摘要:
A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided. The battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrites of lithium or zinc at the time of charge can be prevented, short circuiting between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of long cycle life can be manufactured.
摘要:
A highly reliable rechargeable battery comprising an anode, a separator, a cathode, an electrolyte or an electrolyte solution, and a housing, characterized in that said anode is structured to have a size which is greater than that of said cathode. The rechargeable battery provides an increased energy density and has a prolonged charging and discharging cycle life, in which a dendrite causing a reduction in the battery performance, which is generated upon operating charging in the conventional rechargeable battery, is effectively prevented from generating or from growing in the case where it should be generated.
摘要:
A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrite of lithium or zinc at the time of the charge can be prevented, short circuit between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of the long cycle life can be manufactured.
摘要:
An anode for a rechargeable lithium battery which comprises an anode substrate and a coat disposed so as to cover at least a surface of said anode substrate opposed to said cathode, said coat comprising a film comprised of a metal oxide material of 1.5 or less in standard electrode potential difference with respect to lithium and capable of intercalating or deintercalating lithium ions generated during battery reaction. A process for producing said anode, characterized in that said film is formed using a polyacid or a peroxo polyacid. A rechargeable lithium battery is provided with said anode.
摘要:
A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrite of lithium or zinc at the time of the charge can be prevented, short circuit between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of the long cycle life can be manufactured.
摘要:
A highly reliable rechargeable battery comprising an anode, a cathode, a separator positioned between said anode and said cathode, and an electrolyte or an electrolyte solution disposed so as to contact with said anode and said cathode, characterized in that said anode is provided with an anode active material-retaining body comprising (a) an electrically conductive material and (b) an insulating or semiconductor material having a property of allowing an ion dedicated for a battery reaction to pass through but not or substantially not allowing an anode active material deposited upon operating charging to pass through, and said anode active material-body having a number of pores distributed therein at a porosity rate of 10% or more.
摘要:
A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrites of lithium or zinc at the time of charge can be prevented, short circuiting between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of long cycle life can be manufactured.
摘要:
A rechargeable lithium cell comprising an anode, a separator, a cathode, and an electrolyte or an electrolyte solution, characterized in that said anode comprises (a) a metal capable of being alloyed with lithium and (b) a metal incapable of being alloyed with lithium, said anode contains lithium when charging is operated, and wherein an anode terminal is extended from a portion formed of said metal (b).
摘要:
The object of the present invention is to provide a secondary battery that has a lamination of negative electrodes and positive electrodes with intervening separators that acquires a low battery internal impedance and excellent charging and discharging power by the sufficient compressing of the electrodes, and that is very safe and easy to recycle, and to provide a method for manufacturing such a battery. To achieve the above object, according to the present invention, in a battery wherein positive electrodes and negative electrodes are disposed with intervening separators, and are stored in a battery housing with a solid electrolyte or an electrolyte solution, provided in the battery housing is a member whose shape is changed at a predetermined temperature (first temperature), which is lower than the melting point of the separator that maintains the shape in the battery operating temperature range. By heating or cooling the member to the first temperature, pressure is applied to at least one part of the battery housing or the applied pressure is released.
摘要:
A rechargeable battery consisting of an anode, a cathode, a separator which is placed between the anode and the cathode and an electrolyte or electrolyte solution in contact with the anode and the cathode. The anode has an electrically conductive material which contains insulating or semiconductor film. The film covers protrusions present in the electrically conductive material. An opening between adjacent protrusions communicates with the electrical conductive material. Additionally, the electrically conductive material of the anode and the cathode contact the electrolyte through this opening. The rechargeable battery because of increased capacity and increased energy density has a prolonged charging and discharging life cycle. Moreover, the generation and growth of lithium or zinc dendrites are prevented.