公开(公告)号：US06939580B2

公开(公告)日：2005-09-06

申请号：US10239994

申请日：2001-03-29

申请人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

发明人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

IPC分类号： A47G27/02 ,  C03C25/26 ,  C09K3/18 ,  D06M13/236 ,  D06M13/428 ,  D06M15/277 ,  D06M15/576 ,  B05D3/02 ,  B05D3/04 ,  B05D3/10

CPC分类号： C03C25/26 ,  D06M13/236 ,  D06M13/428 ,  D06M15/277 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12

摘要： A textile having durability of maintaining water- and sufficient oil-repellency and soil releasability before and after cleaning can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid containing a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, preferably at most 3, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent is an emulsion containing a fluorine-containing compound and an emulsifier, the fluorine-containing compound is a fluorine-containing polymer and/or a fluorine-containing low molecular weight compound, and the emulsifier contains an anionic surface active agent having pKa of at least 2.

摘要翻译： 可以通过制备经处理的织物的方法获得在清洁之前和之后保持水和足够的防油性和污垢释放性的耐久性的织物，其具有以下步骤：（1）制备含有水和油 - （2）将处理液的pH调节至7以下，优选为3以下，（3）将处理液施加到织物上，（4）用蒸汽处理织物，（5）用纺织品洗涤 水和脱水剂，其中拒水拒油剂是含有含氟化合物和乳化剂的乳液，含氟化合物是含氟聚合物和/或含氟低分子化合物 ，乳化剂含有pKa为2以上的阴离子表面活性剂。

公开(公告)号：US07758656B2

公开(公告)日：2010-07-20

申请号：US10258067

申请日：2001-04-16

申请人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda ,  Kayo Kusumi

发明人： Takashi Enomoto ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda ,  Kayo Kusumi

IPC分类号： D06M15/00 ,  B05D7/00

CPC分类号： D06M13/184 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T442/2164 ,  Y10T442/2189 ,  Y10T442/2197

摘要： A textile having excellent water- and oil-repellency can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, preferably at most 3, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent is at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains an organic salt.

摘要翻译： 通过制备处理过的纺织品的方法可以获得具有优异的拒水拒油性的织物，其具有以下步骤：（1）制备包含拒水拒油剂的处理液，（2）调节 （3）将处理液施加到纺织品上，（4）用蒸汽处理织物，和（5）用水洗涤织物并使织物脱水，其中， 防油剂为选自含氟聚合物和含氟低分子化合物中的至少一种含氟化合物，防水防油剂或处理液含有有机物 盐。

公开(公告)号：US06284853B1

公开(公告)日：2001-09-04

申请号：US09015764

申请日：1998-01-29

申请人： Masayuki Yamana ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

发明人： Masayuki Yamana ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

IPC分类号： C08F1820

CPC分类号： C08F20/36 ,  C08F220/22 ,  C08F220/36 ,  Y10T428/2969

摘要： The present invention provides a copolymer whose durability on cleaning is improved while maintaining good water- and oil-repellency. Disclosed is a copolymer having: (i) a fluoroalkyl group, (ii) a urethane or urea linkage, and (iii) a functional group selected from the group consisting of a carboxyl group, a carboxylic anhydride group, an epoxy group, a phosphoric group, an alkoxysilane group, a imine group, a sulfonic group, an amino group, an isocyanate group and a chlorine atom, and a stainproof agent containing the copolymer as an active component.

摘要翻译： 本发明提供了一种在保持良好的拒水拒油性的同时提高了清洗耐久性的共聚物。 公开了具有以下的共聚物：（i）氟烷基，（ii）氨基甲酸酯或脲键，（iii）选自羧基，羧酸酐基，环氧基，磷酸 基团，烷氧基硅烷基，亚胺基，磺酸基，氨基，异氰酸酯基和氯原子，以及含有该共聚物作为活性成分的防污剂。

公开(公告)号：US06355753B1

公开(公告)日：2002-03-12

申请号：US09424215

申请日：2000-01-19

申请人： Masayuki Yamana ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

发明人： Masayuki Yamana ,  Ikuo Yamamoto ,  Norihito Otsuki ,  Teruyuki Fukuda

IPC分类号： C08F1800

CPC分类号： D06M15/233 ,  C08F222/16 ,  C08F222/18 ,  C08F222/20 ,  C08F246/00 ,  C09K3/18 ,  D06M15/263 ,  D06M15/277 ,  D06M15/353 ,  D06M2400/01

摘要： A stainproofing polymer having: (i) a reactive group selected from the group consisting of a carboxyl group or its salt, a hydroxyl group, an epoxy group, a phosphoric acid group, an alkoxysilane group, an imine group, a sulfonic acid group, an amino group, an isocyanate group and a blocked isocyanate group; and (ii) a fluoroalkyl group, characterized in that a melting point of a monomer having a fluoroalkyl group, which constitutes the polymer, is at least 70° C. and a melting point of the stainproofing polymer is at least 50° C., gives durability capable of maintaining sufficient water- and oil-repellency after cleaning.

