂存在下，接触时间为约0.001秒至约300小时。 催化剂经受以下一个或两个：（a）在反应之前通过与选自氟化氢，三氟甲烷，氢，碘化氢，碘，氟和氧的气体接触来处理催化剂， 其中所述接触在足以减少所述催化剂的诱导期的长度的温度和接触时间下进行; 和（b）在反应后通过与选自氟化氢，氢，氟，氧或空气的气体在足以再生催化剂的温度和接触时间下处理催化剂。

    Catalyst promoters for producing trifluoroiodomethane and pentafluoroiodoethane
    2.
    发明授权
    Catalyst promoters for producing trifluoroiodomethane and pentafluoroiodoethane 有权
    用于生产三氟碘甲烷和五氟碘乙烷的催化剂促进剂

    公开(公告)号：US08871986B2

    公开(公告)日：2014-10-28

    申请号：US11901672

    申请日：2007-09-18

    申请人： Shuwu Yang ,  Hsueh Sung Tung

    发明人： Shuwu Yang ,  Hsueh Sung Tung

    IPC分类号： C07C22/00 ,  C07C25/13 ,  B01J23/06 ,  B01J23/10 ,  B01J23/78 ,  C07C17/10 ,  C07C17/093 ,  B01J23/04 ,  B01J23/22 ,  B01J23/24 ,  C07C19/16 ,  C09K5/04 ,  C07C17/20 ,  C07C17/158

    CPC分类号： C07C19/16 ,  B01J23/04 ,  B01J23/06 ,  B01J23/10 ,  B01J23/22 ,  B01J23/24 ,  B01J23/78 ,  C07C17/093 ,  C07C17/10 ,  C07C17/158 ,  C07C17/204 ,  C09K5/044

    摘要： The present invention provides a process for the preparation of a fluoroiodoalkane compound represented by the formula CF3(CF2)n—I, wherein n is 0 or 1. The process includes the step of contacting: (i) a compound represented by the formula CF3(CF2)n—Y, wherein Y is selected from H, Cl, Br, and COOH and n is 0 or 1; (ii) a source of iodine; (iii) an alkali or alkaline earth metal salt catalyst supported on a carrier; and (iv) a catalyst promoter for the alkali or alkaline earth metal salt catalyst. The catalyst promoter includes at least one element selected from a transition metal element, a rare earth metal element, a main group element other than the alkali or alkaline earth metal element, any salts thereof, and any combinations thereof. The contacting is carried out at a temperature and pressure and for a length of time sufficient to produce the fluoroiodoalkane compound. The contacting may be carried out in the presence or absence of a solvent and in the presence or absence of oxygen.

    摘要翻译： 本发明提供了制备式CF 3（CF 2）n-1表示的氟代碘代烷烃化合物的方法，其中n为0或1.该方法包括使（ⅰ）式CF 3 （CF 2）n -Y，其中Y选自H，Cl，Br和COOH，n为0或1; （ii）碘源; （iii）负载在载体上的碱金属或碱土金属盐催化剂; 和（iv）碱金属或碱土金属盐催化剂的催化剂促进剂。 催化剂促进剂包括选自过渡金属元素，稀土金属元素，除碱金属或碱土金属元素以外的主要基团的元素中的至少一种元素，它们的任何盐及其任何组合。 接触在温度和压力下进行足够长的时间以产生氟代碘代烷烃化合物。 接触可以在存在或不存在溶剂的情况下以及在存在或不存在氧的情况下进行。

    Manufacture of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2-tetrafluoropropane via catalytic hydrogenation
    3.
    发明授权
    Manufacture of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2-tetrafluoropropane via catalytic hydrogenation 有权
    通过催化氢化制备1,1,1,2,3,3-六氟丙烷和1,1,1,2-四氟丙烷

    公开(公告)号：US08044250B2

    公开(公告)日：2011-10-25

    申请号：US12264735

    申请日：2008-11-04

    申请人： Shuwu Yang ,  Hsueh Sung Tung

    发明人： Shuwu Yang ,  Hsueh Sung Tung

    IPC分类号： C07C19/08

    CPC分类号： C07C17/354 ,  B01J21/18 ,  B01J23/26 ,  B01J23/40 ,  B01J23/42 ,  B01J23/48 ,  B01J23/70 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  C07C19/08

