公开(公告)号：US5532054A

公开(公告)日：1996-07-02

申请号：US307031

申请日：1994-09-16

申请人： Tomohita Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Misao Masuda ,  Satoru Kishi ,  Chiaki Maruko

发明人： Tomohita Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Misao Masuda ,  Satoru Kishi ,  Chiaki Maruko

IPC分类号： B29B9/14 ,  B29B15/12 ,  B29C70/14 ,  D04H1/00

CPC分类号： B29B15/122 ,  B29B9/14 ,  B29C70/14 ,  B29K2307/00 ,  B29K2309/08 ,  Y10T428/249945 ,  Y10T428/249946 ,  Y10T428/26 ,  Y10T428/2904 ,  Y10T428/2918 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2964 ,  Y10T428/2971 ,  Y10T428/298 ,  Y10T428/2982 ,  Y10T428/2996 ,  Y10T428/2998

摘要： A molding material shaped like a plate and comprising a composite of continuous fibers and thermoplastic resin wherein each of the filaments which form the continuous fiber is coated around the surface thereof with the thermoplastic resin. Although the molding material has a high density of reinforcing fibers therein, it provides excellent distribution of fibers in the molding process; few of its fibers are broken, and its mechanical strength is considerably enhanced when its specific surface is made larger than a certain value. This molding material can be used for injection, extrusion and compression moldings.

摘要翻译： 一种成形为板状的成型材料，包括连续纤维和热塑性树脂的复合材料，其中形成连续纤维的每根长丝在其表面上涂覆有热塑性树脂。 虽然模塑材料在其中具有高密度的增强纤维，但是其在模制过程中提供了优异的纤维分布; 很少的纤维被破坏，并且当其比表面大于一定值时，其机械强度显着提高。 该成型材料可用于注射，挤出和压缩模塑。

公开(公告)号：US5043419A

公开(公告)日：1991-08-27

申请号：US261520

申请日：1988-10-24

申请人： Masahiro Ohta ,  Saburo Kawashima ,  Shoji Tamai ,  Hideaki Oikawa ,  Akihiro Yamaguchi ,  Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Misao Masuda ,  Satoru Kishi ,  Chiaki Maruko

发明人： Masahiro Ohta ,  Saburo Kawashima ,  Shoji Tamai ,  Hideaki Oikawa ,  Akihiro Yamaguchi ,  Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Misao Masuda ,  Satoru Kishi ,  Chiaki Maruko

IPC分类号： C08G73/10 ,  C08K7/04 ,  C08L79/08

CPC分类号： C08K7/04 ,  C08G73/1014 ,  C08G73/105 ,  C08G73/1064 ,  C08L79/08

摘要： This invention relates to a method for preparing a polyimide having good heat-stability and excellent flowability in a molten state.The polymide is prepared by reacting aromatic diamines such as 4,4'-bis(3-aminophenoxy)biphenyl, bis[4-(3-aminophenoxy)phenyl] ketone and bis [4-(3-aminophenoxy)phenyl] sulfone; tetracarboxylic dianhydrides such as pyromellitic dianhydride, 3,3', 4,4'-benzophenonetetracarboxylic dianhydride and bis(3,4-dicarboxyphenyl) ether dianhydride; and dicarboxylic anhydrides such as glutaric anhydride, 1,2-hexanedicarboxylic anhydride, phthalic anhydride and 3,4-benzophenonedicarboxylic anhydride. The molar ratio of aromatic diamine: tetracarboxylic dianhydride: dicarboxylic anhydride is 1:(0.9 to 1.0):(0.001 to 1.0).The invention also relates to polyimide composite materials which are excellent in mechanical strengths and processability. The materials contain the polyimide and fibrous reinforcing materials such as yarn, roving, tow, fabrics, mats and felts of glass fiber, carbon fibers or aromatic polyamide fibers.

公开(公告)号：US06613423B1

公开(公告)日：2003-09-02

申请号：US08169621

申请日：1993-12-20

申请人： Hideo Sakai ,  Toshiyuki Nakakura ,  Tomohito Koba ,  Misao Masuda ,  Chiaki Maruko ,  Satoru Kishi

发明人： Hideo Sakai ,  Toshiyuki Nakakura ,  Tomohito Koba ,  Misao Masuda ,  Chiaki Maruko ,  Satoru Kishi

IPC分类号： B32B2712

CPC分类号： B29C70/345 ,  B29C51/02 ,  B29C51/145 ,  B29L2031/7692 ,  Y10T428/249942 ,  Y10T428/24995

摘要： A process for preparing a molded article of fiber-reinforced plastic having an optional configuration and no tendency to deformation and cracks by using a plate material consisting essentially of a fibrous reinforcement and a thermoplastic resin, comprising the steps of previously setting-up, on the plate material and/or a mold, a sheet prepreg obtained by impregnating a unidirectionally arranged fiber or woven cloth with a thermoplastic resin in areas where the fibrous reinforcement does not follow the flow of the resin well or in areas where special reinforcement is required and successively carrying out integral molding to obtain said article; and a molded article obtained by said process.