摘要翻译： 一种防污聚合物，其具有：（i）选自羧基或其盐，羟基，环氧基，磷酸基，烷氧基硅烷基，亚胺基，磺酸基， 氨基，异氰酸酯基和封端异氰酸酯基; 和（ii）氟代烷基，其特征在于构成聚合物的具有氟代烷基的单体的熔点至少为70℃，防污聚合物的熔点至少为50℃， 提供了在清洁后能够保持足够的防水和防油性的耐久性。

公开(公告)号：US6013732A

公开(公告)日：2000-01-11

申请号：US8484

申请日：1998-01-16

申请人： Masayuki Yamana ,  Ikuo Yamamoto ,  Teruyuki Fukuda

发明人： Masayuki Yamana ,  Ikuo Yamamoto ,  Teruyuki Fukuda

IPC分类号： D06M15/256 ,  C08L33/16 ,  D06M13/428 ,  D06M15/227 ,  D06M15/233 ,  D06M15/248 ,  D06M15/263 ,  D06M15/277 ,  D06M15/31 ,  D06M15/333 ,  D06M15/576 ,  D06M15/00

CPC分类号： D06M15/576 ,  C08L33/16 ,  D06M13/428 ,  D06M15/227 ,  D06M15/233 ,  D06M15/248 ,  D06M15/263 ,  D06M15/277 ,  D06M15/31 ,  D06M15/333 ,  Y10T428/23986

摘要： The present invention provides a stainproofing agent having the durability capable of maintaining sufficient water- and oil-repellency as well as stainproofing properties before and after cleaning. Disclosed is a stainproofing agent containing (A) a fluroalkyl group-containg copolymer having (I) a structure unit derived from a monomer having a fluoroalkyl group, (II) a structure unit derived from a monomer containing no fluorine, (III) a structure unit derived from vinyl chloride, and (IV) a structure unit derived from a crosslinking monomer; (B) a urethane compound having a fluoroalkyl group, or a copolymer having (V) a structure unit derived from a monomer having a fluoroalkyl group and a carbon-carbon double bond, and (VI) a structure unit derived from a monomer which contains no fluorine atom and has at least one urethane or urea linkage and one carbon-carbon double bond; and (C) an acrylic copolymer containing no fluorine.

摘要翻译： 本发明提供了一种具有耐清洗性和防污性的耐久性以及清洗前后的防污性的防污剂。 公开了含有（A）含氟烷基基团的共聚物的防污剂，其具有（I）来自具有氟代烷基的单体的结构单元，（II）来自不含氟的单体的结构单元，（III） 衍生自氯乙烯的单元，和（IV）衍生自交联单体的结构单元; （B）具有氟代烷基的氨基甲酸酯化合物或具有（V）衍生自具有氟代烷基和碳 - 碳双键的单体的结构单元的共聚物，和（VI）衍生自含有 无氟原子，并具有至少一个氨基甲酸酯或脲键和一个碳 - 碳双键; 和（C）不含氟的丙烯酸共聚物。

公开(公告)号：US06833082B2

公开(公告)日：2004-12-21

申请号：US10058376

申请日：2002-01-30

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Teruyuki Fukuda ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Teruyuki Fukuda ,  Kayo Kusumi

IPC分类号： D06M1555

CPC分类号： D06M15/263 ,  D06M11/56 ,  D06M11/66 ,  D06M13/188 ,  D06M13/2243 ,  D06M13/262 ,  D06M15/412 ,  D06M2200/25 ,  Y10T428/23986

摘要： Excellent stain block property, WAQE resistance and yellowing resistance are imparted to a textile by a method of preparing a treated textile has the steps of (1) preparing a treatment liquid comprising a stain blocking agent and a sulfated castor oil and having pH of at most 7, (2) applying the treatment liquid to the textile, (3) treating the textile with steam, and (4) washing the textile with water and dehydrating the textile.

摘要翻译： 通过制备经处理的织物的方法赋予纺织品优异的防污性，耐WAQE性和耐黄变性，具有以下步骤：（1）制备包含防污剂和硫酸化蓖麻油并具有最多pH值的处理液 7，（2）将处理液施加到纺织品上，（3）用蒸汽处理织物，（4）用水洗涤织物并使织物脱水。

公开(公告)号：US09988759B2

公开(公告)日：2018-06-05

申请号：US13063809

申请日：2009-09-11

申请人： Shinichi Minami ,  Takashi Enomoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Mitsuhiro Usugaya ,  Rumi Takeuchi ,  Ikuo Yamamoto ,  Peter Cheshire Hupfield

发明人： Shinichi Minami ,  Takashi Enomoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Mitsuhiro Usugaya ,  Rumi Takeuchi ,  Ikuo Yamamoto ,  Peter Cheshire Hupfield

IPC分类号： B32B27/04 ,  D06M15/643 ,  C08F283/12 ,  C08F290/06 ,  D06M15/277 ,  D06M15/356

CPC分类号： D06M15/6436 ,  C08F283/122 ,  C08F290/068 ,  D06M15/277 ,  D06M15/3568 ,  Y10T442/2172 ,  C08F220/24 ,  C08F220/68

摘要： A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.

