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1.发明授权公开(公告)号：US08524886B2
公开(公告)日：2013-09-03
申请号：US12705753
申请日：2010-02-15
申请人： Susan P. James , Min Zhang , Guy Beauregard
发明人： Susan P. James , Min Zhang , Guy Beauregard
CPC分类号： C08J9/42 , B05D5/00 , B29C67/24 , C08B37/00 , C08B37/0072 , C08L5/08 , C08L101/00 , Y10T428/249953 , Y10T428/31504 , Y10T428/31855 , Y10T428/31971 , C08L2666/02 , C08L2666/26
摘要： An outer layer having an entanglement comprising an intermingling of cloaked hydrophilic guest and a hydrophobic polymer host, wherein molecules of the guest have been crosslinked with each other. Under certain circumstances, using complexes of the guest may be desirable or even necessary. The intermingling of the guest and host includes a physical tangling, whether it also comprises crosslinking by primary bonding (e.g., chemical/covalent bonding) there-between. Also a method of producing an outer layer having such an entanglement, including the steps of: temporarily cloaking at least a portion of the hydrophilic groups of the guest; intermingling at least a portion of the cloaked groups with a porous polymeric structure by diffusing the guest with cloaked groups into at least a portion of the structure's pores; within the pores, crosslinking at least a portion of the molecules of the guest with the guest; and removing the cloaking. Cloaking may be performed by silylation or acylation. Intermingling may be performed by producing a mixture of guest and host (whether in solution, powdered, granular, etc., form); next, a crosslinking of the guest with itself is performed; then, the mixture is molded into the outer layer.
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2.发明授权Outer layer material having entanglement of hydrophobic polymer hostblended with a maleated hydrophobic polymer co-host, and hydrophilic polymer guest 有权外层材料具有与马来酸化疏水性聚合物共主体共混的疏水性聚合物和亲水性聚合物客体的缠结公开(公告)号：US08524884B2
公开(公告)日：2013-09-03
申请号：US12148598
申请日：2008-04-21
CPC分类号： C08J3/246 , A61L31/048 , C08B37/00 , C08B37/0072 , C08J9/42 , C08J2323/06 , C08J2405/08 , C08L5/08 , Y10T428/249953 , C08L2666/02 , C08L101/00 , C08L2666/26
摘要： An outer layer material having an entanglement comprising an intermingling of cloaked hydrophilic guest and a hydrophobic polymer host, wherein molecules of the guest have been crosslinked with each other. Under certain circumstances, using complexes of the guest may be desirable or even necessary. Prior to intermingling with the guest, a host blend may be produced to include a physical blend of a hydrophobic polymer host and a maleated hydrophobic co-host (preferably, an anhydride functionalized hydrophobic polymer, whereby the polymer so functionalized, is the same as that selected for the host). The intermingling of the guest and host, or host-co-host blend, includes a physical tangling, whether it also comprises crosslinking by primary bonding (e.g., chemical/covalent bonding) there-between. Also a method of producing an outer layer material having such an entanglement, including the steps of: temporarily cloaking at least a portion of the hydrophilic groups of the guest; intermingling at least a portion of the cloaked groups with a porous polymeric structure by diffusing the guest with cloaked groups into at least a portion of the structure's pores; within the pores, crosslinking at least a portion of the molecules of the guest with the guest; and removing the cloaking. Cloaking may be performed by silylation or acylation. Intermingling may be performed by producing a mixture of guest and host, or host blend, (whether in solution, powdered, granular, etc., form); next, a crosslinking of the guest with itself is performed; then, the mixture is molded into the outer layer with or without additional crosslinking of the host to the host.
