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1.发明授权Composition including a lanthanum perovskite on an alumina or aluminium oxyhydroxide substrate, preparation method and use in catalysis 有权在氧化铝或羟基氧化铝基体上的钙钛矿型镧的组成，其制备方法和催化剂的用途公开(公告)号：US08974764B2
公开(公告)日：2015-03-10
申请号：US13254151
申请日：2010-02-25
申请人： Simon Ifrah , Olivier Larcher , Rui Jorge Coelho Marques , Michael Lallemand , Julien Hernandez
发明人： Simon Ifrah , Olivier Larcher , Rui Jorge Coelho Marques , Michael Lallemand , Julien Hernandez
IPC分类号： C01B13/00 , C01C1/00 , C01D1/02 , C01G49/00 , C01G45/12 , C01F7/00 , B01J23/00 , B01J23/10 , B01J23/83 , B01J23/34 , B01J35/00 , B01J37/03 , B82Y30/00 , C04B35/26
CPC分类号： B01J35/026 , B01J21/04 , B01J23/002 , B01J23/10 , B01J23/34 , B01J23/83 , B01J35/006 , B01J37/031 , B01J2523/00 , B82Y30/00 , C01G45/1264 , C01G49/0054 , C01P2002/34 , C01P2002/72 , C01P2004/64 , C04B35/2675 , C04B2235/3208 , C04B2235/3227 , C04B2235/3229 , Y02C20/10 , B01J2523/3706 , B01J2523/842 , B01J2523/72 , B01J2523/23 , B01J2523/3712
摘要： A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminum or manganese, in the form of particles dispersed on an alumina or aluminum oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.
摘要翻译： 描述了一种组合物，其包括式LaMO 3的钙钛矿，其中M是选自铁，铝或锰中的至少一种元素，分散在氧化铝或羟基氧化铝基质上的颗粒形式，其中在700℃下煅烧 4小时，钙钛矿为纯晶相，形成钙钛矿颗粒的尺寸不超过15nm。 所述组合物可用于催化领域。
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2.发明申请COMPOSITION INCLUDING A LANTHANUM PEROVSKITE ON AN ALUMINA OR ALUMINIUM OXYHYDROXIDE SUBSTRATE, PREPARATION METHOD AND USE IN CATALYSIS 有权在氧化铝或氧化铝氧化物基材上包括一种兰蔻酸钙的组合物，制备方法和在催化中的应用公开(公告)号：US20120046163A1
公开(公告)日：2012-02-23
申请号：US13254151
申请日：2010-02-25
申请人： Simon Ifrah , Olivier L'archer , Rui Jorge Coelho Marques , Michael Lallemand , Julien Hernandez
发明人： Simon Ifrah , Olivier L'archer , Rui Jorge Coelho Marques , Michael Lallemand , Julien Hernandez
CPC分类号： B01J35/026 , B01J21/04 , B01J23/002 , B01J23/10 , B01J23/34 , B01J23/83 , B01J35/006 , B01J37/031 , B01J2523/00 , B82Y30/00 , C01G45/1264 , C01G49/0054 , C01P2002/34 , C01P2002/72 , C01P2004/64 , C04B35/2675 , C04B2235/3208 , C04B2235/3227 , C04B2235/3229 , Y02C20/10 , B01J2523/3706 , B01J2523/842 , B01J2523/72 , B01J2523/23 , B01J2523/3712
摘要： A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.
摘要翻译： 描述了一种组合物，其包括式LaMO 3的钙钛矿，其中M是选自铁，铝或锰中的至少一种元素，分散在氧化铝或羟基氧化铝基质上的颗粒形式，其中在700℃下煅烧 4小时，钙钛矿为纯晶相，形成钙钛矿颗粒的尺寸不超过15nm。 所述组合物可用于催化领域。
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3.发明授权Method for treating a gas containing nitrogen oxides (NOx), in which a composition comprising cerium oxide and niobium oxide is used as a catalyst 有权用于处理包含氮氧化物（NOx）的气体的方法，其中使用包含氧化铈和氧化铌的组合物作为催化剂公开(公告)号：US08734742B2
公开(公告)日：2014-05-27
申请号：US13877154
申请日：2011-09-28
申请人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jayne Harris , Clare Jones
发明人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jayne Harris , Clare Jones
CPC分类号： B01D53/9418 , B01D2255/2065 , B01D2255/20715 , B01D2255/407 , B01D2255/50 , B01D2257/404 , B01J23/002 , B01J23/20 , B01J37/031 , B01J2523/00 , F01N3/2066 , F01N2570/14 , F01N2610/02 , Y02A50/2325 , Y02A50/2344 , B01J2523/3712 , B01J2523/48 , B01J2523/56
摘要： A method is described for treating a gas including nitrogen oxides (NOx). The method can include conducting a reduction reaction of the nitrogen oxides with a nitrogen reducing agent. Further described, is a catalyst used for the reduction reaction which is a catalytic system including a composition based on cerium oxide and including niobium oxide in a proportion by a mass of from 2% to 20%.