公开(公告)号：US20110124803A1

公开(公告)日：2011-05-26

申请号：US12935344

申请日：2009-03-12

申请人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Takashi Enomoto ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Samantha Reed ,  Avril E. Surgenor

发明人： Ikuo Yamamoto ,  Tetsuya Masutani ,  Masahiro Miyahara ,  Takashi Enomoto ,  Shinichi Minami ,  Peter Cheshire Hupfield ,  Samantha Reed ,  Avril E. Surgenor

IPC分类号： C09D183/08 ,  C08L83/08

CPC分类号： C08F283/122 ,  C08F14/18 ,  C08F14/22 ,  C08F214/186 ,  C08F283/124 ,  C08J3/03 ,  C08J2383/10 ,  D06M15/277 ,  D06M15/3568 ,  D06M15/643 ,  D06M15/6436 ,  D06M15/657 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50 ,  C08F2/30

摘要： A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.

摘要翻译： 公开了巯基或乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。 氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。 氟硅酮反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）巯基或乙烯基官能的有机聚硅氧烷制备。

公开(公告)号：US20110027593A1

公开(公告)日：2011-02-03

申请号：US12935554

申请日：2009-03-27

申请人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

发明人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

IPC分类号： B32B27/10 ,  C08F220/22 ,  C08L27/12

CPC分类号： D21H17/20 ,  A61K8/8152 ,  A61Q3/02 ,  A61Q5/06 ,  A61Q19/00 ,  B29C33/62 ,  C08F220/24 ,  C08F222/1006 ,  C09D133/16 ,  D21H19/20 ,  Y10T428/3154 ,  C08F220/26

摘要： Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH2═C(—X)—C(═O)—Y—[—(CH2)m—Z—]p—(CH2)n—Rf (wherein X represents a hydrogen atom; Y represents —O— or —NH—; Z represents a direct bond, —S— or —SO2—; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH2═C(X′)—C(═O)—O—(RO)q—H (wherein X′ represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group.

摘要翻译： 公开了一种在水中具有足够稳定性的含氟共聚物，其能够为纸提供足够的耐油性。 含氟聚合物含有作为必要成分的（a）由通式（I）表示的含氟单体CH 2 = C（-X）-C（= O）-Y - [ - （CH 2）m-Z - ]对 - （CH 2）n -R f（其中X表示氢原子; Y表示-O-或-NH-; Z表示直接键，-S-或-SO 2 - ; Rf表示具有1- 6个碳原子; m是1-10的数; n是0-10的数; p是0或1）和（b）由通式（II）表示的含烷氧基的单体CH 2 = C（ X'）-C（= O）-O-（RO）q-H（其中X'表示氢原子或甲基; R表示具有2-4个碳原子的亚烷基，其中部分或全部氢原子 可以被羟基取代; q表示1-50的整数）。 含氟聚合物不含有具有氨基的单体。

公开(公告)号：US08568886B2

公开(公告)日：2013-10-29

申请号：US12935554

申请日：2009-03-27

申请人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

发明人： Michio Matsuda ,  Tetsuya Uehara ,  Mitsuhiro Usugaya ,  Ikuo Yamamoto ,  Takashi Enomoto ,  Kayo Kusumi

IPC分类号： B32B27/10

CPC分类号： D21H17/20 ,  A61K8/8152 ,  A61Q3/02 ,  A61Q5/06 ,  A61Q19/00 ,  B29C33/62 ,  C08F220/24 ,  C08F222/1006 ,  C09D133/16 ,  D21H19/20 ,  Y10T428/3154 ,  C08F220/26

摘要： Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH2═C(—X)—C(═O)—Y—[—(CH2)m—Z—]p—(CH2)n—Rf (wherein X represents a hydrogen atom; Y represents —O— or —NH—; Z represents a direct bond, —S— or —SO2—; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH2═C(X′)—C(═O)—O—(RO)q—H (wherein X′ represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group.

摘要翻译： 公开了一种在水中具有足够稳定性的含氟共聚物，其能够为纸提供足够的耐油性。 含氟聚合物含有（a）由通式（I）表示的含氟单体CH 2 = C（-X）-C（= O）-Y - [ - （CH 2）m Z-） 对 - （CH 2）n -R f（其中X表示氢原子; Y表示-O-或-NH-; Z表示直接键，-S-或-SO 2 - ; Rf表示具有1-6个碳原子的氟代烷基 原子; m是1-10的数; n是0-10的数; p是0或1）和（b）由通式（II）表示的含烷氧基的单体CH 2 = C（X' ）-C（= O）-O-（RO）qH（其中X'表示氢原子或甲基; R表示具有2-4个碳原子的亚烷基，其中部分或全部氢原子可以被 羟基; q表示1-50的整数）。 含氟聚合物不含有具有氨基的单体。