公开(公告)号：US5821301A

公开(公告)日：1998-10-13

申请号：US835568

申请日：1997-04-09

申请人： Tatsuo Tsuneka ,  Takafumi Masuda ,  Kenichiro Isomoto ,  Teruaki Ashihara ,  Shozo Maekawa ,  Tetsuzo Nishioka ,  Ryozo Orita

发明人： Tatsuo Tsuneka ,  Takafumi Masuda ,  Kenichiro Isomoto ,  Teruaki Ashihara ,  Shozo Maekawa ,  Tetsuzo Nishioka ,  Ryozo Orita

IPC分类号： C08F8/20 ,  C09D123/28 ,  C09D151/06 ,  C08F10/00

CPC分类号： C09D151/06 ,  C08F8/20 ,  C09D123/28

摘要： Disclosed is a modified chlorinated polyolefin resin composition, as well as a method for producing the same, which has adhesion to polyolefin substrates without the need of steam-washing or degreasing the polyolefin surface with chlorine-based organic solvents such as trichloroethane, and which is improved in such properties as interlayer adhesion to base-coats and/or top-coats and gasohol resistance. The modified polyolefin resin composition for polyolefin resin paints comprises: a chlorinated polyolefin having an acid value of 1 to 500 mg.multidot.KOH/g, which is obtained by chlorinating a polyolefin modified with one kind, or more than one kind, of compounds selected from a group consisting of .alpha., .beta.-unsaturated carboxylic acids and/or acid anhydrides thereof in a range of 1 to 50% by weight; and a compound and/or a resin thereof having one epoxy group per molecule represented by the structural formula as described in the specification.

摘要翻译： 公开了一种改性氯化聚烯烃树脂组合物及其制造方法，其具有与聚烯烃基材的粘合性，而不需要用氯基有机溶剂如三氯乙烷进行蒸汽洗涤或脱脂聚烯烃表面，并且其是 改进了诸如层间粘合到底涂层和/或顶涂层和耐汽油醇的性能。 用于聚烯烃树脂涂料的改性聚烯烃树脂组合物包括：酸值为1至500mgxKOH / g的氯化聚烯烃，其通过氯化由一种或多种选自下组的化合物 由α，β-不饱和羧酸和/或其酸酐在1至50重量％的范围内组成; 以及每分子具有一个环氧基的化合物和/或树脂，由说明书中所述的结构式表示。

公开(公告)号：US06277912B1

公开(公告)日：2001-08-21

申请号：US09063891

申请日：1998-04-22

申请人： Teruaki Ashihara ,  Tadanori Funasaka ,  Shoji Maekawa ,  Ryozo Orita

发明人： Teruaki Ashihara ,  Tadanori Funasaka ,  Shoji Maekawa ,  Ryozo Orita

IPC分类号： C08L5104

CPC分类号： C08F287/00 ,  C08F8/20 ,  C08F255/02 ,  C08F255/023 ,  C08L51/06 ,  C08L2666/14

摘要： An aqueous, chlorinated modified polyolefin-based resin composition and its manufacture, which resin composition provides, as an adhesive, a paint for ink, a coating material, etc., moldings and films consisting mainly of polyolefin-based resins with a coating film excellent at the properties such as adhesiveness, gasohol resistance, moisture resistance, impact resistance, flexibility, etc. and which resin composition is particularly good at environmental conservation, safety, and health and hygiene because the resin composition doesn't contain organic solvents including aromatic solvents such as xylene, toluene, etc.

摘要翻译： 一种氯化改性聚烯烃基树脂组合物及其制造方法，该树脂组合物作为粘合剂提供油墨用涂料，涂料等，主要由聚烯烃类树脂组成的成膜和膜，其涂膜具有优异的性能 在粘合性，耐汽油性，耐湿性，耐冲击性，柔软性等性质方面，由于树脂组合物不含有芳香族溶剂等有机溶剂，所以树脂组合物在环境保护，安全性，健康卫生上特别优异 如二甲苯，甲苯等

公开(公告)号：US5130373A

公开(公告)日：1992-07-14

申请号：US698779

申请日：1991-05-13

申请人： Teruaki Ashihara ,  Shingo Tone ,  Ryozo Orita

发明人： Teruaki Ashihara ,  Shingo Tone ,  Ryozo Orita

IPC分类号： C08J7/04 ,  C08F290/04 ,  C09D123/26 ,  C09D123/28 ,  C09D151/04 ,  C09D151/06 ,  C09D155/00

CPC分类号： C09D155/005 ,  C08F290/04 ,  C09D151/04 ,  C09D151/06

摘要： Polyolefin type coating resin compositions obtained by copolymerizing acrylic type oligomers, polydienes, acrylic type monomers and chlorinated polyolefins containing 10-60 weight % chlorine in the existence or the absence of the Hardener. The obtained copolymers are used for coatings, printing inks or adhesives applying as one coat finish or primer to give excellent coating films of adhesive property, solvent resistance and the appearance.

