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    Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream
    1.
    发明申请
    Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream 有权
    用于从含H 2 S的气流中回收硫的装置和催化部分氧化方法

    公开(公告)号：US20060051275A1

    公开(公告)日：2006-03-09

    申请号：US11225355

    申请日：2005-09-13

    申请人： Sriram Ramani ,  Alfred Keller ,  Devadas Panjala

    发明人： Sriram Ramani ,  Alfred Keller ,  Devadas Panjala

    IPC分类号： C01B17/16

    CPC分类号： C01B17/0465 ,  B01D53/8612 ,  B01J23/58 ,  B01J23/626 ,  C01B17/046 ,  C01B2203/1241 ,  C01B2203/127 ,  C01B2203/1282 ,  C10L3/10 ,  C10L3/102

    摘要： A process for purifying a light hydrocarbon stream containing H2S is disclosed in which the selective catalytic partial oxidation of the H2S component is carried out while the hydrocarbon components slip through substantially unconverted. A catalyst that favors the partial oxidation of H2S over conversion of the hydrocarbon component of a gaseous H2S-light hydrocarbon mixture is employed. Apparatus for selectively cleaning up light hydrocarbon streams containing low concentrations (e.g., less than 25 vol. %), and apparatus for selectively cleaning up light hydrocarbon streams having higher concentrations (e.g., greater than 25 vol. %) of H2S are also disclosed.

    摘要翻译： 公开了一种用于纯化含有H 2 S的轻质烃流的方法，其中进行H 2 S 2组分的选择性催化部分氧化，同时烃组分滑过 基本未转换 采用有利于H 2 S 2部分氧化的催化剂超过气态H 2 S-S / S轻烃混合物的烃组分的转化。 用于选择性清洁含有低浓度（例如小于25体积％）的轻质烃流的装置，以及用于选择性清洗具有较高浓度（例如大于25体积％）H 2的轻烃流的装置 还公开了S。

    Catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream
    2.
    发明授权
    Catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream 有权
    用于从含H 2 S的气流中回收硫的催化部分氧化方法

    公开(公告)号：US07326397B2

    公开(公告)日：2008-02-05

    申请号：US11225355

    申请日：2005-09-13

    申请人： Sriram Ramani ,  Alfred E. Keller ,  Devadas Panjala

    发明人： Sriram Ramani ,  Alfred E. Keller ,  Devadas Panjala

    IPC分类号： C01B17/04

    CPC分类号： C01B17/0465 ,  B01D53/8612 ,  B01J23/58 ,  B01J23/626 ,  C01B17/046 ,  C01B2203/1241 ,  C01B2203/127 ,  C01B2203/1282 ,  C10L3/10 ,  C10L3/102

    摘要： A process for purifying a light hydrocarbon stream containing H2S is disclosed in which the selective catalytic partial oxidation of the H2S component is carried out while the hydrocarbon components slip through substantially unconverted. A catalyst that favors the partial oxidation of H2S over conversion of the hydrocarbon component of a gaseous H2S-light hydrocarbon mixture is employed. Apparatus for selectively cleaning up light hydrocarbon streams containing low concentrations (e.g., less than 25 vol. %), and apparatus for selectively cleaning up light hydrocarbon streams having higher concentrations (e.g., greater than 25 vol. %) of H2S are also disclosed.

    摘要翻译： 公开了一种用于纯化含有H 2 S的轻质烃流的方法，其中进行H 2 S 2组分的选择性催化部分氧化，同时烃组分滑过 基本未转换 采用有利于H 2 S 2部分氧化的催化剂超过气态H 2 S-S / S轻烃混合物的烃组分的转化。 用于选择性清洗含有低浓度（例如小于25体积％）的轻烃流的装置，以及用于选择性清洗具有较高浓度（例如大于25体积％）H 2的轻质烃流的装置 还公开了S。

    SCRUBBING HYDROGEN SULFIDE FROM HYDROTREATED PRODUCT
    4.
    发明申请
    SCRUBBING HYDROGEN SULFIDE FROM HYDROTREATED PRODUCT 有权
    从氢化产品中加入硫化氢

    公开(公告)号：US20130001135A1

    公开(公告)日：2013-01-03

    申请号：US13493667

    申请日：2012-06-11

    申请人： Joe E. Bares ,  Devadas Panjala ,  Fred Clark ,  Brad E. Vanwinkle

    发明人： Joe E. Bares ,  Devadas Panjala ,  Fred Clark ,  Brad E. Vanwinkle

    IPC分类号： B01J8/02 ,  C10G29/20 ,  C10G29/00

    CPC分类号： B01D19/0015 ,  C10G45/02 ,  C10G45/08 ,  C10G2300/202 ,  C10G2300/4056

    摘要： This application provides an H2S scrubbing system, a column packed with an inert material, wherein an inert gas passes counter to a flow of a hydrotreated product containing H2S through said column. There is also provided a method for scrubbing H2S from a hydrotreated product, comprising providing a hydrotreated product containing H2S; and passing the hydrotreated product over a column packed with an inert material, wherein an inert gas passed counter to a flow of the hydrotreated product.