摘要翻译： 具有缠结的外层材料，其包含掩蔽的亲水性客体和疏水性聚合物主体的混合物，其中客体的分子彼此交联。 在某些情况下，使用客人的复合物可能是理想的或甚至是必需的。 在与客体混合之前，可以制备主体共混物以包括疏水性聚合物主体和马来酸化疏水性共主体的物理共混物（优选为酸酐官能化的疏水性聚合物，由此使官能化的聚合物与之相同） 为主机选择）。 客体和宿主或宿主 - 共同宿主混合物的混合包括物理缠结，不管其是否还包括通过其间的初次键合（例如，化学/共价键合）的交联。 还有一种制造具有这种缠结的外层材料的方法，包括以下步骤：暂时掩蔽客体的至少一部分亲水基团; 通过将具有掩蔽基团的客体扩散到结构的孔的至少一部分中来将具有多孔聚合物结构的至少一部分掩蔽组混合; 在孔内，与客体交联客体的至少一部分分子; 并去除隐形。 掩蔽可以通过甲硅烷基化或酰化进行。 混合可以通过生产客体和主体或主体混合物的混合物（无论是溶液，粉末状，颗粒状等）形式进行; 接下来，进行客人与其自身的交联; 然后，将该混合物模塑到外层中，该主体与主体有或没有额外的交联。
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3.发明授权Hyaluronan (HA) esterification via acylation technique for moldable devices 有权乙酰透明质酸（HA）通过酰化技术进行酯化反应公开(公告)号：US07692000B2
公开(公告)日：2010-04-06
申请号：US10571662
申请日：2004-09-20
申请人： Susan P. James , Min Zhang
发明人： Susan P. James , Min Zhang
IPC分类号： C08B37/00
CPC分类号： C08B37/0072
摘要： A series of novel, melt- or mold-processable HA esters with varying aliphatic chain lengths are synthesized from silyl HA-quaternary (quat.) ammonium salt complex (preferably silyl HA-CTA, a silylated HA complex with cetyltrimethyl ammonium salt). Introduction of aliphatic acyl groups, preferably acid chlorides, to disrupt the strong HA intermolecular bonding, is done via acylation. Acylation takes place at the oxygen of the trimethylsilyloxy group —O—Si(CH3)3 in the silyl HA-CTA by removal of trimethylsilyl groups therefrom. Optionally, crosslinking may be performed during the shaping/molding of the HA esters into a structure/device, or thereafter, if at all. Native HA can then be regenerated/recovered by saponification hydrolysis, removing acyl groups, —CH3(CH2)10CO, and the cetyltrimethyl ammonium salt groups, -CTA, from HA ester. The structure/device of a preselected shape (e.g., porous or solid, bulk structure or fibers) may become a component of an assembly, a product that is further processed, integrated into another component (e.g., laminated, adhered, assembled, further shaped, chemically-intermixed/intermingled), and so on.
摘要翻译： 从甲硅烷基HA-季（铵）铵盐络合物（优选甲硅烷基HA-CTA，甲硅烷基化的HA配合物与十六烷基三甲基铵盐）合成一系列具有不同脂肪链长度的新型，熔融或可模塑加工的HA酯。 引入脂族酰基，优选酰氯，以破坏强HA分子间键，是通过酰化进行的。 通过从其中除去三甲基甲硅烷基，在甲硅烷基HA-CTA中的三甲基甲硅烷氧基-O-Si（CH 3）3的氧上进行酰化。 任选地，可以在将HA酯成型/成型成结构/装置期间或之后（如果有的话）进行交联。 然后可以通过皂化水解再生/回收天然HA，从HA酯除去酰基，-CH 3（CH 2）10 CO和十六烷基三甲基铵盐基团-CTA。 预选形状（例如，多孔或固体，本体结构或纤维）的结构/装置可以成为组件的组件，进一步加工的产品集成到另一部件中（例如，层压，粘合，组装，进一步成形 ，化学混合/混合）等。
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4.发明授权Outer layer having entanglement of hydrophobic polymer host and hydrophilic polymer guest 有权外层具有疏水聚合物主体和亲水聚合物客体的缠结公开(公告)号：US07662954B2
公开(公告)日：2010-02-16
申请号：US10283760
申请日：2002-10-29
申请人： Susan P. James , Min Zhang , Guy Beauregard
发明人： Susan P. James , Min Zhang , Guy Beauregard
CPC分类号： C08J9/42 , B05D5/00 , B29C67/24 , C08B37/00 , C08B37/0072 , C08L5/08 , C08L101/00 , Y10T428/249953 , Y10T428/31504 , Y10T428/31855 , Y10T428/31971 , C08L2666/02 , C08L2666/26
摘要： An outer layer having an entanglement comprising an intermingling of cloaked hydrophilic guest and a hydrophobic polymer host, wherein molecules of the guest have been crosslinked with each other. Under certain circumstances, using complexes of the guest may be desirable or even necessary. The intermingling of the guest and host includes a physical tangling, whether it also comprises crosslinking by primary bonding (e.g., chemical/covalent bonding) there-between. Also a method of producing an outer layer having such an entanglement, including the steps of: temporarily cloaking at least a portion of the hydrophilic groups of the guest; intermingling at least a portion of the cloaked groups with a porous polymeric structure by diffusing the guest with cloaked groups into at least a portion of the structure's pores; within the pores, crosslinking at least a portion of the molecules of the guest with the guest; and removing the cloaking. Cloaking may be performed by silylation or acylation. Intermingling may be performed by producing a mixture of guest and host (whether in solution, powdered, granular, etc., form); next, a crosslinking of the guest with itself is performed; then, the mixture is molded into the outer layer.
