Silicon-containing curing composition and heat cured product thereof
    1.
    发明申请
    Silicon-containing curing composition and heat cured product thereof 有权
    含硅固化组合物及其热固化产物

    公开(公告)号:US20070197755A1

    公开(公告)日:2007-08-23

    申请号:US10594221

    申请日:2005-05-10

    IPC分类号: C08L83/04 C08G77/04

    摘要: A curable composition which comprises at least one of the following (A), (B), and (C) and further contains the following (D) (provided that when (C) is not contained, both (A) and (B) are contained). (A): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has a reactive group A′ and one or more Si—O—Si bonds. (B): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has an Si—H group and one or more Si—O—Si bonds. (C): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has a reactive group A′, an Si—H group, and one or more Si—O—Si bonds. (D): A catalyst for curing reaction which is a platinum catalyst. The reactive group A′ is any of Si—R1, Si—O—R2, and Si—R3—OCOC(R4)═CH2, provided that R1 and R2 each is alkenyl, R3 is alkylene and/or arylene, and R4 is hydrogen or methyl.

    摘要翻译: 包含以下(A),(B)和(C)中的至少一个的可固化组合物,并且还包含以下(D)(前提是不含(C)时,(A)和(B) 被包含)。 (A):重均分子量为1000以下的成分的含量为20重量%的含硅聚合物。 %以下,具有反应性基团A'和一个或多个Si-O-Si键。 (B):重均分子量为1000以下的成分的含量为20重量%的含硅聚合物。 %以下,并且具有Si-H基和一个或多个Si-O-Si键。 (C):重均分子量为1000以下的成分的含量为20重量%的含硅聚合物。 %以下,具有反应性基团A',Si-H基和一个或多个Si-O-Si键。 (D):铂催化剂用于固化反应的催化剂。 反应性基团A'是Si-R 1,Si-OR 2和Si-R 3 -OCOC(R SUP)中的任何一种 > 4 ) - CH 2,条件是R 1和R 2各自为烯基,R 3, SUP>是亚烷基和/或亚芳基,R 4是氢或甲基。

    Silicon-containing compound, curable composition and cured product
    2.
    发明授权
    Silicon-containing compound, curable composition and cured product 失效
    含硅化合物,固化性组合物和固化物

    公开(公告)号:US08003736B2

    公开(公告)日:2011-08-23

    申请号:US12596933

    申请日:2008-04-21

    IPC分类号: C08F283/00

    CPC分类号: C08G77/50 C08L83/14 C08L83/00

    摘要: A silicon-containing compound of formula (1), and a curing composition containing a silicon-containing compound of formula (1) wherein Z is hydrogen, a silicon-containing compound of formula (1) wherein Z is C2-C4 alkenyl or alkynyl and a hydrosilylation catalyst. The composition has excellent handling and curing properties and provides a cured product with excellent heat resistance and flexibility. In formula (1), Ra-Rg=C1-C12 saturated aliphatic hydrocarbon group or C6-C12 aromatic hydrocarbon group. Re and Rf do not simultaneously represent C1-C12 saturated aliphatic hydrocarbon group; Y=C2-C4 alkylene; Z=hydrogen or C2-C4 alkenyl or alkynyl; K is 2-7; T is 1-7; P is 0-3; and M and N are numbers selected such that N:M=1:1 to 1:100, that all M's and N's total at least 15, and that the mass average molecular weight of the compound of formula (1) is 3,000 to 1,000,000.

    摘要翻译: 一种式(1)的含硅化合物和含有其中Z是氢的式(1)的含硅化合物的固化组合物,其中Z是C 2 -C 4烯基或炔基的式(1)的含硅化合物 和氢化硅烷化催化剂。 该组合物具有优异的处理和固化性能,并提供具有优异的耐热性和柔韧性的固化产物。 在式(1)中,Ra-Rg = C1-C12饱和脂族烃基或C6-C12芳族烃基。 Re和Rf不同时代表C1-C12饱和脂族烃基; Y = C2-C4亚烷基; Z =氢或C 2 -C 4烯基或炔基; K为2-7; T为1-7; P为0-3; 并且M和N是选择为N:M = 1:1至1:100的数字,所有M和N的总数至少为15,并且式(1)化合物的质均分子量为3,000至1,000,000 。

    Silicon-containing curing composition and heat cured product thereof
    3.
    发明授权
    Silicon-containing curing composition and heat cured product thereof 有权
    含硅固化性组合物以及它们的热固化产物

