PHOTOSENSITIVE POLYIMIDE COMPOSITION, BASE AGENT THEREOF, METHOD OF MAKING THE BASE AGENT, AND SOLDER-RESISTANT POLYIMIDE THIN FILM MADE FROM THE COMPOSITION
    5.
    发明申请
    PHOTOSENSITIVE POLYIMIDE COMPOSITION, BASE AGENT THEREOF, METHOD OF MAKING THE BASE AGENT, AND SOLDER-RESISTANT POLYIMIDE THIN FILM MADE FROM THE COMPOSITION 有权
    感光性聚酰亚胺组合物,其基础代理,制备基剂的方法和由组合物制成的耐电极聚酰亚胺薄膜

    公开(公告)号:US20160018733A1

    公开(公告)日:2016-01-21

    申请号:US14332904

    申请日:2014-07-16

    Abstract: A photosensitive polyimide composition; the composition comprises a base agent and a curing agent comprising a photoinitiator. By applying an aliphatic diamine monomer, which has a long carbon chain, and a grafting monomer, which has a main carbon chain having a double bond and an epoxy group at two ends respectively, to a method of making the base agent, a mixture of the base agent and the curing agent can be screen printed to form a photosensitive polyimide film on a copper foil. Also, the photosensitive polyimide film can be exposed under low exposure energy, and can be developed to a solder-resistant polyimide thin film by a weak alkaline developer after exposed. In addition, the solder-resistant polyimide thin film has low dielectric constant, low dielectric loss, good flame resistance, good solder resistance, and good pencil hardness. Accordingly, the photosensitive polyimide composition is applicable to high density flexible printed circuit boards.

    Abstract translation: 光敏聚酰亚胺组合物; 组合物包含基剂和包含光引发剂的固化剂。 通过将具有长碳链的脂族二胺单体和分别具有两端的主链碳原子和双环氧基的接枝单体分别与制备该基剂的方法相同, 可以将基础剂和固化剂丝网印刷以在铜箔上形成感光性聚酰亚胺膜。 此外,感光性聚酰亚胺膜可以以低曝光能量曝光,并且可以在暴露后通过弱碱性显影剂显影成耐焊料聚酰亚胺薄膜。 此外,耐焊料聚酰亚胺薄膜具有低介电常数,低介电损耗,良好的阻燃性,良好的阻焊性和良好的铅笔硬度。 因此,光敏聚酰亚胺组合物可应用于高密度柔性印刷电路板。

    POLYIMIDE METAL LAMINATED PLATE AND METHOD OF MAKING THE SAME
    6.
    发明申请
    POLYIMIDE METAL LAMINATED PLATE AND METHOD OF MAKING THE SAME 有权
    聚酰亚胺金属层压板及其制备方法

    公开(公告)号:US20150367606A1

    公开(公告)日:2015-12-24

    申请号:US14312827

    申请日:2014-06-24

    Abstract: A polyimide metal laminated plate has a first metallic film, a first thermoplastic polyimide film laminated on a surface of the first metallic film, a first thermosetting polyimide film laminated on a surface of the first thermoplastic polyimide film distal from the first metallic film, and a second thermoplastic polyimide film laminated on a surface of the first thermosetting polyimide film distal from the first thermoplastic polyimide film. The polyimide metal laminated plate has no adhesive layer, so the polyimide metal laminated plate not only has good heat resistance, flame resistance, anti-chemical properties, and dimensional stability, but also meets the thinning tendency of FPCB. In addition, by the first thermosetting polyimide film and the second thermoplastic polyimide film having a water vapor transmission rate equal to or more than 170 g-μm/m2-day, the delamination and whitening of the polyimide metal laminated plate is prevented.

    Abstract translation: 聚酰亚胺金属层压板具有第一金属膜,层压在第一金属膜的表面上的第一热塑性聚酰亚胺膜,层压在远离第一金属膜的第一热塑性聚酰亚胺膜的表面上的第一热固性聚酰亚胺膜, 第二热塑性聚酰亚胺膜层叠在远离第一热塑性聚酰亚胺膜的第一热固性聚酰亚胺膜的表面上。 聚酰亚胺金属层压板没有粘合层,因此聚酰亚胺金属层压板不仅具有良好的耐热性,阻燃性,抗化学性能和尺寸稳定性,而且还满足FPCB的变薄趋势。 此外,通过第一热固性聚酰亚胺膜和水蒸汽透过率等于或大于170g-μm/ m 2·天的第二热塑性聚酰亚胺膜,防止了聚酰亚胺金属叠层板的脱层和增白。