摘要翻译： 在存在或不存在固化剂的情况下通过丙烯酸类低聚物，聚二烯，丙烯酸类单体和含有10-60重量％氯的氯化聚烯烃共聚获得的聚烯烃类涂料树脂组合物。 所获得的共聚物用于作为一个涂层或底漆施加的涂料，印刷油墨或粘合剂，以提供优异的粘合性，耐溶剂性和外观的涂膜。

公开(公告)号：US5349022A

公开(公告)日：1994-09-20

申请号：US847307

申请日：1992-03-06

申请人： Teruaki Ashihara ,  Shingo Tone ,  Toshimitsu Saito ,  Ryozo Orita

发明人： Teruaki Ashihara ,  Shingo Tone ,  Toshimitsu Saito ,  Ryozo Orita

IPC分类号： C08F2/18 ,  C08F2/20 ,  C08F2/38 ,  C08F2/44 ,  C08F255/02 ,  C08F289/00 ,  C08F290/08 ,  C09D4/00 ,  C09D4/02 ,  C09J4/02 ,  C08K3/26 ,  C08L13/02

CPC分类号： C08F290/08 ,  C08F255/023

摘要： Non-organic solvent, non-polluting and stable emulsions of modified chlorinated polyolefins are prepared by dissolving chlorinated polyolefins and oligomers of a (metha)acrylate system uniformly in a (metha)acrylate monomer in the presence or absence of catalyst or chain transfer moderator, and suspension polymerization is achieved in an aqueous solvent. The obtained suspensions are stable more than 3 months at room temperature, and these emulsions give one coat coating films and primer coating films which have good properties such as good adhesion, and waterproof and weatherproof properties.

摘要翻译： 通过在催化剂或链转移调节剂存在或不存在下将（甲基）丙烯酸酯体系的氯化聚烯烃和（甲基）丙烯酸酯体系的低聚物均匀地溶解在（甲基）丙烯酸酯单体中来制备改性氯化聚烯烃的非有机溶剂，无污染和稳定的乳液， 并且在水性溶剂中实现悬浮聚合。 所获得的悬浮液在室温下稳定3个月以上，这些乳液得到一种具有良好粘附性，防水防风性等良好性能的涂膜和底漆涂膜。

公开(公告)号：US5143976A

公开(公告)日：1992-09-01

申请号：US640733

申请日：1991-01-16

申请人： Teruaki Ashihara ,  Shingo Tone ,  Ryozo Orita

发明人： Teruaki Ashihara ,  Shingo Tone ,  Ryozo Orita

IPC分类号： C08J7/04 ,  C08F290/00 ,  C08F291/00 ,  C08F299/00 ,  C08F299/02 ,  C08G18/63 ,  C08L51/06 ,  C09D151/00 ,  C09D151/06 ,  C09D155/00

CPC分类号： C08G18/633 ,  C08F299/00 ,  C08F299/022 ,  C09D151/00

摘要： The present invention concerns the polyolefin resin compositions wherein acrylic oligomers, polydiene and chlorinated polyolefins which contain 10-60 weight % chlorine are graft copolymerized. Films of the polyolefin resin compositions have good adhesive properties, moisture-resistant properties and appearance.

摘要翻译： 本发明涉及聚烯烃树脂组合物，其中含有10-60重量％氯的丙烯酸低聚物，聚二烯和氯化聚烯烃被接枝共聚。 聚烯烃树脂组合物的膜具有良好的粘合性，耐湿性和外观。

公开(公告)号：US20050124753A1

公开(公告)日：2005-06-09

申请号：US10972914

申请日：2004-10-26

申请人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

发明人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

IPC分类号： C08J3/00 ,  C08J3/05 ,  C08J7/04 ,  C08K3/00 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  C08L53/00 ,  C09D123/10 ,  C09J151/06 ,  C09J153/00

CPC分类号： C08J3/05 ,  C08J3/005 ,  C08J7/047 ,  C08J2323/10 ,  C08J2423/00 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/04 ,  C09D123/10 ,  C09J151/06 ,  C09J153/00 ,  C08L2666/06 ,  C08L2666/24

摘要： A polypropylene type aqueous dispersion comprising the following components (a) to (c): (a) a polypropylene type polymer100parts by weight and/or a modified polypropylene type polymer (b) a surfactant1 to 100parts by weight, and (c) water100 to 1,000parts by weight, wherein the component (a) has a main chain having the following features (1) and (2) and dispersion particles in the dispersion have an average particle size of at most 0.5 μm, Feature (1) when observing a peak derived from a carbon atom of a methyl group in a propylene unit chain part comprising a head-to-tail bond by 13C-NMR and fixing a chemical shift of a peak top at a peak attributable to pentad expressed by mmmm to 21.8 ppm, a ratio (S1/S) of an area S1 of a peak of a peak top at 21.8 ppm to a total area S of peaks at from 19.8 ppm to 22.1 ppm is at least 10% and at most 60%, and when an area of a peak (mmmr) of a peak top at 21.5 to 21.6 ppm is expressed as S2, 4+2S1/S2>5, and Feature (2) a content ratio (mol ratio) of propylene unit (A): other olefin unit (B) is from 100:0 to 90:10.