摘要翻译： 描述了一种用于处理包括氮氧化物（NOx）的气体的方法。 该方法可以包括进行氮氧化物与还原剂的还原反应。 进一步描述的是用于还原反应的催化剂，其是包含基于氧化铈的组合物并且包含比例为2％至20％的氧化铌的催化体系。
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4.发明授权Composition based on cerium, zirconium and tungsten, preparation process and use in catalysis 有权基于铈，锆和钨的组成，制备方法和用于催化公开(公告)号：US09169129B2
公开(公告)日：2015-10-27
申请号：US13698659
申请日：2011-05-17
申请人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jane Harris , Clare Jones
发明人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jane Harris , Clare Jones
IPC分类号： B01J21/00 , B01J23/00 , B01J23/10 , B01J25/00 , B01J29/00 , C01G41/00 , B01D53/94 , B01J21/06 , B01J23/30 , B01J35/10 , C01G25/00
CPC分类号： C01G41/006 , B01D53/9418 , B01D53/944 , B01D2251/2062 , B01D2251/2067 , B01D2255/2065 , B01D2255/20715 , B01D2255/20776 , B01D2258/014 , B01J21/066 , B01J23/002 , B01J23/30 , B01J35/1014 , B01J2523/00 , C01G25/006 , C01P2002/52 , C01P2002/72 , C01P2002/74 , C01P2006/12 , Y02A50/2325 , B01J2523/3712 , B01J2523/48 , B01J2523/69
摘要： A composition based on cerium, zirconium and tungsten is described. The composition has a content expressed as an oxide, of which cerium is from 5% to 30% of the composition, tungsten is from 2% to 17% of the composition, and the remainder of the composition is zirconium. After aging at 750° C. under an air atmosphere including 10% water, it has a two-phase crystallographic structure having a tetragonal zirconia phase and a monoclinic zirconia phase, with no presence of a crystalline phase including tungsten. The composition can be used as a catalyst, especially in an SCR process.
摘要翻译： 描述了基于铈，锆和钨的组合物。 该组合物具有以氧化物表示的含量，其中铈为组合物的5％至30％，钨为组合物的2％至17％，其余组成为锆。 在含有10％水的空气气氛下，在750℃下老化后，其具有四方晶氧化锆相和单斜氧化锆相的两相晶体结构，不存在包含钨的结晶相。 该组合物可以用作催化剂，特别是在SCR工艺中。
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5.发明申请COMPOSITION BASED ON OXIDES OF CERIUM, OF NIOBIUM AND, OPTIONALLY, OF ZIRCONIUM AND USE THEREOF IN CATALYSIS 审中-公开基于氧化铈，铌和锆的氧化物的组合物及其在催化中的应用公开(公告)号：US20130210617A1
公开(公告)日：2013-08-15
申请号：US13808804
申请日：2011-07-05
IPC分类号： B01J23/20
CPC分类号： B01J23/20 , B01J23/002 , B01J37/031 , B01J2523/00 , C01F17/0012 , C01F17/0043 , C01G33/00 , C01G33/006 , C01P2006/13 , Y02C20/10 , B01J2523/3712 , B01J2523/48 , B01J2523/56
摘要： A composition based on cerium and niobium oxide in a proportion of niobium oxide of 2% to 20% is described. This composition can include zirconium oxide, optionally 50% of cerium oxide, 2% to 20% of niobium oxide, and at most 48% of zirconium oxide. Also described, is the use of the composition for treating exhaust gases.
摘要翻译： 描述了基于氧化铌的比例为2％至20％的基于铈和铌氧化物的组合物。 该组合物可以包括氧化锆，任选50％的氧化铈，2％至20％的氧化铌和至多48％的氧化锆。 还描述了用于处理废气的组合物的用途。
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6.发明申请COMPOSITION BASED ON CERIUM, ZIRCONIUM AND TUNGSTEN, PREPARATION PROCESS AND USE IN CATALYSIS 有权基于CERIUM，ZIRCONIUM和TUNGSTEN的组合物，制备方法和在催化中的应用公开(公告)号：US20130164201A1
公开(公告)日：2013-06-27
申请号：US13698659
申请日：2011-05-17
申请人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jane Harris , Clare Jones
发明人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jane Harris , Clare Jones
CPC分类号： C01G41/006 , B01D53/9418 , B01D53/944 , B01D2251/2062 , B01D2251/2067 , B01D2255/2065 , B01D2255/20715 , B01D2255/20776 , B01D2258/014 , B01J21/066 , B01J23/002 , B01J23/30 , B01J35/1014 , B01J2523/00 , C01G25/006 , C01P2002/52 , C01P2002/72 , C01P2002/74 , C01P2006/12 , Y02A50/2325 , B01J2523/3712 , B01J2523/48 , B01J2523/69
摘要： A composition based on cerium, zirconium and tungsten is described. The composition has a content expressed as an oxide, of which cerium is from 5% to 30% of the composition, tungsten is from 2% to 17% of the composition, and the remainder of the composition is zirconium. After aging at 750° C. under an air atmosphere including 10% water, it has a two-phase crystallographic structure having a tetragonal zirconia phase and a monoclinic zirconia phase, with no presence of a crystalline phase including tungsten. The composition can be used as a catalyst, especially in an SCR process.