    THERMALLY CURABLE SOLDER-RESISTANT INK AND METHOD OF MAKING THE SAME
    7.
    发明申请
    THERMALLY CURABLE SOLDER-RESISTANT INK AND METHOD OF MAKING THE SAME 有权
    耐热耐焊锡塞及其制造方法

    公开(公告)号:US20150322274A1

    公开(公告)日:2015-11-12

    申请号:US14270413

    申请日:2014-05-06

    CPC classification number: C09D11/102 C08L63/00 C08L79/08 C08L2205/05

    Abstract: A method of making a thermally curable solder-resistant ink, which comprises the following steps: polymerizing an aliphatic diamine monomer having a long carbon chain, an aromatic dianhydride monomer, an aromatic diamine monomer having a carboxylic group, and an anhydride monomer having a carboxylic group in an aprotic solvent to obtain a polyamine acid; cyclizing the polyamine acid to obtain a modified polyimide; and mixing the modified polyimide and a curing agent to obtain the thermally curable solder-resistant ink. By the steps mentioned above, the thermally curable solder-resistant ink made from the method has a dielectric constant less than 3.00 and a dielectric loss less than 0.01 and thereby is applicable to high frequency electronic equipments. Also, the thermally curable solder-resistant ink has good electrical properties, folding endurance, solder resistance, warpage resistance, flame resistance, acid endurance, alkali endurance, good solvent resistance and low water absorption.

    Abstract translation: 一种制备耐热可焊性耐油墨的方法,包括以下步骤:聚合具有长碳链的脂族二胺单体,芳族二酐单体,具有羧基的芳族二胺单体和具有羧酸的酸酐单体 将其置于非质子溶剂中以获得多胺酸; 环化多胺酸得到改性聚酰亚胺; 并将改性聚酰亚胺和固化剂混合,得到可热固化的耐焊料油墨。 通过上述步骤,由该方法制成的可热固化的耐焊锡墨水具有小于3.00的介电常数和小于0.01的介电损耗,因此可应用于高频电子设备。 另外,可热固化的耐焊锡墨水具有良好的电气性能,耐折叠性,耐焊接性,耐翘曲性,阻燃性,耐酸性,耐碱性,耐溶剂性和低吸水性。

    SOLUBLE THERMOPLASTIC POLYIMIDE COMPOSITION, METHOD OF MAKING THE COMPOSITION, POLYIMIDE METAL LAMINATE HAVING CONNECTING LAYER MADE FROM THE COMPOSITION, AND METHOD OF MAKING THE LAMINATE
    9.
    发明申请
    SOLUBLE THERMOPLASTIC POLYIMIDE COMPOSITION, METHOD OF MAKING THE COMPOSITION, POLYIMIDE METAL LAMINATE HAVING CONNECTING LAYER MADE FROM THE COMPOSITION, AND METHOD OF MAKING THE LAMINATE 审中-公开
    可溶性热塑性聚酰亚胺组合物,组合物的制造方法,具有连接层的聚酰亚胺金属层压体及其制造方法

    公开(公告)号:US20160053055A1

    公开(公告)日:2016-02-25

    申请号:US14510213

    申请日:2014-10-09

    Abstract: A method of making a soluble thermoplastic polyimide composition, which comprises the steps of: polymerizing a first diamine, a second diamine different from the first diamine, and a dianhydride in a polar aprotic solvent to obtain a polyamine acid, wherein the first diamine contains a carboxyl group; and imidizing the polyamine acid to obtain the composition, wherein the composition contains the carboxyl group. By controlling the content of the dianhydride within a range from 85 mol. % to 99 mol. % based on the total content of the first diamine and the second diamine, the soluble thermoplastic polyimide composition made from the method can be laminated with a commercial polyimide film and a metal foil via simple steps of coating, drying, and pressing, to form a polyimide metal laminate. Therefore, by utilizing the soluble thermoplastic polyimide composition made from the method, making a polyimide metal laminate is simple and economical.

    Abstract translation: 一种制备可溶性热塑性聚酰亚胺组合物的方法,其包括以下步骤:聚合第一二胺,不同于第一二胺的第二二胺和极性非质子溶剂中的二酐以获得多胺酸,其中第一二胺包含 羧基; 并酰亚胺化多胺酸得到组合物,其中组合物含有羧基。 通过将二酐的含量控制在85mol的范围内。 %至99mol。 基于第一二胺和第二二胺的总含量的%,由该方法制备的可溶性热塑性聚酰亚胺组合物可以通过简单的涂布,干燥和压制步骤与市售的聚酰亚胺膜和金属箔层压,形成 聚酰亚胺金属层压板。 因此,通过利用由该方法制成的可溶性热塑性聚酰亚胺组合物,制造聚酰亚胺金属层压体是简单和经济的。

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