摘要翻译： 具有缠结的外层，其包含掩蔽的亲水客体和疏水性聚合物主体的混合物，其中客体的分子彼此交联。 在某些情况下，使用客人的复合物可能是理想的或甚至是必需的。 客人和主持人的混合包括物理缠结，无论其是否还包括通过其间的初次键合（例如，化学/共价键合）的交联。 还有一种制造具有这种缠结的外层的方法，包括以下步骤：暂时隐藏客人的至少一部分亲水基团; 通过将具有掩蔽基团的客体扩散到结构的孔的至少一部分中来将具有多孔聚合物结构的至少一部分掩蔽组混合; 在孔内，与客体交联客体的至少一部分分子; 并去除隐形。 掩蔽可以通过甲硅烷基化或酰化进行。 混合可以通过生产客体和主机的混合物（无论是溶液，粉末，颗粒等）形式进行; 接下来，进行客人与其自身的交联; 然后将混合物模塑成外层。
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5.发明申请Outer layer material having entanglement of hydrophobic polymer host blended with a maleated hydrophobic polymer co-host, and hydrophilic polymer guest 有权具有与马来酸化疏水性聚合物共主体共混的疏水性聚合物主体的缠结的外层材料和亲水性聚合物客体公开(公告)号：US20080318022A1
公开(公告)日：2008-12-25
申请号：US12148598
申请日：2008-04-21
CPC分类号： C08J3/246 , A61L31/048 , C08B37/00 , C08B37/0072 , C08J9/42 , C08J2323/06 , C08J2405/08 , C08L5/08 , Y10T428/249953 , C08L2666/02 , C08L101/00 , C08L2666/26
摘要： An outer layer material having an entanglement comprising an intermingling of cloaked hydrophilic guest and a hydrophobic polymer host, wherein molecules of the guest have been crosslinked with each other. Under certain circumstances, using complexes of the guest may be desirable or even necessary. Prior to intermingling with the guest, a host blend may be produced to include a physical blend of a hydrophobic polymer host and a maleated hydrophobic co-host (preferably, an anhydride functionalized hydrophobic polymer, whereby the polymer so functionalized, is the same as that selected for the host). The intermingling of the guest and host, or host-co-host blend, includes a physical tangling, whether it also comprises crosslinking by primary bonding (e.g., chemical/covalent bonding) there-between. Also a method of producing an outer layer material having such an entanglement, including the steps of: temporarily cloaking at least a portion of the hydrophilic groups of the guest; intermingling at least a portion of the cloaked groups with a porous polymeric structure by diffusing the guest with cloaked groups into at least a portion of the structure's pores; within the pores, crosslinking at least a portion of the molecules of the guest with the guest; and removing the cloaking. Cloaking may be performed by silylation or acylation. Intermingling may be performed by producing a mixture of guest and host, or host blend, (whether in solution, powdered, granular, etc., form); next, a crosslinking of the guest with itself is performed; then, the mixture is molded into the outer layer with or without additional crosslinking of the host to the host.
