公开(公告)号：US07172809B2

公开(公告)日：2007-02-06

申请号：US10642826

申请日：2003-08-19

申请人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

发明人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC分类号： B32B5/16

CPC分类号： C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

摘要翻译： 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US06635341B1

公开(公告)日：2003-10-21

申请号：US09629421

申请日：2000-07-31

申请人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

发明人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC分类号： B32B516

CPC分类号： C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition, formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

摘要翻译： 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US06592999B1

公开(公告)日：2003-07-15

申请号：US09919200

申请日：2001-07-31

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B904

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

公开(公告)号：US06592998B2

公开(公告)日：2003-07-15

申请号：US09919095

申请日：2001-07-31

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Roger L. Scriven ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Roger L. Scriven ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B904

CPC分类号： C09D183/06 ,  B05D7/57 ,  B05D7/576 ,  C08L33/08 ,  C08L83/00 ,  C08L83/04 ,  C08L2666/52 ,  C09D133/08 ,  C09J133/08 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31667

摘要： Improved multi-layer composites are provided. The multi-layer composites include at least a first polymeric layer and a second polymeric layer formed over the first polymeric layer thereby forming an interface region there between. At least one of the polymeric layers is formed from a thermosetting composition which contains an adhesion promoter composition. The adhesion promoter composition is formed from (1) at least one adhesion promoting component, and (2) at least one surface active component. The improvement is represented by the presence of the adhesion promoting component (1) at the interface region.

公开(公告)号：US07329468B2

公开(公告)日：2008-02-12

申请号：US10935643

申请日：2004-09-07

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B9/04

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

摘要翻译： 本发明提供了两种或更多种聚合物层的改进的多层复合材料，其中至少一种由热固性组合物形成。 所述复合材料包括形成在基材上的至少第一聚合物层和在所述第一聚合物层上的第二聚合物层，其中在不存在含硼化合物的情况下，所述第一和第二聚合物层具有差的层间粘合性。 改进在于在足以改善第一和第二聚合物层之间的层间粘合力的量中将至少一种含硼化合物包含在第一和第二聚合物层的一个或两个中。 还提供了一种改进的可固化涂料组合物，其用于形成两层或多层固化涂层的多层复合涂层，其中至少一层由热固性组合物形成。 还提供了相关方法和涂覆的基底。

公开(公告)号：US07005472B2

公开(公告)日：2006-02-28

申请号：US10784830

申请日：2004-02-24

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarje L. Koster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarje L. Koster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

公开(公告)号：US06759478B2

公开(公告)日：2004-07-06

申请号：US10456552

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06593417B1

公开(公告)日：2003-07-15

申请号：US09629443

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Karen A. Barkac ,  Shawn A. DeSaw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Gregory J. McCollum ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K3/22 ,  C08K3/36 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/28 ,  C08L2666/54 ,  C08L2666/14 ,  C08L2666/04

摘要： Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

摘要翻译： 提供涂料组合物，其由包含（a）至少一种包含至少一个反应性官能团的聚硅氧烷的组分形成; （b）至少一种包含至少一种与至少一种选自至少一种聚硅氧烷的至少一种反应性官能团和至少一种反应物官能团的官能团反应的官能团的官能团; 和（c）多个颗粒，其中每个组分是不同的，并且其中所述至少一种聚硅氧烷的至少一种反应性官能团和所述至少一种反应物的至少一种官能团基本上与颗粒不反应。 还提供了由底涂层和从可固化涂料组合物沉积的面涂层形成的多组分复合涂料组合物。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。

公开(公告)号：US06987144B2

公开(公告)日：2006-01-17

申请号：US10456576

申请日：2003-06-09

申请人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L83/04 ,  C08L83/06 ,  C08L83/08

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04 ,  C08L2666/28

摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

公开(公告)号：US06610777B1

公开(公告)日：2003-08-26

申请号：US09629420

申请日：2000-07-31

申请人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

发明人： Lawrence G. Anderson ,  Shawn A. De Saw ,  Marvis E. Hartman ,  Deborah E. Hayes ,  Thomas R. Hockswender ,  Kymarie L. Kuster ,  Michael Allen Mayo ,  Masayuki Nakajima ,  Kurt G. Olson ,  Richard J. Sadvary ,  Laura E. Schilling ,  Dennis A. Simpson ,  Shiryn Tyebjee ,  Truman F. Wilt

IPC分类号： C08L8304

CPC分类号： B82Y30/00 ,  C08J3/20 ,  C08K3/01 ,  C08K3/013 ,  C08K2201/011 ,  C09D7/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/69 ,  C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04 ,  C08L2666/28

摘要： Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

摘要翻译： 提供涂料组合物，其包括包含至少一个反应性官能团的聚硅氧烷和至少一种包含至少一个反应性官能团的材料。 还提供了由从着色涂料组合物沉积的底涂层和涂覆在底涂层上的顶涂层，由上述涂料组合物沉积的面漆形成的多层复合涂层。 还提供了一种用于改善涂覆基材的耐擦伤性的方法以及涂覆的基材。 本发明的组合物提供高度耐刮擦的涂层，特别是高度耐刮擦的彩色 - 透明涂层。