Aqueous coating composition
    2.
    发明授权
    Aqueous coating composition 失效
    水性涂​​料组合物

    公开(公告)号:US5151125A

    公开(公告)日:1992-09-29

    申请号:US703804

    申请日:1991-05-21

    摘要: Disclosed is an aqueous metallic coating composition which significantly reduces the production of hydrogen gas and does not have the problems which are brought about from hydrophobic segments. The composition can be stored for a long period of time and provide a metallic coating having good appearance and film properties (e.g. water resistance and adhesive properties with substrates). The aqueous coating composition of the present invention comprises(a) an acryl resin having a number average molecular weight of 1,000 to 50,000, an acid value of 15 to 200 and a hydroxyl value of 20 to 200, prepared by copolymerizing an ethylenic monomer and a phosphate monomer represented by ##STR1## [wherein X represents a hydrogen atom or a methyl group, Y represents an alkylene group having 2 to 4 carbon atoms and n is an integer of 3 to 30.] and(b) a pigment;the acryl resin being present in an amount of 2 to 500 parts by weight, based on 100 parts by weight of the pigment.

    摘要翻译: 公开了一种显着降低氢气产生的水性金属涂料组合物,并且不具有从疏水链段引起的问题。 该组合物可以长期储存并提供具有良好外观和膜性质(例如耐水性和与基材的粘合性)的金属涂层。 本发明的水性涂料组合物包含(a)通过使乙烯类单体和乙烯类单体共聚制备的数均分子量为1,000〜50,000,酸值为15〜200,羟基值为20〜200的丙烯酸树脂 由下式表示的磷酸酯单体(I)[式中,X表示氢原子或甲基,Y表示碳原子数2〜4的亚烷基,n表示3〜30的整数。]和(b)颜料 ; 基于100重量份的颜料,丙烯酸树脂以2至500重量份的量存在。

    Metallic pigment composition and water borne coating composition thereof
    4.
    发明授权
    Metallic pigment composition and water borne coating composition thereof 失效
    金属颜料组合物及其水性涂料组合物

    公开(公告)号:US5057156A

    公开(公告)日:1991-10-15

    申请号:US502771

    申请日:1990-04-02

    摘要: Disclosed is a metallic pigment composition which is stably dispersed in a water borne coating composition and which also provides with smooth coatings having superior water resistance. The metallic pigment composition comprises a metallic pigment and a phosphorous compound represented by the following formula (I) or (II); ##STR1## wherein l and 0 or 1, m is an integer of 1 to 4, R.sub.1, R.sub.2 R.sub.7 and R.sub.8 represent aliphatic, alicyclic or aromatic hydrocarbon groups which are the same or different, selected from a hydrogen atom, a C.sub.1 -C.sub.24 aliphatic hydrocarbon group, a C.sub.3 -C.sub.24 alicyclic hydrocarbon group or a C.sub.6 -C.sub.24 aromatic hydrocarbon group, and R.sub.1 has a valence of m, R.sub.3, R.sub.4, R.sub.5 and R.sub.6, which are the same or different, represent C.sub.1 -C.sub.3 aliphatic hydrocarbon group or a C.sub.6 or C.sub.7 aromatic hydrocarbon group, ##STR2## wherein n is 0, 1 or 2, p is an integer of 1 to 3, n+P equals 3, q is 0 or 1, R.sub.9, R.sub.14 and R.sub.15, which are the same or different, represent a hydrogen atom, a C.sub.1 -C.sub.24 aliphatic hydrocarbon group, a C.sub.3 -C.sub.24 alicyclic hydrocarbon group or a C.sub.6 -C.sub.24 aromatic hydrocarbon group, R.sub.10, R.sub.11, R.sub.12 and R.sub.13, which are the same or different, represent a C.sub.1 -C.sub.3 aliphatic hydrocarbon group or a C.sub.6 or C.sub.7 aromatic hydrocarbon group;the phosphorus compound being present in an amount of 0.5 to 200 parts by weight based on 100 parts by weight of the metallic pigment.The present invention also provides a water borne coating composition which contains the metallic pigment composition.

    Aqueous coating composition containing fine particles of water insoluble
resin solution
    7.
    发明授权
    Aqueous coating composition containing fine particles of water insoluble resin solution 失效
    水性涂​​料组合物含有水不溶性树脂溶液的微粒

    公开(公告)号:US4731409A

    公开(公告)日:1988-03-15

    申请号:US11211

    申请日:1987-02-03

    CPC分类号: C09D5/02

    摘要: An aqueous coating composition comprising (A) an aqueous medium, (B) at least one water soluble or dilutable resin which has a water tolerance of 4 or more and whose 1% by weight aqueous solution shows a surface tension of 51 dyne/cm or less, and (C) fine particles of resinous solution of water insoluble resin in a hydrophobic solvent, the particles being uniformly dispersed in the combination of said aqueous medium (A) and the water soluble or dilutable resin (B) and having a mean diameter of 1.mu. or less, which is characterized in that the absolute value of difference in solubility parameter (.vertline..DELTA.Sp.vertline.) between said resinous solution and said water soluble or dilutable resin is within a range of .vertline..DELTA.Sp.vertline.