摘要翻译： 具有缠结的外层材料，其包含掩蔽的亲水性客体和疏水性聚合物主体的混合物，其中客体的分子彼此交联。 在某些情况下，使用客人的复合物可能是理想的或甚至是必需的。 在与客体混合之前，可以制备主体共混物以包括疏水性聚合物主体和马来酸化疏水性共主体的物理共混物（优选为酸酐官能化的疏水性聚合物，由此使官能化的聚合物与之相同） 为主机选择）。 客体和宿主或宿主 - 共同宿主混合物的混合包括物理缠结，不管其是否还包括通过其间的初次键合（例如，化学/共价键合）的交联。 还有一种制造具有这种缠结的外层材料的方法，包括以下步骤：暂时掩蔽客体的至少一部分亲水基团; 通过将具有掩蔽基团的客体扩散到结构的孔的至少一部分中来将具有多孔聚合物结构的至少一部分掩蔽组混合; 在孔内，与客体交联客体的至少一部分分子; 并去除隐形。 掩蔽可以通过甲硅烷基化或酰化进行。 混合可以通过生产客体和主体或主体混合物的混合物（无论是溶液，粉末状，颗粒状等）形式进行; 接下来，进行客人与其自身的交联; 然后，将该混合物模塑到外层中，该主体与主体有或没有额外的交联。
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公开(公告)号：US20230329599A1
公开(公告)日：2023-10-19
申请号：US17972593
申请日：2022-10-25
申请人： Min Zhang , Hongyang Cao
发明人： Min Zhang , Hongyang Cao
IPC分类号： A61B5/1468
CPC分类号： A61B5/1468 , A61B2562/227
摘要： The invention relates to an electrochemical sensor based on an associated sensor, including an interface base and a probe part, where the interface base is provided with two groups of electrical connection terminals, the probe part is provided with a working sensor and an associated sensor, both sensors are provided with a counter electrode, a working electrode and a reference electrode, and the counter electrode of the working sensor and the counter electrode of the associated sensor are the same electrode. The invention adds the associated sensor to the probe part, and the two sensors with high similarity share the same counter electrode, and form an associated relationship with an original working sensor; the associated sensor is equivalent to a “standard ruler”, works in a known calibration environment and provides a standard reference value for the working sensor to be corrected, so as to obtain a more accurate result.
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7.发明授权公开(公告)号：US09562242B2
公开(公告)日：2017-02-07
申请号：US14344608
申请日：2012-09-13
申请人： Min Jiang , Min Zhang , Jiangfeng Ma , Hao Wu , Liya Liang , Rongming Liu , Guangming Wang , Ping Wei
发明人： Min Jiang , Min Zhang , Jiangfeng Ma , Hao Wu , Liya Liang , Rongming Liu , Guangming Wang , Ping Wei
CPC分类号： C12P7/46 , C07C51/412 , C07C51/43 , C07C51/44 , C07C55/10
摘要： This invention belongs to the field of biochemical engineering and relates to a method of cyclic utilization of water during separation of succinic acid made by fermentation. This invention uses water from separation process for aerobic growth of E. coli AFP111 and production of succinic acid by anaerobic fermentation, obtaining final succinic acid concentration of 55 g/L and yield of 91.6%. Compared with results of fermentation using culture medium prepared from tap water, succinic acid concentration and productivity increased by 8.5% and 8.46%, respectively. An outstanding advantage of this invention is recovery and utilization of evaporated water during separation of succinic acid, realizing cyclic use of water during industrial production of succinic acid, which is an environment-friendly process. Also, as evaporated water generated during separation of succinic acid contains small amount of organic acids such as acetic acid and formic acid, if this water is used for aerobic growth of thalli, the small amount of organic acids contained therein can be used as gluconeogenesis carbon source, improving activity of some key enzymes in cell and favoring succinic acid production by anaerobic fermentation of thalli.