    公开(公告)号:US07939614B2

    公开(公告)日:2011-05-10

    申请号:US10594221

    申请日:2005-05-10

    摘要: A curable composition which comprises at least one of the following (A), (B), and (C) and further contains (D) (provided that when (C) is not contained, both (A) and (B) are in the composition. (A): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has a reactive group A′ and one or more Si—O—Si bonds. (B): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has an Si—H group and one or more Si—O—Si bonds. (C): A silicon-containing polymer in which the content of components having a weight-average molecular weight of 1,000 or lower is 20 wt. % or lower and which has a reactive group A′, an Si—H group, and one or more Si—O—Si bonds. (D): A catalyst for curing reaction which is a platinum catalyst. The reactive group A′ is any of Si—R1, Si—O—R2, and Si—R3—OCOC(R4)═CH2, provided that R1 and R2 each is alkenyl, R3 is alkylene and/or arylene, and R4 is hydrogen or methyl.

    摘要翻译: 一种可固化的组合物,其包含以下的(A)中的至少一种,(B),和(C),还含有(D)(条件是当(C)不包含,无论(A)和(B)是在 该组合物(A):含硅聚合物,其中具有1,000或更低的重均分子量成分的含量为20重量%或更低,其中有一个反应性基团A'和一个或多个SI- O-Si键(B):A含硅聚合物,其中具有1,000或更低的重均分子量成分的含量为20重量%或更低,其具有Si-H基和一个或多个 Si-O-Si键(C):其中重均分子量为1,000以下的成分的含量为20重量%以下且具有反应性基团A'的含硅聚合物, Si-H基和一个或多个Si-O-Si键;(D):作为铂催化剂的用于固化反应的催化剂,反应性基团A'是Si-R 1,Si-O-R 2和 的Si-R3 OCOC(R 4)═CH2,条件是R1和R2各自是链烯基,R 3是亚烷基和/或亚芳基,并且R 4是氢或甲基。

    SILICON-CONTAINING COMPOUND, CURABLE COMPOSITION AND CURED PRODUCT
    4.
    发明申请
    SILICON-CONTAINING COMPOUND, CURABLE COMPOSITION AND CURED PRODUCT 失效
    含硅化合物,可固化组合物和固化产品

    公开(公告)号:US20100179283A1

    公开(公告)日:2010-07-15

    申请号:US12596933

    申请日:2008-04-21

    IPC分类号: C08L83/00 C07F7/02 C08G77/12

    CPC分类号: C08G77/50 C08L83/14 C08L83/00

    摘要: A silicon-containing compound of formula (1), and a curing composition containing a silicon-containing compound of formula (1) wherein Z is hydrogen, a silicon-containing compound of formula (1) wherein Z is C2-C4 alkenyl or alkynyl and a hydrosilylation catalyst. The composition has excellent handling and curing properties and provides a cured product with excellent heat resistance and flexibility. In formula (1), Ra—Rg=C1-C12 saturated aliphatic hydrocarbon group or C6-C12 aromatic hydrocarbon group. Re and Rf do not simultaneously represent C1-C12 saturated aliphatic hydrocarbon group; Y═C2-C4 alkylene; Z=hydrogen or C2-C4 alkenyl or alkynyl; K is 2-7; T is 1-7; P is 0-3; and M and N are numbers selected such that N:M=1:1 to 1:100, that all M's and N's total at least 15, and that the mass average molecular weight of the compound of formula (1) is 3,000 to 1,000,000.

    摘要翻译: 一种式(1)的含硅化合物和含有其中Z是氢的式(1)的含硅化合物的固化组合物,其中Z是C 2 -C 4烯基或炔基的式(1)的含硅化合物 和氢化硅烷化催化剂。 该组合物具有优异的处理和固化性能,并提供具有优异的耐热性和柔韧性的固化产物。 在式(1)中,Ra-Rg = C1-C12饱和脂族烃基或C6-C12芳族烃基。 Re和Rf不同时代表C1-C12饱和脂族烃基; Y = C 2 -C 4亚烷基; Z =氢或C 2 -C 4烯基或炔基; K为2-7; T为1-7; P为0-3; 并且M和N是选择为N:M = 1:1至1:100的数字,所有M和N的总数至少为15,并且式(1)化合物的质均分子量为3,000至1,000,000 。

    Optical fiber
    6.
    发明授权
    Optical fiber 有权
    光纤

    公开(公告)号:US09297950B2

    公开(公告)日:2016-03-29

    申请号:US14116384

    申请日:2012-05-10

    摘要: Provided is an optical fiber which is provided with heat resistance and productivity and in which a transmission loss is suppressed even in a high-temperature environment. It has, on an outer periphery of a glass fiber composed of a core part and a cladding part, a coating layer made by crosslinking an energy-curable resin composition containing a silicon compound, in which the silicon compound contained in the energy-curable resin composition of the coating layer as an outermost layer has a specified structure having a cyclic silicone site having an epoxy group and a linear silicone site, with the content of the cyclic silicone site in the compound being from 10 to 30% by mass.