摘要翻译： 描述了基于铈，锆和钨的组合物。 该组合物具有以氧化物表示的含量，其中铈为组合物的5％至30％，钨为组合物的2％至17％，其余组成为锆。 在含有10％水的空气气氛下，在750℃下老化后，其具有四方晶氧化锆相和单斜氧化锆相的两相晶体结构，不存在包含钨的结晶相。 该组合物可以用作催化剂，特别是在SCR工艺中。
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7.发明申请METHOD FOR TREATING A GAS CONTAINING NITROGEN OXIDES (NOX), IN WHICH A COMPOSITION COMPRISING CERIUM OXIDE AND NIOBIUM OXIDE IS USED AS A CATALYST 有权用于处理包含氮氧化物（NOX）的气体的方法，其中包含氧化铈和氧化镍的组合物用作催化剂公开(公告)号：US20130195743A1
公开(公告)日：2013-08-01
申请号：US13877154
申请日：2011-09-28
申请人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jayne Harris , Clare Jones
发明人： Julien Hernandez , Emmanuel Rohart , Rui Jorge Coelho Marques , Deborah Jayne Harris , Clare Jones
CPC分类号： B01D53/9418 , B01D2255/2065 , B01D2255/20715 , B01D2255/407 , B01D2255/50 , B01D2257/404 , B01J23/002 , B01J23/20 , B01J37/031 , B01J2523/00 , F01N3/2066 , F01N2570/14 , F01N2610/02 , Y02A50/2325 , Y02A50/2344 , B01J2523/3712 , B01J2523/48 , B01J2523/56
摘要： A method is described for treating a gas including nitrogen oxides (NOx). The method can include conducting a reduction reaction of the nitrogen oxides with a nitrogen reducing agent. Further described, is a catalyst used for the reduction reaction which is a catalytic system including a composition based on cerium oxide and including niobium oxide in a proportion by a mass of from 2% to 20%.
摘要翻译： 描述了一种用于处理包括氮氧化物（NOx）的气体的方法。 该方法可以包括进行氮氧化物与还原剂的还原反应。 进一步描述的是用于还原反应的催化剂，其是包含基于氧化铈的组合物并且包含比例为2％至20％的氧化铌的催化体系。
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8.发明申请COMPOSITION CONTAINING OXIDES OF ZIRCONIUM, CERIUM AND ANOTHER RARE EARTH HAVING REDUCED MAXIMUM REDUCIBILITY TEMPERATURE, A PROCESS FOR PREPARATION AND USE THEREOF IN THE FIELD OF CATALYSIS 有权含有ZIRCONIUM，CER和其他稀土的氧化物的组合物具有降低的最大可还原温度，其在制备和在其中的用途的方法公开(公告)号：US20130052108A1
公开(公告)日：2013-02-28
申请号：US13521673
申请日：2011-01-10
CPC分类号： C01G25/00 , B01D53/8603 , B01D53/8612 , B01D53/94 , B01D53/944 , B01D2255/2061 , B01D2255/2063 , B01D2255/2066 , B01D2255/2068 , B01D2255/407 , B01J21/066 , B01J23/10 , B01J35/023 , B01J35/1014 , B01J37/009 , B01J37/031 , B01J37/038 , C01G25/02 , C01P2002/50 , C01P2002/88 , C01P2004/62 , C01P2006/13 , C01P2006/32
摘要： A composition is described that includes oxides of zirconium, cerium and another rare earth different from cerium, having a cerium oxide content not exceeding 50 wt % and, after calcination at 1000° C. for 6 hours, a maximal reducibility temperature not exceeding 500° C. and a specific surface of at least 45 m2/g. The composition can be prepared according to a method that includes continuously reacting a mixture that includes compounds of zirconium, cerium and another rare earth having a basic compound for a residence time not exceeding 100 milliseconds, wherein the precipitate is heated and contacted with a surfactant before calcination.
