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公开(公告)号：US07504021B2
公开(公告)日：2009-03-17
申请号：US11106289
申请日：2005-04-14
IPC分类号： C10G11/05
摘要： This invention relates to a FCC process using a mesoporous catalytic cracking catalyst. The mesoporous fluidized catalytic cracking catalyst is selective for minimizing the production of coke and light gas. The catalyst comprises at least one amorphous, porous matrix, each matrix having pores ranging in diameter from about 1 Å to about 10 Å and pores ranging in diameter from about 40 Å to about 500 Å, wherein in the pore range from 50 Å to 250 Å, there is a single maximum in differential pore volume distribution over the 50 Å to 250 Å range.
摘要翻译： 本发明涉及使用中孔催化裂化催化剂的FCC方法。 中孔流化催化裂化催化剂是选择性地使焦炭和轻质气体的生产最小化。 催化剂包含至少一种无定形多孔基质，每个基质的孔直径约为约至约10埃，孔径范围为约40至约500，其中孔径范围为50埃至250埃 Å，在50Å至250Å范围内，微分孔体积分布有单一最大值。
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公开(公告)号：US20090139900A1
公开(公告)日：2009-06-04
申请号：US12322485
申请日：2009-02-03
IPC分类号： C10G11/02
摘要： This invention relates to a FCC process using a mesoporous catalytic cracking catalyst. The mesoporous fluidized catalytic cracking catalyst is selective for minimizing the production of coke and light gas. The catalyst comprises at least one amorphous, porous matrix, each matrix having pores ranging in diameter from about 1 Å to about 10 Å and pores ranging in diameter from about 40 Å to about 500 Å, wherein in the pore range from 50 Å to 250 Å, there is a single maximum in differential pore volume distribution over the 50 Å to 250 Å range.
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3.发明授权Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst 失效碳氢转化过程用碱土金属离子交换选择沸石催化剂
公开(公告)号：US5849968A
公开(公告)日：1998-12-15
申请号：US901822
申请日：1997-07-28
申请人： Jeffrey S. Beck , David L. Stern
发明人： Jeffrey S. Beck , David L. Stern
IPC分类号： B01J29/40 , B01J31/02 , C07C2/12 , C07C2/66 , C07C5/27 , C07C5/41 , C07C6/12 , C10G35/095 , C07C5/22
CPC分类号： C07C6/123 , B01J29/40 , C07C2/12 , C07C2/66 , C07C5/2708 , C07C5/41 , B01J2229/12 , B01J2229/42 , C07C2521/08 , C07C2529/06 , C07C2529/40
摘要： There is provided a zeolite catalyst, which is first selectivated with a siliceous material and then treated with an aqueous solution comprising alkaline earth metal ions under ion exchange conditions.
摘要翻译： 提供沸石催化剂，其首先用硅质材料选择，然后在离子交换条件下用包含碱土金属离子的水溶液处理。
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公开(公告)号：US5773679A
公开(公告)日：1998-06-30
申请号：US578346
申请日：1995-12-26
申请人： Jeffrey S. Beck , David L. Stern
发明人： Jeffrey S. Beck , David L. Stern
CPC分类号： C07C6/123 , B01J2229/12 , B01J2229/32 , C07C2529/40
摘要： A process for shape-selective hydrocarbon conversion that involves initially contacting a feed stream which includes an alkylaromatic compound and a co-feed of water, under conversion conditions with a catalytic molecular sieve. Preferably, the catalytic molecular sieve has been modified by being ex situ selectivated with a silicon compound. After an effective amount of time, the water co-feed is omitted from the feed stream and the hydrocarbon conversion process is continued. Optionally, the catalytic molecular sieve can also be in situ trim-selectivated.