摘要翻译： 本发明属于生物化学工程领域，涉及通过发酵制备的琥珀酸分离期间循环利用水的方法。 本发明利用分离过程中的水分进行大肠杆菌AFP111的有氧生长，通过厌氧发酵生产琥珀酸，得到最终琥珀酸浓度为55g / L，产率为91.6％。 与使用自来水制备的培养基的发酵结果相比，琥珀酸浓度和产率分别提高了8.5％和8.46％。 本发明的突出优点是分离琥珀酸期间蒸发水的回收利用，在工业生产琥珀酸期间循环使用水，这是一个环保的工艺。 另外，由于琥珀酸分离过程中产生的蒸发水含有少量的有机酸如乙酸和甲酸，所以如果这种水用于铊的有氧生长，其中所含的少量有机酸可用作糖异生碳 来源，改善细胞中一些关键酶的活性，并通过thalli的厌氧发酵有利于琥珀酸生产。
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公开(公告)号：US09439097B2
公开(公告)日：2016-09-06
申请号：US14176670
申请日：2014-02-10
申请人： Min Zhang , Matthew Baker , Hakon Helmers , Philippe Godin , Fangchen Cheng
发明人： Min Zhang , Matthew Baker , Hakon Helmers , Philippe Godin , Fangchen Cheng
CPC分类号： H04W24/10 , H04L5/0035 , H04L5/0091 , H04L43/06 , H04W28/02
摘要： A method of facilitating coordinated multi-point communication (CoMP) in a wireless communications network including at least a first base station (BS) and a second BS, a plurality of user equipment (UEs) being associated with the second BS, includes generating, at the first BS, a status request message for requesting the second BS to report one or more types of status information, the status request message including at least one of an aggregation indicator and conditional reporting indicator, the aggregation indicator specifying whether the second BS is to report individual measurements or aggregated measurements to the first BS, the conditional reporting indicator indicating to the second BS to report measurements corresponding to the one or more types of resource status information to the first BS only when one or more conditions are met; and sending the status request message to the second BS.
摘要翻译： 一种促进包括至少第一基站（BS）和第二BS的无线通信网络中的协调多点通信（CoMP）的方法，与第二BS相关联的多个用户设备（UE）包括： 在第一BS处，用于请求第二BS报告一种或多种类型的状态信息的状态请求消息，所述状态请求消息包括聚合指示符和条件报告指示符中的至少一个，所述聚合指示符指定所述第二BS是否是 将单个测量或聚合测量报告给第一BS，条件报告指示符仅在满足一个或多个条件时向第二BS指示向第一BS报告对应于一种或多种类型的资源状态信息的测量结果; 并向第二BS发送状态请求消息。
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公开(公告)号：US08924994B2
公开(公告)日：2014-12-30
申请号：US13149500
申请日：2011-05-31
CPC分类号： H04N21/442 , H04H60/32
摘要： Power management methods, apparatus and articles of manufacture for audience measurement meters are disclosed. An example method disclosed herein comprises determining an activation state of a media presentation device, and controlling activation of an audience measurement meter based on the activation state of the media presentation device, the audience measurement meter to monitor the media presentation device when the activation state is an active state. Another example method disclosed herein comprises obtaining presentation device state data representing an activation state of a media presentation device to be monitored by an audience measurement meter, the presentation device state data including time information, and determining whether to fault audience measurement data reported by the audience measurement meter based on the presentation device state data and outage information determined from the audience measurement data.
摘要翻译： 公开了用于观众测量计的电源管理方法，设备和制造品。 本文公开的示例性方法包括：确定媒体呈现设备的激活状态，以及基于媒体呈现设备的激活状态来控制观众测量计的激活;观众测量仪，用于当激活状态为 活跃状态。 本文公开的另一示例性方法包括获取表示设备状态数据，表示由观众测量计监视的媒体呈现设备的激活状态，所述呈现设备状态数据包括时间信息，以及确定是否故障由观众报告的观众测量数据 基于从观众测量数据确定的呈现设备状态数据和中断信息的测量计。
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公开(公告)号：US08822384B2
公开(公告)日：2014-09-02
申请号：US13814610
申请日：2011-09-30
CPC分类号： G01N31/22 , B82Y15/00 , B82Y30/00 , Y10S977/742 , Y10S977/773 , Y10S977/774 , Y10S977/92
摘要： Nanoparticles having one or more attached sensing moieties including uridine 5′-triphosphate (UTP) and deoxythymidine 5′-triphosphate (dTTP), are disclosed herein. These nanoparticles can, for example, be used for detection of plasticizers, such as phthalates, in the sample. Methods, kits and apparatuses using these nanoparticles for detecting plasticizers in a sample are also disclosed herein.
摘要翻译： 具有包含尿苷5'-三磷酸（UTP）和脱氧胸苷5'-三磷酸（dTTP）的一个或多个连接的感测部分的纳米颗粒在本文中公开。 例如，这些纳米颗粒可用于检测样品中的增塑剂，例如邻苯二甲酸酯。 本文还公开了使用这些纳米颗粒检测样品中增塑剂的方法，试剂盒和装置。
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