摘要翻译： 一种制备纤维增强塑料的成型制品的方法，其具有任选的构造，并且不使用基本上由纤维增强材料和热塑性树脂组成的板材的变形和裂纹的趋势，包括以下步骤： 板材和/或模具，通过在热塑性树脂浸渍单向布置的纤维或机织布的纤维增强体不会在树脂的流动不完全的区域或需要特殊加强的区域中浸渍而获得的片材预浸料 进行整体成型以获得所述制品; 和通过所述方法获得的模塑制品。

公开(公告)号：US5013817A

公开(公告)日：1991-05-07

申请号：US266678

申请日：1988-11-03

申请人： Masahiro Ohta ,  Saburo Kawashima ,  Shoji Tamai ,  Hideaki Oikawa ,  Akihiro Yamaguchi ,  Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Misao Masuda ,  Satoru Kishi ,  Chiaki Maruko

发明人： Masahiro Ohta ,  Saburo Kawashima ,  Shoji Tamai ,  Hideaki Oikawa ,  Akihiro Yamaguchi ,  Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Misao Masuda ,  Satoru Kishi ,  Chiaki Maruko

IPC分类号： C08G73/10

CPC分类号： C08G73/105 ,  C08G73/1017

摘要： The invention relates to processes for preparing a polyimide, a polyimide composition prepared by the processes and polyimide composite materials containing the same.

公开(公告)号：US5294394A

公开(公告)日：1994-03-15

申请号：US584167

申请日：1990-09-18

申请人： Hideo Sakai ,  Toshiyuki Nakakura ,  Kaba Tomohito ,  Misao Masuda ,  Chiaki Maruko ,  Satoru Kishi

发明人： Hideo Sakai ,  Toshiyuki Nakakura ,  Kaba Tomohito ,  Misao Masuda ,  Chiaki Maruko ,  Satoru Kishi

IPC分类号： B29C43/18 ,  B29C51/02 ,  B29C51/14 ,  B29C70/34 ,  B29K105/06 ,  B29C67/14

CPC分类号： B29C70/345 ,  B29C51/02 ,  B29C51/145 ,  B29L2031/7692 ,  Y10T428/249942 ,  Y10T428/24995

摘要： A process for preparing a molded article of fiber-reinforced plastic having an optional configuration and no tendency to deformation and cracks by using a plate material including a fibrous reinforcement and a thermoplastic resin, including the steps of previously setting-up, on the plate material and/or a mold, a sheet prepreg obtained by impregnating a unidirectionally arranged fiber or woven cloth with a thermoplastic resin in areas where the fibrous reinforcement does not follow the flow of the resin well or in areas where special reinforcement is required and successively carrying out integral molding to obtain said article; and a molded article obtained by the process.

摘要翻译： 一种制备纤维增强塑料的成型制品的方法，其具有任选的构造，并且通过使用包括纤维增强材料和热塑性树脂的板材，不会发生变形和裂纹的倾向，包括在板材上预先安装的步骤 和/或模具，通过在热塑性树脂浸渍单向排列的纤维或织布的纤维增强材料不会沿着树脂流动的区域或在需要特殊加固的区域中浸渍而获得的片材预浸料，并且依次进行 一体成型获得所述制品; 和通过该方法获得的成型品。

公开(公告)号：US5445701A

公开(公告)日：1995-08-29

申请号：US268718

申请日：1994-06-30

申请人： Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Satoru Kishi ,  Chiaki Maruko

发明人： Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Satoru Kishi ,  Chiaki Maruko

IPC分类号： B29C70/50 ,  B29C70/16 ,  B29C70/20 ,  B29D9/00 ,  B29K105/10

CPC分类号： B29C70/504 ,  B29K2101/12 ,  B29K2105/0809 ,  B29K2105/101

摘要： Method and apparatus for manufacturing a sheet-prepreg reinforced with fibers wherein a sheet of fibers such as warp or woven fibers such as fabrics is conveyed between a pair of band belts one of which is coated with a film of thermoplastic resin which has been heated higher than its softening point to enhance resin-impregnating efficiency and prevent the impregnated resin from contacting air. Further, when the sheet of fibers or woven fibers is conveyed in this manner, the molten resin is not maintained on the manufacturing line, thereby preventing it from being deteriorated by heat. The apparatus can be thus kept under operation for a long time and the sheet-prepreg reinforced with the fibers can be made much higher in quality and the deterioration of the impregnated resin can be further delayed.