摘要翻译： 描述了一种组合物，其包括锆，铈和另一种不同于铈的稀土，氧化铈含量不超过50重量％的氧化物，并且在1000℃煅烧6小时后，最大还原性温度不超过500℃ 且比表面积至少为45m2 / g。 该组合物可以根据包括使包含锆，铈和另一种具有碱性化合物的稀土的混合物连续反应的方法来制备，其中停留时间不超过100毫秒，其中将沉淀物加热并与表面活性剂接触 煅烧。
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9.发明申请COMPOSITION BASED ON OXIDES OF CERIUM, OF ZIRCONIUM AND OF ANOTHER RARE EARTH METAL WITH HIGH REDUCIBILITY, PREPARATION PROCESS AND USE IN THE FIELD OF CATALYSIS 审中-公开基于氧化铈，氧化锆和其他稀土金属的组合物，具有高度可降低性，制备工艺和在催化领域中的应用公开(公告)号：US20140205522A1
公开(公告)日：2014-07-24
申请号：US14125639
申请日：2012-06-13
申请人： Simon Ifrah , Emmanuel Rohart , Julien Hernandez , Dominique Horbez , Lama Itani
发明人： Simon Ifrah , Emmanuel Rohart , Julien Hernandez , Dominique Horbez , Lama Itani
CPC分类号： B01J23/10 , B01D53/944 , B01D53/945 , B01D2255/206 , B01D2255/2065 , B01D2255/20715 , B01D2255/9207 , B01J23/34 , B01J23/83 , B01J35/023 , B01J35/1014 , B01J37/0018 , B01J37/031 , B01J37/06 , B01J37/343 , C01G25/006 , C01P2002/50 , C01P2004/61 , C01P2006/13 , Y02T10/22
摘要： The composition of the invention is based on oxides of cerium, of zirconium and of at least one rare earth metal other than cerium, with a cerium oxide content of greater than 50% by weight and it has, after calcination at 1000° C. for 4 hours, a specific surface area of at least 20 m2/g and an amount of mobile oxygen between 200° C. and 400° C. of at least 0.8 ml O2/g. It is prepared by a process in which, in a reactor, a mixture of compounds of cerium, of zirconium and of the other rare earth metal is reacted continuously with a basic compound with a residence time of the reaction medium in the mixing zone of the reactor of at most 100 milliseconds; the precipitate is heated then brought into contact with a surfactant before being calcine.
摘要翻译： 本发明的组合物是基于铈，锆和至少一种除铈以外的稀土金属的氧化物，氧化铈含量大于50重量％，并且在1000℃下煅烧后， 4小时，至少20m 2 / g的比表面积和200℃至400℃之间的可移动氧量至少为0.8ml O2 / g。 它是通过以下方法制备的，其中在反应器中，锆和其它稀土金属的化合物的混合物与碱性化合物连续反应，反应介质的停留时间在 反应釜至多100毫秒; 将沉淀物加热，然后在煅烧之前与表面活性剂接触。
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10.发明授权Composition containing oxides of zirconium, cerium and another rare earth having reduced maximum reducibility temperature, a process for preparation and use thereof in the field of catalysis 有权含有锆，铈和另一种具有降低的最大还原性温度的稀土的氧化物的组合物，其在催化领域中的制备及其应用的方法公开(公告)号：US08524183B2
公开(公告)日：2013-09-03
申请号：US13521673
申请日：2011-01-10
CPC分类号： C01G25/00 , B01D53/8603 , B01D53/8612 , B01D53/94 , B01D53/944 , B01D2255/2061 , B01D2255/2063 , B01D2255/2066 , B01D2255/2068 , B01D2255/407 , B01J21/066 , B01J23/10 , B01J35/023 , B01J35/1014 , B01J37/009 , B01J37/031 , B01J37/038 , C01G25/02 , C01P2002/50 , C01P2002/88 , C01P2004/62 , C01P2006/13 , C01P2006/32
摘要： A composition is described that includes oxides of zirconium, cerium and another rare earth different from cerium, having a cerium oxide content not exceeding 50 wt % and, after calcination at 1000° C. for 6 hours, a maximal reducibility temperature not exceeding 500° C. and a specific surface of at least 45 m2/g. The composition can be prepared according to a method that includes continuously reacting a mixture that includes compounds of zirconium, cerium and another rare earth having a basic compound for a residence time not exceeding 100 milliseconds, wherein the precipitate is heated and contacted with a surfactant before calcination.
摘要翻译： 描述了一种组合物，其包括锆，铈和另一种不同于铈的稀土，氧化铈含量不超过50重量％的氧化物，并且在1000℃煅烧6小时后，最大还原性温度不超过500℃ 且比表面积至少为45m2 / g。 该组合物可以根据包括使包含锆，铈和另一种具有碱性化合物的稀土的混合物连续反应的方法来制备，其中停留时间不超过100毫秒，其中将沉淀物加热并与表面活性剂接触 煅烧。
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