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公开(公告)号：US10155704B2
公开(公告)日：2018-12-18
申请号：US15789934
申请日：2017-10-20
申请人： UOP LLC , TPC Group, LLC
摘要： Processes and apparatuses for the production of butadienes are provided. In an embodiment, a process for production of butadienes includes passing a reactor feed stream comprising a hydrocarbon stream comprising butene, a steam stream and a oxygen rich stream to a dehydrogenation reactor. The reactor feed stream is oxidatively dehydrogenated in the dehydrogenation reactor in presence of an oxidative dehydrogenation catalyst to provide an effluent stream comprising butadiene. The effluent stream is cooled in a quench tower to provide a cooled effluent stream and a bottoms water stream. The cooled effluent stream is passed to an aldehyde scrubber to provide a scrubbed effluent stream and a spent water stream comprising aldehydes. A first portion of the bottoms water stream is passed from the quench tower to the aldehyde scrubber.
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公开(公告)号：US20180037523A1
公开(公告)日：2018-02-08
申请号：US15789934
申请日：2017-10-20
申请人： UOP LLC , TPC Group, LLC
CPC分类号： C07C5/48 , C07C7/005 , C07C7/09 , C07C7/11 , C07C2523/745 , C07C11/167
摘要： Processes and apparatuses for the production of butadienes are provided. In an embodiment, a process for production of butadienes includes passing a reactor feed stream comprising a hydrocarbon stream comprising butene, a steam stream and a oxygen rich stream to a dehydrogenation reactor. The reactor feed stream is oxidatively dehydrogenated in the dehydrogenation reactor in presence of an oxidative dehydrogenation catalyst to provide an effluent stream comprising butadiene. The effluent stream is cooled in a quench tower to provide a cooled effluent stream and a bottoms water stream. The cooled effluent stream is passed to an aldehyde scrubber to provide a scrubbed effluent stream and a spent water stream comprising aldehydes. A first portion of the bottoms water stream is passed from the quench tower to the aldehyde scrubber.
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公开(公告)号：US10538466B2
公开(公告)日：2020-01-21
申请号：US15968909
申请日：2018-05-02
申请人： UOP LLC , TPC Group, LLC
发明人： John J. Senetar , Jeannie M. Blommel , Charles P. Luebke , Dana K. Sullivan , Joseph G. Duff , Jillian M. Horn , Clifford A. Maat , Michael O. Nutt
IPC分类号： C07C1/24 , C07C11/167 , C07C7/11 , C07C7/09 , C07C5/48 , C07C7/00 , B01D19/00 , C07C7/04 , B01L3/14 , B01J19/00 , C07C5/42
摘要： A process is presented for the production of butadienes. The process includes the separation of oxygenates from the product stream from an oxidative dehydrogenation reactor. The process includes quenching the product stream and solvent and oxygenates from the product stream. The oxygenates are stripped from the solvent with an inert gas to reduce the energy consumption of the process, and the solvent is recycled and reused in the process.
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公开(公告)号：US20180258015A1
公开(公告)日：2018-09-13
申请号：US15968909
申请日：2018-05-02
申请人： UOP LLC , TPC Group, LLC
发明人： John J. Senetar , Jeannie M. Blommel , Charles P. Luebke , Dana K. Sullivan , Joseph G. Duff , Jillian M. Horn , Clifford A. Maat , Michael O. Nutt
IPC分类号： C07C11/167 , C07C5/42 , C07C1/24 , B01J19/00 , B01D3/14
CPC分类号： C07C11/167 , B01D3/14 , B01D19/0015 , B01D2256/24 , B01D2257/70 , B01J19/0053 , C07C1/24 , C07C5/42 , C07C5/48 , C07C7/005 , C07C7/04 , C07C7/09 , C07C7/11
摘要： A process is presented for the production of butadienes. The process includes the separation of oxygenates from the product stream from an oxidative dehydrogenation reactor. The process includes quenching the product stream and solvent and oxygenates from the product stream. The oxygenates are stripped from the solvent with an inert gas to reduce the energy consumption of the process, and the solvent is recycled and reused in the process.
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公开(公告)号：US10584081B2
公开(公告)日：2020-03-10
申请号：US15588906
申请日：2017-05-08
申请人： UOP LLC
发明人： Raul Zavala , Charles P. Luebke , Adam J. Kanyuh
摘要： A process is presented for the recovery of solvent used in an alkylation process. The solvent removes heavy hydrocarbons from a C4 stream. The C4 stream is passed to an alkylation unit to generate an alkylate product. A portion of the solvent is carried over with the C4 stream and needs to be recovered to reduce the aromatics content in the C4 stream, to reduce any deleterious effects of the aromatics in downstream processing.