    摘要翻译: 一种水性涂料组合物,其包含(A)水性介质,(B)至少一种水溶性或可稀释的树脂,其耐水性为4以上,并且其1重量%的水溶液表现出51达因/厘米的表面张力或 少量,(C)水不溶性树脂的树脂溶液在疏水性溶剂中的微细颗粒,均匀分散在所述水性介质(A)和水溶性或可稀释树脂(B)的组合中,其平均直径 其特征在于,所述树脂溶液和所述水溶性或可稀释树脂之间的溶解度参数(| DELTA Sp|)的差异绝对值在| DELTA Sp| <2的范围内。 本涂料组合物的储存稳定性和施加特性优异,得到具有优异光泽和表面光滑度的涂料。

    Aqueous coating composition, and its production
    8.
    发明授权
    Aqueous coating composition, and its production 失效
    水性涂​​料组合物及其制备

    公开(公告)号:US4528318A

    公开(公告)日:1985-07-09

    申请号:US462235

    申请日:1983-01-31

    CPC分类号: C09D201/06

    摘要: An aqueous coating composition which comprises an aqueous resin having a carboxyl group (I) and a water-insoluble resin powder (II), the aqueous resin (I) being the one dispersible or soluble into an aqueous medium by ionization when the carboxyl group is neutralized with a basic substance, and the water-insoluble resin powder (II) being the one of 5 to 100 in acid value obtained by reaction between a carboxyl group-containing resin of 20 to 300 in acid value in a solid state at room temperature and a monoepoxy compound or a monoisocyanate compound.

    摘要翻译: 一种水性涂料组合物,其包含具有羧基(I)和水不溶性树脂粉末(II)的水性树脂,所述水性树脂(I)是当所述羧基为羧基时,通过离子化可分散或溶解于水性介质中的水性树脂 用碱性物质中和,水溶性树脂粉末(II)为酸值的5〜100的酸值,通过在室温下的固体状态的酸值为20〜300的羧基树脂反应而得到 和单环氧化合物或单异氰酸酯化合物。

    Resinous particles for coating composition and its production
    9.
    发明授权
    Resinous particles for coating composition and its production 失效
    用于涂料组合物的树脂颗粒及其生产

    公开(公告)号:US4365043A

    公开(公告)日:1982-12-21

    申请号:US777548

    申请日:1977-03-14

    摘要: A process for preparing resinous particles for a coating composition, which comprises the steps of (1) subjecting an aqueous resin composition having an ionic group and no material solubility or dispersibility in water is dissolved or dispersed in an aqueous medium by at least partly neutralizing the ionic group to treatment with a powdering agent while applying thereto an operation for pulverization to deposit the resin in a particulate form and (2) recovering the deposited resinous particles from the aqueous medium.

    摘要翻译: 一种制备用于涂料组合物的树脂颗粒的方法,其包括以下步骤:(1)将具有离子性基团的水性树脂组合物在水中的溶解性或分散性不受物质溶解或分散在水性介质中,至少部分中和 用粉末化剂处理,同时施加粉碎操作以将树脂沉积成颗粒形式,和(2)从水性介质中回收沉积的树脂颗粒。

    Resin dispersion type aqueous coating composition comprising
microparticles of 1 .mu.m or less
    10.
    发明授权
    Resin dispersion type aqueous coating composition comprising microparticles of 1 .mu.m or less 失效
    含有1μm以下的微粒的树脂分散型水性涂料组合物

    公开(公告)号:US5037865A

    公开(公告)日:1991-08-06

    申请号:US339822

    申请日:1989-01-23

    摘要: A resin dispersion type aqueous coating composition comprising a continuous phase of water medium and an aqueous resin and water insoluble resin microparticles uniformly dispersed, as a discontinuous phase, in said continuous phase, which is characterized in that said water insoluble resin is prepared by the reaction of a resin which is liquid at room temperatures and bears in its molecule functional groups capable of reacting with an epoxy or isocyanate group, and an epoxy compound or an isocyanate compound so as to give 10.about.100% reaction rate of the epoxy or isocyanate group contained in said compound. The present aqueous coating composition is excellent in its application characteristics and can give a coating with excellent gloss and smoothness.

    摘要翻译: 树脂分散水漆。 包含(a)连续相,由aq。 介质和水性树脂,(b)由水不溶性树脂制成的分散相。 通过使环氧化物或异氰酸酯与cpd反应。 对比 功能性GPS。 其与环氧树脂或异氰酸酯gps反应。 使环氧或异氰酸酯gps的反应比例。 是10-100%。 水洗鞋 树脂可以用有机溶剂配制。