    摘要翻译： 该应用提供了一种H2S洗涤系统，填充有惰性材料的柱，其中惰性气体与包含H 2 S的加氢处理产物的流动相反通过所述塔。 还提供了用于从加氢处理的产物中洗涤H 2 S的方法，其包括提供含有H 2 S的加氢处理产物; 并将加氢处理的产物通过填充有惰性物质的柱，其中惰性气体与加氢处理产物的流动相反。

    Scrubbing hydrogen sulfide from hydrotreated product
    6.
    发明授权
    Scrubbing hydrogen sulfide from hydrotreated product 有权
    从加氢处理的产品中洗涤硫化氢

    公开(公告)号：US09028678B2

    公开(公告)日：2015-05-12

    申请号：US13493667

    申请日：2012-06-11

    申请人： Joe E. Bares ,  Devadas Panjala ,  Fred Clark ,  Brad E. Vanwinkle

    发明人： Joe E. Bares ,  Devadas Panjala ,  Fred Clark ,  Brad E. Vanwinkle

    IPC分类号： C10G45/00 ,  B01D19/00 ,  C10G45/02 ,  C10G45/08

    CPC分类号： B01D19/0015 ,  C10G45/02 ,  C10G45/08 ,  C10G2300/202 ,  C10G2300/4056

    摘要： This application provides an H2S scrubbing system, a column packed with an inert material, wherein an inert gas passes counter to a flow of a hydrotreated product containing H2S through said column. There is also provided a method for scrubbing H2S from a hydrotreated product, comprising providing a hydrotreated product containing H2S; and passing the hydrotreated product over a column packed with an inert material, wherein an inert gas passed counter to a flow of the hydrotreated product.

    摘要翻译： 该应用提供了一种H2S洗涤系统，填充有惰性材料的柱，其中惰性气体与包含H 2 S的加氢处理产物的流动相反通过所述塔。 还提供了用于从加氢处理的产物中洗涤H 2 S的方法，其包括提供含有H 2 S的加氢处理产物; 并将加氢处理的产物通过填充有惰性物质的柱，其中惰性气体与加氢处理产物的流动相反。

    Catalytic conversion of hydrocarbons to hydrogen and high-value carbon
    8.
    发明授权
    Catalytic conversion of hydrocarbons to hydrogen and high-value carbon 失效
    碳氢化合物催化转化为氢和高碳

    公开(公告)号：US06875417B1

    公开(公告)日：2005-04-05

    申请号：US10279489

    申请日：2002-10-24

    申请人： Naresh Shah ,  Devadas Panjala ,  Gerald P. Huffman

    发明人： Naresh Shah ,  Devadas Panjala ,  Gerald P. Huffman

    IPC分类号： B01J23/755 ,  B01J23/80 ,  B01J23/84 ,  B01J23/881 ,  B01J23/89 ,  B01J37/00 ,  B01J37/03 ,  B01J37/18 ,  C01B3/26

    CPC分类号： B82Y30/00 ,  B01J23/755 ,  B01J23/80 ,  B01J23/84 ,  B01J23/881 ,  B01J23/8906 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/18 ,  C01B3/26 ,  C01B2203/0277 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1076 ,  C01B2203/1241

    摘要： The present invention provides novel catalysts for accomplishing catalytic decomposition of undiluted light hydrocarbons to a hydrogen product, and methods for preparing such catalysts. In one aspect, a method is provided for preparing a catalyst by admixing an aqueous solution of an iron salt, at least one additional catalyst metal salt, and a suitable oxide substrate support, and precipitating metal oxyhydroxides onto the substrate support. An incipient wetness method, comprising addition of aqueous solutions of metal salts to a dry oxide substrate support, extruding the resulting paste to pellet form, and calcining the pellets in air is also discloses. In yet another aspect, a process is provided for producing hydrogen from an undiluted light hydrocarbon reactant, comprising contacting the hydrocarbon reactant with a catalyst as described above in a reactor, and recovering a substantially carbon monoxide-free hydrogen product stream. In still yet another aspect, a process is provided for catalytic decomposition of an undiluted light hydrocarbon reactant to obtain hydrogen and a valuable multi-walled carbon nanotube coproduct.

    摘要翻译： 本发明提供了用于实现未稀释的轻烃催化分解成氢产物的新催化剂，以及制备这种催化剂的方法。 在一个方面，提供了一种通过混合铁盐水溶液，至少一种另外的催化剂金属盐和合适的氧化物底物载体以及将金属羟基氧化物沉淀到基材载体上来制备催化剂的方法。 初始润湿方法，包括将金属盐水溶液加入到干氧化物基质载体中，将所得糊料挤出成颗粒形式，并在空气中煅烧颗粒。 在另一方面，提供了用于从未稀释的轻烃反应物生产氢的方法，包括如上所述在反应器中使烃反应物与催化剂接触，并回收基本上一氧化碳的氢产物流。 在另一方面，提供了一种用于未稀释的轻烃反应物的催化分解以获得氢气和有价值的多壁碳纳米管副产物的方法。