公开(公告)号：US20050075441A1

公开(公告)日：2005-04-07

申请号：US10986341

申请日：2004-11-12

申请人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

发明人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

IPC分类号： C08F8/00 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/08 ,  C08L51/00 ,  C08L51/06 ,  C09J151/00 ,  C09J151/06 ,  C08K5/34 ,  C08L51/08

CPC分类号： C09J151/006 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/083 ,  C08L51/006 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  C08F222/06

摘要： This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.

公开(公告)号：US07122604B2

公开(公告)日：2006-10-17

申请号：US10986341

申请日：2004-11-12

申请人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

发明人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

IPC分类号： C08F255/02

CPC分类号： C09J151/006 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/083 ,  C08L51/006 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  C08F222/06

摘要： This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.

公开(公告)号：US07659356B2

公开(公告)日：2010-02-09

申请号：US12185225

申请日：2008-08-04

申请人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

发明人： Teruaki Ashihara ,  Masato Onoe ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Yukihito Zanka ,  Kouichi Nakayama

IPC分类号： C08F210/00 ,  C08F110/06 ,  C08F20/06 ,  C08F283/04 ,  C08G65/32

CPC分类号： C08J3/05 ,  C08J3/005 ,  C08J7/047 ,  C08J2323/10 ,  C08J2423/00 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/04 ,  C09D123/10 ,  C09J151/06 ,  C09J153/00 ,  C08L2666/06 ,  C08L2666/24

摘要： A polypropylene type aqueous dispersion comprising the following components (a) to (c): (a)a polypropylene type polymer100parts by weight and/or a modified polypropylene type polymer (b)a surfactant1 to 100parts by weight, and (c)water100 to 1,000parts by weight, wherein the component (a) has a main chain having the following features (1) and (2) and dispersion particles in the dispersion have an average particle size of at most 0.5 μm, Feature (1) when observing a peak derived from a carbon atom of a methyl group in a propylene unit chain part comprising a head-to-tail bond by 13C-NMR and fixing a chemical shift of a peak top at a peak attributable to pentad expressed by mmmm to 21.8 ppm, a ratio (S1/S) of an area S1 of a peak of a peak top at 21.8 ppm to a total area S of peaks at from 19.8 ppm to 22.1 ppm is at least 10% and at most 60%, and when an area of a peak (mmmr) of a peak top at 21.5 to 21.6 ppm is expressed as S2, 4+2S1/S2>5, andFeature (2) a content ratio (mol ratio) of propylene unit (A): other olefin unit (B) is from 100:0 to 90:10.

摘要翻译： 包含以下组分（a）至（c）的聚丙烯型水性分散体：（a）100重量份的聚丙烯类聚合物和/或改性聚丙烯类聚合物（b）1至100重量份的表面活性剂和（ c）水100-1000重量份，其中组分（a）具有具有以下特征（1）和（2）的主链，并且分散体中的分散体颗粒具有至多0.5μm的平均粒径特征（ 1）当通过13 C-NMR观察由包含头 - 尾键的丙烯单元链部分中的甲基的碳原子衍生出的峰时，并且将峰顶的化学位移固定为归因于由 在21.8ppm的峰值峰值的面积S1与19.8ppm至22.1ppm的峰面积S的比值（S1 / S）至少为10％且至多为60％ ，21.5〜21.6ppm的峰顶的面积（mmmr）表示为S2，4 + 2S1 / S2> 5，特征（2）的含量比（mol 丙烯单元（A）的比例）：其它烯烃单元（B）为100:0至90:10。

公开(公告)号：US06887943B2

公开(公告)日：2005-05-03

申请号：US10284241

申请日：2002-10-31

申请人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

发明人： Masato Onoe ,  Teruaki Ashihara ,  Kazuyuki Hata ,  Fumihiko Shimizu ,  Naomasa Sato ,  Akio Tanna

IPC分类号： C08F8/00 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/08 ,  C08L51/00 ,  C08L51/06 ,  C09J151/00 ,  C09J151/06

CPC分类号： C09J151/006 ,  C08F255/02 ,  C08F255/04 ,  C08F287/00 ,  C08F297/083 ,  C08L51/006 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  C08F222/06

摘要： This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.

摘要翻译： 本发明提供一种不含卤素的接枝改性聚丙烯聚合物，其溶解性等某些性能优异，能够提高结晶性丙烯类聚合物基材的粘合性和涂布能力，以及含有它们的组合物。 特别是提供一种丙烯聚合物，其含有具有含有全同立构嵌段的立体嵌段结构的丙烯聚合物主链和含有羧酸基，酸酐基或羧酸酯基的侧链，其中当其 在25℃下溶解于甲苯浓度为10重量％，不溶物为总重量的1重量％以下，以及含有该聚合物的组合物。