摘要翻译： 制造用纤维增强的片材预浸料的方法和装置，其中将诸如织物之类的经纱或织造纤维的纤维片材在一对带带之间输送，其中一条带带被涂覆有已经被加热的热塑性树脂膜 比其软化点提高树脂浸渍效率并防止浸渍树脂与空气接触。 此外，当以这种方式输送纤维或织造纤维时，熔融树脂不会保持在生产线上，从而防止其被热损坏。 因此，该设备可以长期保持运行，并且可以使用纤维增强的片材预浸料的质量高得多，并且可以进一步延迟浸渍树脂的劣化。

公开(公告)号：US5201979A

公开(公告)日：1993-04-13

申请号：US841204

申请日：1992-02-27

申请人： Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Satoru Kishi ,  Chiaki Maruko

发明人： Tomohito Koba ,  Toshiyuki Nakakura ,  Hideo Sakai ,  Satoru Kishi ,  Chiaki Maruko

IPC分类号： B29C70/50 ,  B32B31/00

CPC分类号： B29C70/504 ,  B29K2101/12 ,  B29K2105/0809 ,  B29K2105/101

摘要： Method and apparatus for manufacturing a sheet-prepreg reinforced with fibers wherein a sheet of fibers such as warp or woven fibers such as fabrics is conveyed between a pair of band belts one of which is coated with a film of thermoplastic resin which has been heated higher than its softening point to enhance resin-impregnating efficiency and prevent the impregnated resin from contacting air. Further, when the sheet of fibers or woven fibers is conveyed in this manner, the molten resin is not maintained on the manufacturing line, thereby preventing it from being deteriorated by heat. The apparatus can be thus kept under operation for a long time and the sheet-prepreg reinforced with the fibers can be made much higher in quality and the deterioration of the impregnated resin can be further delayed.

摘要翻译： 制造用纤维增强的片材预浸料的方法和装置，其中将诸如织物之类的经纱或织造纤维的纤维片材在一对带带之间输送，其中一条带带被涂覆有已经被加热的热塑性树脂膜 比其软化点提高树脂浸渍效率并防止浸渍树脂与空气接触。 此外，当以这种方式输送纤维或织造纤维时，熔融树脂不会保持在生产线上，从而防止其被热损坏。 因此，该设备可以长期保持运行，并且可以使用纤维增强的片材预浸料的质量高得多，并且可以进一步延迟浸渍树脂的劣化。

公开(公告)号：US5514448A

公开(公告)日：1996-05-07

申请号：US92794

申请日：1993-07-19

申请人： Satoru Kishi ,  Toshiyuki Nakakura ,  Hiroshi Tanabe ,  Hideo Sakai

发明人： Satoru Kishi ,  Toshiyuki Nakakura ,  Hiroshi Tanabe ,  Hideo Sakai

IPC分类号： B29C70/08 ,  B29C70/30 ,  B29C70/88 ,  B32B37/00 ,  B32B37/30 ,  B60R19/18 ,  C08J5/08 ,  F16F1/366 ,  F16F7/12 ,  B32B1/04

CPC分类号： B32B37/0076 ,  B29C70/086 ,  B29C70/30 ,  B29C70/88 ,  C08J5/08 ,  F16F1/366 ,  F16F7/12 ,  B29K2023/12 ,  B29K2105/108 ,  B29K2995/0091 ,  B29L2031/3044 ,  B60R2019/1853 ,  Y10T428/24124 ,  Y10T428/24132 ,  Y10T428/24347 ,  Y10T428/24471 ,  Y10T428/24479 ,  Y10T428/24562 ,  Y10T428/2457 ,  Y10T428/24579 ,  Y10T428/24752 ,  Y10T428/2476 ,  Y10T428/24777 ,  Y10T428/24793 ,  Y10T428/249953 ,  Y10T428/249959 ,  Y10T428/24996

摘要： A molding obtained by laminating resinous plates of 0.05 to 1 mm thick, prepared by impregnating 20% by volume or more of a reinforcing fiber with a thermoplastic resin, and molding the resultant laminate, wherein sections where deviation or deformation is caused by an external force, or preferably nonjoining parts having an area of 5 to 60% based on the area of the location where impact is absorbed, are provided between the laminated layers constituting the molding, or the laminated layer surface where the impact is absorbed is formed with a shape having a curvature of 5 to 20 mm in radius. The molding absorbs impact force significantly and prevents efficiently human body, etc. from the shock upon striking.

