摘要:
In a process for producing a hydrogen-containing gas, a hydrocarbon feed gas and steam are introduced into a reaction vessel containing a complex metal oxide and steam-hydrocarbon reforming catalyst thereby forming a combustible gas mixture comprising hydrogen. A regeneration gas comprising greater than 0.1 volume % oxygen up to and including 2 volume % oxygen is introduced into the reaction vessel to displace at least a portion of the combustible gas mixture from the reaction vessel. Subsequently, additional regeneration gases may be introduced into the reaction vessel. Numerous means for providing various regeneration gases are presented.
摘要:
In a process for producing a hydrogen-containing gas, a hydrocarbon feed gas and steam are introduced into a reaction vessel containing a complex metal oxide and steam-hydrocarbon reforming catalyst thereby forming a combustible gas mixture comprising hydrogen. A regeneration gas comprising greater than 0.1 volume % oxygen up to and including 2 volume % oxygen is introduced into the reaction vessel to displace at least a portion of the combustible gas mixture from the reaction vessel. Subsequently, additional regeneration gases may be introduced into the reaction vessel. Numerous means for providing various regeneration gases are presented.
摘要:
A process for producing a hydrogen-containing product gas by catalytic steam-hydrocarbon reforming with an overall steam-to-carbon molar ratio between 1.5 and 2.4 for the process. The process stream is reacted in at least two prereformers prior to reaction in catalyst-containing tubes in a top-fired reformer furnace. The process stream is reacted adiabatically in the first prereformer, while the process stream is heated prior to being introduced into the second prereformer and/or the second prereformer is heated. The process avoids carbon formation on the catalyst in the catalyst-containing tubes in the primary reformer.
摘要:
CO2 sorptive pellets and/or granules and their use for removing CO2 from CO2-containing gases and for producing hydrogen. CO2 sorptive pellets are suitable for use in fixed bed reactors and the like due to sufficient crush strength. CO2 sorptive granules are suitable for moving, ebullated, expanded and fluidized beds. The CO2 sorptive pellets and/or granules comprise calcium oxide and/or magnesium oxide and at least one binding agent such as calcium titanate, calcium aluminate, calcium zirconate, magnesium titanate, magnesium aluminate, and magnesium zirconate. A method for making the CO2-sorptive pellets is described. The CO2 sorptive pellets optionally comprise at Ni, Pd, Pt, and/or Rh.
摘要翻译:CO2吸附颗粒和/或颗粒,以及它们用于从含CO 2气体中除去CO 2和用于产生氢的用途。 CO 2吸附颗粒由于足够的压碎强度而适合用于固定床反应器等。 CO2吸附颗粒适用于移动,沸腾,膨胀和流化床。 CO 2吸附性颗粒和/或颗粒包含氧化钙和/或氧化镁和至少一种结合剂,例如钛酸钙,铝酸钙,锆酸锆,钛酸镁,铝酸镁和锆酸镁。 描述了制备二氧化碳吸附颗粒的方法。 CO 2吸附颗粒任选地包含Ni,Pd,Pt和/或Rh。
摘要:
A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.
摘要:
The present invention provides a process for making a complex metal oxide comprising the formula AxByOz. The process comprises the steps of: (a) reacting in solution at a temperature of between about 75° C. to about 100° C. at least one water-soluble salt of A, at least one water-soluble salt of B and a stoichiometric amount of a carbonate salt or a bicarbonate salt required to form a mole of a carbonate precipitate represented by the formula AxBy(CO3)n, wherein the reacting is conducted in a substantial absence of carbon dioxide to form the carbonate precipitate and wherein the molar amount of carbonate salt or bicarbonate salt is at least three times the stoichiometric amount of carbonate or bicarbonate salt required to form a mole of the carbonate precipitate; and (b) reacting the carbonate precipitate with an oxygen containing fluid under conditions to form the complex metal oxide.
摘要:
An apparatus for treatment a substrate with an activated reactive gas which includes a processing chamber, an exhaust manifold, a conveyor adapted to sequentially introduce into the processing chamber untreated portions of the substrate for said treatment and to sequentially remove from the processing chamber treated portions of the substrate, wherein the length of the substrate exceeds a dimension of the inner volume of the processing chamber, a distribution conduit disposed in the processing chamber, wherein the length of the distribution conduit is approximately equal to the width of the substrate, and wherein the distribution conduit has a number (N) of openings, each opening has a cross sectional area (Ao), a cross sectional area of the distribution conduit (Ac), and wherein a maximum cross-sectional area (N*Ao) of the openings can be determined by the following expression: 1.0*Ac>N*Ao≧0.1*Ac.
摘要翻译:一种用活性反应性气体处理衬底的设备,其包括处理室,排气歧管,适于顺次向处理室中引入未经处理的用于所述处理的衬底的部分的传送器,并且从处理室中顺次地将处理的部分 所述基板,其中所述基板的长度超过所述处理室的内部体积的尺寸;布置在所述处理室中的分配导管,其中所述分配导管的长度近似等于所述基板的宽度,并且其中, 分配导管具有数个(N)个开口,每个开口具有横截面面积(A SUB),分配导管(A SUB C)的横截面面积, 并且其中开口的最大横截面积(N * A)可以通过以下表达式来确定:1.0 * A sub> N * A < ○ SUB> = 0.1 * A SUB>。
摘要:
A method of producing an electrochromic device, includes the steps of: providing a first electron conducting layer on a substrate, providing a working electrode in communication with the first electron conducting layer, providing an ion conducting layer in communication with the working electrode, providing an ion storage electrode in communication with the ion conducting layer, and providing a second electron conducting layer in communication with the ion storage electrode, wherein at least one and less than all of the providing steps include(s) plasma chemical vapor deposition. An electrochromic device produced by the method of the invention is disclosed, as is an apparatus adapted to perform the method of the invention, including plasma CVD devices and vacuum sputtering devices.
摘要:
A method and apparatus for introducing an oxidant mixed with a carrier gas into pre-heating zone of a continuous furnace for effectively removing lubricant from powder metal compacts prior to sintering at high temperatures. Mixing a controlled amount of a gaseous oxidizing agent such as moisture, carbon dioxide, air or mixtures thereof with a carrier gas and introducing the mixture into the preheating zone of a continuous furnace under controlled conditions accelerates removal of lubricant from powder metal compacts prior to sintering at high temperature by decomposing lubricant vapors into smaller and more volatile hydrocarbons, produces sintered components with close to soot- and residue-free surfaces and with the desired physical properties, prolongs the life of furnace components including muffles and belts, and reduces downtime, maintenance and operating costs.
摘要:
The present invention discloses novel nitrogen-hydrogen based atmospheres for sintering steel components in continuous furnaces with consistent quality and properties while prolonging the life of the wire mesh belts, reducing maintenance costs, and improving furnace productivity. Specifically, it discloses the use of a controlled amount of an oxidizing agent such as moisture, carbon dioxide, nitrous oxide, or mixtures thereof along with nitrogen-hydrogen atmospheres. The amount of an oxidizing agent added to the nitrogen-hydrogen atmospheres to pre-condition belt material prior to its use for sintering and to sinter steel components is controlled in such a way that atmospheres become oxidizing to the belt material but reducing to steel components being sintered, specifically in the high heating and cooling zones of continuous furnaces.