    摘要： A process for producing hydrofluorocarbon compounds represented by the following formula: CF3CHFCHm+1Fn wherein m is 0 or 2; n is 0 or 2; and m+n=2. The process has the step of contacting, i.e., reacting, hydrogen with a precursor compound represented by the following formula: CF3CF═CHmFn wherein m is 0 or 2; n is 0 or 2; and m+n=2. The contact is carried out in the presence of a solid catalyst and in the presence or absence of an inert gas. The catalyst is selected from the group consisting of: Fe, Co, Ni, Cu, Cr, Ru, Rh, Ag, Re, Os, Ir, Pt, Au, Sn, and any combinations thereof. For the hydrogenation of 1234yf to 254eb, Pd can also be used as catalyst in addition to the other above-referenced metals. These metals are preferably supported on a carrier such as activated carbon.

    摘要翻译： 由下式表示的氢氟烃化合物的制造方法：CF 3 CHFCHm + 1Fn，其中m为0或2; n为0或2; m + n = 2。 该方法具有使氢与由下式表示的前体化合物接触，即使其反应的步骤：其中m为0或2的CF 3 CF = CH m F n; n为0或2; m + n = 2。 该接触在固体催化剂存在下和在惰性气体存在或不存在下进行。 催化剂选自：Fe，Co，Ni，Cu，Cr，Ru，Rh，Ag，Re，Os，Ir，Pt，Au，Sn及其任何组合。 对于1234yf至254eb的氢化，除了其它上述金属之外，Pd也可用作催化剂。 这些金属优选负载在载体如活性炭上。

    METHOD FOR PRETREATING AND REGENERATING CATALYSTS USED IN A PROCESS FOR MAKING FLUOROIODOALKANES
    4.
    发明申请
    METHOD FOR PRETREATING AND REGENERATING CATALYSTS USED IN A PROCESS FOR MAKING FLUOROIODOALKANES 有权
    用于制备荧光体的方法中用于预处理和再生催化剂的方法

    公开(公告)号：US20090137852A1

    公开(公告)日：2009-05-28

    申请号：US12264635

    申请日：2008-11-04

    申请人： Shuwu Yang ,  Hsueh Sung Tung

    发明人： Shuwu Yang ,  Hsueh Sung Tung

    IPC分类号： C07C19/16

    CPC分类号： C07C17/093 ,  B01J21/18 ,  B01J23/04 ,  B01J23/10 ,  B01J23/63 ,  B01J23/92 ,  B01J23/96 ,  B01J27/1806 ,  B01J27/285 ,  B01J38/14 ,  C07C17/10 ,  C07C17/202 ,  C07C17/204 ,  C07C17/206 ,  Y02P20/584 ,  C07C19/16

    摘要： A process for the preparation of a fluoroiodoalkane represented by the structural formula CF3(CF2)n—I, wherein n is 0 or 1. The process has the step of reacting a source of iodine with a compound represented by the structural formula CF3(CF2)n—Y, wherein Y is selected from H, Cl, Br and COOH and wherein n is 0 or 1. The reaction is carried out at a temperature from about 100° C. to about 750° C. and at a pressure from about 0.001 to about 100 atm for a contact time from about 0.001 second to about 300 hours in the presence a catalyst. The catalyst is subject to one or both of the following: (a) treating the catalyst prior to the reaction via contact with a gas selected from the group consisting of hydrogen fluoride, trifluoromethane, hydrogen, hydrogen iodide, iodine, fluorine, and oxygen, wherein the contact is carried out at a temperature and for a contact time sufficient to reduce the length of the induction period of the catalyst; and (b) treating the catalyst after the reaction via contact with a gas selected from the group consisting of hydrogen fluoride, hydrogen, fluorine, oxygen, or air at a temperature and for a contact time sufficient to regenerate the catalyst.