摘要翻译： 通过将通过用热塑性树脂浸渍20体积％以上的增强纤维制备的0.05〜1mm厚的树脂板，并成型所得层压体的成型体，其中由外力引起偏差或变形的部分 或者优选地，在构成模制件的层叠层之间设置面积为5〜60％的冲击吸收位置的面积的非接合部，或者形成有冲击被吸收的层叠面的形状 具有半径为5至20mm的曲率。 成型体显着吸收冲击力，有效防止人体等撞击时的冲击。

公开(公告)号：US4990207A

公开(公告)日：1991-02-05

申请号：US351533

申请日：1989-05-15

申请人： Hideo Sakai ,  Toshiyuki Nakakura ,  Satoru Kishi

发明人： Hideo Sakai ,  Toshiyuki Nakakura ,  Satoru Kishi

IPC分类号： B29B15/08 ,  B32B31/18

CPC分类号： B29C70/345 ,  B29C70/545 ,  B29K2101/12 ,  B29K2105/101 ,  Y10T156/1056 ,  Y10T156/1057 ,  Y10T156/1074

摘要： This invention relates to a process for preparing fiber-reinforced thermoplastic (FRTP) molded articles comprising stacking sheet prepregs comprising unidirectionally arranged reinforcing fibers impregnated with thermoplastic resin and molding the same, and to a process for preparing FRTP molded articles by using woven reinforcing fibers in place of unidirectionally arranged reinforcing fibers. The FRTP molded articles obtained by the process of this invention have high quality and can be molded without unevenness in strength.

摘要翻译： 本发明涉及一种制备纤维增强热塑性塑料（FRTP）模塑制品的方法，其包括将包含单向布置的增塑纤维浸渍在热塑性树脂中并将其成型的层叠片材预浸料，以及通过使用编织增强纤维制备FRTP模塑制品的方法 单向排列增强纤维的地方。 通过本发明的方法获得的FRTP成型品具有高质量并且可以在不强度不均匀的情况下成型。

公开(公告)号：US5494737A

公开(公告)日：1996-02-27

申请号：US171439

申请日：1993-12-22

申请人： Hideo Sakai ,  Kojiro Motai ,  Satoru Kishi ,  Katsuyuki Morita ,  Hiroshi Tanabe

发明人： Hideo Sakai ,  Kojiro Motai ,  Satoru Kishi ,  Katsuyuki Morita ,  Hiroshi Tanabe

IPC分类号： B29C51/08 ,  B29C51/14 ,  B32B27/04 ,  B60R13/02 ,  B32B5/22 ,  B28B5/00 ,  B60J7/00

CPC分类号： B32B38/00 ,  B29C51/145 ,  B32B27/04 ,  B29C51/08 ,  B29C51/082 ,  B29L2031/3011 ,  B60R13/0225 ,  Y10T428/233 ,  Y10T428/249969 ,  Y10T428/249986 ,  Y10T428/249987 ,  Y10T428/249988 ,  Y10T428/249989 ,  Y10T428/249992 ,  Y10T442/647

摘要： A ceiling material for vehicles, said ceiling material comprises:a core material (11) composed of a resin foamed article;a protective layer (12) comprising a thermoplastic resin blended with fibers in a range of not less than 40% and not more than 80% in volume content;said protective layer (12) being provided on at least one surface of the core material (11);and a thin sheet-shaped surface material (14) provided on the surface of the protective layer (12).A process of producing ceiling materials for vehicles, which comprises the steps of:a material sheet of a protective layer comprising a thermoplastic resin blended with fibers in a range of not less than 40% and not more than 80% in volume content being heated to not less than a glass transition point of the thermoplastic resin;said material sheet being overlaid with a core material sheet composed of a resin foamed article;a surface material being on the core material sheet;and pressuring and shaping said protective layer, said core material sheet, and said surface material which have been overlaid using a molding mold.

摘要翻译： 一种用于车辆的天花板材料，所述天花板材料包括：由树脂发泡制品构成的芯材料（11）; 保护层（12），其包含与纤维混合的热塑性树脂，所述纤维的体积含量为不小于40％且不大于80％的范围; 所述保护层（12）设置在所述芯材料（11）的至少一个表面上; 以及设置在保护层（12）的表面上的薄片状表面材料（14）。 一种生产车辆用顶棚材料的方法，包括以下步骤：将包含热塑性树脂的保护层的材料片与不同于40重量％且不大于80体积％的纤维混合加热至 不低于热塑性树脂的玻璃化转变点; 所述材料片与由树脂发泡制品构成的芯材片材重叠; 表面材料在芯材片上; 并且使用模制模具将所述保护层，所述芯材片和所述表面材料加压和成型。