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公开(公告)号：US20190185393A1
公开(公告)日：2019-06-20
申请号：US16206968
申请日：2018-11-30
申请人： UOP LLC
摘要： Processes for co-production of methyl tertiary-butyl ether (MTBE) and alkylate is disclosed. The process includes comprising passing a hydrocarbon feed stream comprising C4 hydrocarbons to a dehydrogenation unit to generate a dehydrogenation effluent comprising C4 olefins. The dehydrogenation effluent is passed to a MTBE unit to provide a mixed stream comprising C4 olefins and MTBE. The mixed stream is separated to provide an MTBE product stream and a fractionator overhead stream comprising olefins. The fractionator overhead stream is passed to an alkylation unit to produce an alkylation product stream comprising an alkylate.
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公开(公告)号：US20180345268A1
公开(公告)日：2018-12-06
申请号：US16058841
申请日：2018-08-08
申请人： UOP LLC
CPC分类号： B01J38/48 , B01J19/24 , B01J21/20 , B01J27/32 , B01J29/90 , B01J38/04 , B01J2219/00222 , B01J2219/24 , C07C2/66 , C07C6/06 , Y02P20/584 , C07C15/107
摘要： A process for the regeneration of a catalyst is presented. The catalyst is in a reactor for use in benzene alkylation, and periodically needs to be regenerated. The reactor is taken off-line, and a regenerant is passed through the reactor, producing an effluent stream. A portion of the effluent stream is recycled through the reactor without passing through a clean-up process.
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公开(公告)号：US09957449B2
公开(公告)日：2018-05-01
申请号：US14695352
申请日：2015-04-24
申请人： UOP LLC
IPC分类号： C10G69/00 , C10G50/00 , C10L1/04 , C07C2/08 , C07C2/04 , C07C2/12 , C07C2/02 , C07C2/06 , C10G69/12
CPC分类号： C10G50/00 , C07C2/02 , C07C2/04 , C07C2/06 , C07C2/08 , C07C2/12 , C10G69/126 , C10G2300/1088 , C10G2400/08 , C10L1/04 , C10L2200/043 , C10L2200/0469 , C10L2270/04
摘要： Processes for producing jet-range hydrocarbons includes splitting a renewable olefin feedstock comprising C3 to C8 olefins into a plurality of streams and passing each stream to an oligomerization reactor containing a zeolite catalyst to produce an oligomerized effluent. The reactors may be arranged in series, such that an oligomerized effluent comprises a diluent for a downstream reactor. The net oligomerized effluent may be separated and a heavy olefin stream comprising C8+ olefins may be hydrogenated and separated to provide a distillate range hydrocarbon product.
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公开(公告)号：US20170240821A1
公开(公告)日：2017-08-24
申请号：US15341525
申请日：2016-11-02
申请人： UOP LLC
发明人： Zhihao Fei , Steven L. Krupa , Hosoo Lim , Charles P. Luebke , Robert Mehlberg , Christopher P. Nicholas , Lisa M. Wolschlag
CPC分类号： C10G50/00 , C10G2300/307 , C10G2300/708 , C10G2400/04 , C10L1/08 , C10L2270/026 , C10L2290/12
摘要： Processes for oligomerizing olefins to produce diesel. The oligomerization zone temperature is controlled to counteract catalyst deactivation caused by coking, by contaminants such as cyclo C5 and/or cyclo C6 hydrocarbons, or both. The temperature is increased in increments to ensure that that the oligomerization zone is producing product at a target product yield with a target product quality, which may be measured by a product cetane number. The target product yield is at least 50 wt % and a target product cetane number may be at least 35.
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公开(公告)号：US20160312134A1
公开(公告)日：2016-10-27
申请号：US14695328
申请日：2015-04-24
申请人： UOP LLC
发明人： Geoffrey W. Fichtl , Stanley J. Frey , Charles P. Luebke , Christopher P. Nicholas , Dana K. Sullivan
CPC分类号： C10G69/126 , C10G50/00 , C10G2300/1088 , C10G2400/08 , C10G2400/22
摘要： A method for producing jet-range hydrocarbons includes passing a renewable olefin feedstock comprising C3 to C8 olefins to an oligomerization reactor containing a zeolite catalyst to produce an oligomerized effluent, separating the oligomerized effluent into at least a light stream, and a heavy olefin stream. At least a first portion of the heavy olefin stream is recycled to the oligomerization reactor to dilute the renewable olefin feedstock. portion of heavy olefin stream may be hydrogenated and separated to provide a jet range hydrocarbon product.
摘要翻译： 用于生产喷射范围烃的方法包括将包含C3至C8烯烃的可再生烯烃原料通入含有沸石催化剂的低聚反应器以产生低聚流出物，将低聚流出物分离成至少轻质流和重质烯烃流。 将至少第一部分重质烯烃流再循环到低聚反应器中以稀释可再生烯烃原料。 部分重质烯烃流可以被氢化和分离以提供喷射范围的烃产物。
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