    摘要翻译： 制备由结构式CF 3（CF 2）n I表示的氟代碘烷的方法，其中n为0或1.该方法具有使碘源与由结构式CF 3（CF 2）nY表示的化合物反应的步骤 其中Y选自H，Cl，Br和COOH，并且其中n为0或1.反应在约100℃至约750℃的温度下进行，并且在约0.001至约 在大气压下，在催化剂存在下，接触时间为约0.001秒至约300小时。 催化剂经受以下一个或两个：（a）在反应之前通过与选自氟化氢，三氟甲烷，氢，碘化氢，碘，氟和氧的气体接触来处理催化剂， 其中所述接触在足以减少所述催化剂的诱导期的长度的温度和接触时间下进行; 和（b）在反应后通过与选自氟化氢，氢，氟，氧或空气的气体在足以再生催化剂的温度和接触时间下处理催化剂。

    MANUFACTURE OF 1,1,1,2,3,3-HEXAFLUORORPROPANE AND 1,1,1,2-TETRAFLUOROPROPANE VIA CATALYTIC HYDROGENATION
    5.
    发明申请
    MANUFACTURE OF 1,1,1,2,3,3-HEXAFLUORORPROPANE AND 1,1,1,2-TETRAFLUOROPROPANE VIA CATALYTIC HYDROGENATION 有权
    1,1,1,2,3,3-十六烷基丙烷和1,1,1,2-四氢呋喃的制备通过催化氢化

    公开(公告)号：US20090131727A1

    公开(公告)日：2009-05-21

    申请号：US12264735

    申请日：2008-11-04

    申请人： Shuwu Yang ,  Hsueh Sung Tung

    发明人： Shuwu Yang ,  Hsueh Sung Tung

    IPC分类号： C07C17/354

    CPC分类号： C07C17/354 ,  B01J21/18 ,  B01J23/26 ,  B01J23/40 ,  B01J23/42 ,  B01J23/48 ,  B01J23/70 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  C07C19/08

    摘要： A process for producing hydrofluorocarbon compounds represented by the following formula: CF3CHFCHm+1Fn wherein m is 0 or 2; n is 0 or 2; and m+n=2. The process has the step of contacting, i.e., reacting, hydrogen with a precursor compound represented by the following formula: CF3CF═CHmFn wherein m is 0 or 2; n is 0 or 2; and m+n=2. The contact is carried out in the presence of a solid catalyst and in the presence or absence of an inert gas. The catalyst is selected from the group consisting of: Fe, Co, Ni, Cu, Cr, Ru, Rh, Ag, Re, Os, Ir, Pt, Au, Sn, and any combinations thereof. For the hydrogenation of 1234yf to 254eb, Pd can also be used as catalyst in addition to the other above-referenced metals. These metals are preferably supported on a carrier such as activated carbon.

    摘要翻译： 由下式表示的氢氟烃化合物的制造方法：＆lt;直线式公式说明=“In-line formula”end =“lead”？> CF3CHFCHm + 1Fn <？in-line-formula description =“In-line 式“end =”tail“？>其中m为0或2; n为0或2; m + n = 2。 该方法具有使氢与由下式表示的前体化合物接触，即使其反应的步骤：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF 3 CF-CHmFn < in-line-formula description =“In-line formula”end =“tail”？>其中m为0或2; n为0或2; m + n = 2。 该接触在固体催化剂存在下和在惰性气体存在或不存在下进行。 催化剂选自：Fe，Co，Ni，Cu，Cr，Ru，Rh，Ag，Re，Os，Ir，Pt，Au，Sn及其任何组合。 对于1234yf至254eb的氢化，除了其它上述金属之外，Pd也可用作催化剂。 这些金属优选负载在载体如活性炭上。

    Catalyst promoters for producing trifluoroiodomethane and pentafluoroiodoethane
    6.
    发明申请
    Catalyst promoters for producing trifluoroiodomethane and pentafluoroiodoethane 有权
    用于生产三氟碘甲烷和五氟碘乙烷的催化剂促进剂