    摘要翻译: 提供具有耐热性和生产率的光纤,即使在高温环境下也能抑制传输损失。 在由芯部和包层部分构成的玻璃纤维的外周上,通过将含有硅化合物的能量固化树脂组合物交联而制成的涂层,其中包含在能量固化树脂中的硅化合物 作为最外层的涂层的组成具有具有环氧基和环状硅氧烷部位的环状硅氧烷部位的特定结构,化合物中的环状硅氧烷部位的含量为10〜30质量%。

    OPTICAL FIBER
    7.
    发明申请
    OPTICAL FIBER 有权
    光纤

    公开(公告)号:US20140199040A1

    公开(公告)日:2014-07-17

    申请号:US14116384

    申请日:2012-05-10

    IPC分类号: G02B6/02

    摘要: Provided is an optical fiber which is provided with heat resistance and productivity and in which a transmission loss is suppressed even in a high-temperature environment. It has, on an outer periphery of a glass fiber composed of a core part and a cladding part, a coating layer made by crosslinking an energy-curable resin composition containing a silicon compound, in which the silicon compound contained in the energy-curable resin composition of the coating layer as an outermost layer has a specified structure having a cyclic silicone site having an epoxy group and a linear silicone site, with the content of the cyclic silicone site in the compound being from 10 to 30% by mass.

    摘要翻译: 提供具有耐热性和生产率的光纤,即使在高温环境下也能抑制传输损失。 在由芯部和包层部分构成的玻璃纤维的外周上,通过将含有硅化合物的能量固化树脂组合物交联而制成的涂层,其中包含在能量固化树脂中的硅化合物 作为最外层的涂层的组成具有具有环氧基和环状硅氧烷部位的环状硅氧烷部位的特定结构,化合物中的环状硅氧烷部位的含量为10〜30质量%。

    Scanning probe microscope
    8.
    发明授权
    Scanning probe microscope 失效
    扫描探针显微镜提供地形图像和磁图像

    公开(公告)号:US5939715A

    公开(公告)日:1999-08-17

    申请号:US31641

    申请日:1997-02-27

    摘要: There is disclosed a scanning probe microscope capable of producing a topographic image and a magnetic image of a surface of a sample in one measurement. The microscope has a probe tip made of a magnetic material. A physical force, such as an atomic force, is exerted between the probe tip and the sample. When this physical force does not act on the probe tip, it vibrates at a first vibrational frequency. Displacements of the probe tip are detected by a photodetector. A topographic information-extracting portion including a voltage-to-current converter, a phase shifter, an FM demodulator, a low-pass filter, and an error amplifier extracts a signal representative of topographic information from the output from the photodetector. A magnetic distribution-extracting portion, including an oscillator and a lock-in amplifier, extracts information about the magnetism of the sample from the output from the photodetector.

    摘要翻译: 公开了一种能够在一次测量中产生样品表面的地形图像和磁性图像的扫描探针显微镜。 显微镜具有由磁性材料制成的探针尖端。 在探针尖端和样品之间施加诸如原子力的物理力。 当该物理力不作用于探针尖端时,其以第一振动频率振动。 探针尖端的位移由光检测器检测。 包括电压 - 电流转换器,移相器,FM解调器,低通滤波器和误差放大器的地形信息提取部分从光电检测器的输出中提取表示地形信息的信号。 包括振荡器和锁定放大器的磁分布提取部分从光电检测器的输出中提取关于样品的磁性的信息。

    Scanning probe microscope
    9.
    发明授权
    Scanning probe microscope 失效
    扫描探针显微镜

    公开(公告)号:US6005246A

    公开(公告)日:1999-12-21

    申请号:US111971

    申请日:1998-07-08

    摘要: There is disclosed a scanning probe microscope capable of producing a topographic image at a high resolution with a cantilever of a large spring constant and, at the same time, a surface potential image at a high resolution. This microscope can take the form of an atomic force microscope that detects the surface potential of a sample, using a force gradient acting between the probe tip and the sample. The gradient is represented by the output from a frequency-to-voltage converter.

    摘要翻译: 公开了一种扫描探针显微镜,能够以大的弹簧常数的悬臂以高分辨率产生地形图像,同时以高分辨率产生表面电位图像。 该显微镜可以采用原子力显微镜的形式,使用在探针尖端和样品之间作用的力梯度来检测样品的表面电位。 梯度由频率 - 电压转换器的输出表示。