    公开(公告)号：US20080108854A1

    公开(公告)日：2008-05-08

    申请号：US11901672

    申请日：2007-09-18

    申请人： Shuwu Yang ,  Hsueh Sung Tung

    发明人： Shuwu Yang ,  Hsueh Sung Tung

    IPC分类号： C07C17/00 ,  C07C19/08

    CPC分类号： C07C19/16 ,  B01J23/04 ,  B01J23/06 ,  B01J23/10 ,  B01J23/22 ,  B01J23/24 ,  B01J23/78 ,  C07C17/093 ,  C07C17/10 ,  C07C17/158 ,  C07C17/204 ,  C09K5/044

    摘要： The present invention provides a process for the preparation of a fluoroiodoalkane compound represented by the formula CF3(CF2)n—I, wherein n is 0 or 1. The process includes the step of contacting: (i) a compound represented by the formula CF3(CF2)n—Y, wherein Y is selected from H, Cl, Br, and COOH and n is 0 or 1; (ii) a source of iodine; (iii) an alkali or alkaline earth metal salt catalyst supported on a carrier; and (iv) a catalyst promoter for the alkali or alkaline earth metal salt catalyst. The catalyst promoter includes at least one element selected from a transition metal element, a rare earth metal element, a main group element other than the alkali or alkaline earth metal element, any salts thereof, and any combinations thereof. The contacting is carried out at a temperature and pressure and for a length of time sufficient to produce the fluoroiodoalkane compound. The contacting may be carried out in the presence or absence of a solvent and in the presence or absence of oxygen.

    摘要翻译： 本发明提供一种制备由式CF 3（CF 2）n I-I表示的氟代碘代烷烃化合物的方法，其中n 该方法包括使以下步骤：（i）由式CF 3（CF 2）n表示的化合物 -Y，其中Y选自H，Cl，Br和COOH，n为0或1; （ii）碘源; （iii）负载在载体上的碱金属或碱土金属盐催化剂; 和（iv）碱金属或碱土金属盐催化剂的催化剂促进剂。 催化剂促进剂包括选自过渡金属元素，稀土金属元素，除碱金属或碱土金属元素以外的主要基团的元素中的至少一种元素，它们的任何盐及其任何组合。 接触在温度和压力下进行足够长的时间以产生氟代碘代烷烃化合物。 接触可以在存在或不存在溶剂的情况下以及在存在或不存在氧的情况下进行。

    Catalyst for the synthesis of CF3I and CF3CF2I
    8.
    发明申请
    Catalyst for the synthesis of CF3I and CF3CF2I 失效
    用于合成CF 3 I和CF 3 CF 2 I的催化剂

    公开(公告)号：US20080200735A1

    公开(公告)日：2008-08-21

    申请号：US11706776

    申请日：2007-02-15

    申请人： Shuwu Yang ,  HsuehSung Tung

    发明人： Shuwu Yang ,  HsuehSung Tung

    IPC分类号： C07C17/00

    CPC分类号： C07C1/26 ,  B01J21/18 ,  B01J23/10 ,  B01J23/63 ,  B01J37/0201 ,  C07C17/10 ,  C07C2529/40 ,  C07C9/00 ,  C07C19/075

    摘要： A process for the preparation of a fluoroiodoalkane compound represented by the formula: CF3(CF2)n—Y, wherein n is 0 or 1. The process includes contacting A, B and C. A is represented by the formula: CF3(CF2)n—Y, wherein n is 0 or 1, and Y is selected from the group consisting of: H, Cl, Br, and COOH. B is a source of iodine, and C is a catalyst containing elements with d1s1 configuration and lanthanide elements. The process occurs at a temperature, and for a contact time, sufficient to produce the fluoroiodoalkane compound.

    摘要翻译： 一种制备由下式表示的氟代碘代烷烃化合物的方法：CF 3（CF 2）n -Y，其中n为0或 该方法包括使A，B和C接触.A由下式表示：CF 3 - （CH 2）n - 其中n为0或1，Y选自：H，Cl，Br和COOH。 B是碘的来源，C是含有d 1 O 1配位和镧系元素的元素的催化剂。 该过程发生在足以产生氟代碘烷化合物的温度和接触时间。