摘要翻译： 一种用于形状选择性烃转化的方法，其包括在转化条件下与催化分子筛接触包括烷基芳族化合物和水的共同进料的进料流。 优选地，通过用硅化合物进行异地选择来改变催化分子筛。 在有效量的时间之后，从进料流中省去水共同进料，继续进行烃转化过程。 任选地，催化分子筛也可以原位修剪选择。
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公开(公告)号：US5602066A
公开(公告)日：1997-02-11
申请号：US441106
申请日：1995-06-29
申请人： Jeffrey S. Beck , David L. Stern
发明人： Jeffrey S. Beck , David L. Stern
CPC分类号： B01J37/086 , B01J29/40 , B01J37/06 , B01J2229/26 , B01J2229/42
摘要： There is provided a zeolite catalyst, which is first selectivated with a siliceous material and then washed with a liquid. The washing step may comprise slurrying the catalyst in water and recovering the washed catalyst by filtration.
摘要翻译： 提供沸石催化剂，其首先用硅质材料选择，然后用液体洗涤。 洗涤步骤可以包括将催化剂浆化成水，并通过过滤回收洗涤过的催化剂。
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公开(公告)号：US06777583B2
公开(公告)日：2004-08-17
申请号：US10227663
申请日：2002-08-26
IPC分类号： C07C552
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/00
摘要： There is provided a substantially binder-free catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The catalyst may be used in a hydrocarbon conversion process, such as toluene disproportionation.
摘要翻译： 提供了基本上不含粘合剂的催化分子筛，其通过用硅化合物进行异地选择而被改性。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 催化剂可用于烃转化过程中，例如甲苯歧化。
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公开(公告)号：US5998688A
公开(公告)日：1999-12-07
申请号：US139465
申请日：1998-08-25
申请人： Jeevan S. Abichandani , Jeffrey S. Beck , Stephen H. Brown , Ronald J. Cimini , Ivy D. Johnson , Selma Kwok , Dimitris K. Liguras , David L. Stern
发明人： Jeevan S. Abichandani , Jeffrey S. Beck , Stephen H. Brown , Ronald J. Cimini , Ivy D. Johnson , Selma Kwok , Dimitris K. Liguras , David L. Stern
CPC分类号： C07C4/18 , C07C5/2702 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2529/80
摘要： A method for minimizing the loss of xylenes in an ethylbenzene conversion/isomerization process by adding toluene to the feedstock. The concentration of toluene in the feedstock is increased by co-feeding toluene or by recycling toluene separated from the ethylbenzene conversion reactor effluent. The increased toluene concentration reduces the loss of xylenes during the ethylbenzene conversion reaction and under preferred operating conditions increases the amount of xylenes in the product.
摘要翻译： 通过向原料中加入甲苯来最小化乙苯转化/异构化方法中二甲苯损失的方法。 原料中甲苯的浓度通过共同加入甲苯或通过回收从乙苯转化反应器流出物中分离的甲苯而增加。 增加的甲苯浓度降低了乙苯转化反应期间二甲苯的损失，并且在优选的操作条件下增加了产物中二甲苯的量。
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公开(公告)号：US5567666A
公开(公告)日：1996-10-22
申请号：US441518
申请日：1995-05-15
申请人： Jeffrey S. Beck , David L. Stern
发明人： Jeffrey S. Beck , David L. Stern
CPC分类号： B01J37/082 , B01J29/40 , B01J2229/16 , B01J2229/37 , B01J2229/42
摘要： There is provided a zeolite catalyst, which is first selectivated with a siliceous material and then treated with an aqueous solution comprising a dealuminizing agent such as an acid or a chelating agent.
摘要翻译： 提供沸石催化剂，其首先用硅质材料选择，然后用包含脱铝剂如酸或螯合剂的水溶液处理。
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公开(公告)号：US5530170A
公开(公告)日：1996-06-25
申请号：US468597
申请日：1995-06-06
CPC分类号： B01J29/40 , B01J37/086 , C07C2/66 , C07C2/864 , C07C6/123 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52
摘要： There is provided a process for the alkylation of ethylbenzene with ethylene to selectively produce para-diethylbenzene over a catalyst which has been selectivated by multiple treatments with a siliceous material.
摘要翻译： 提供了一种使用乙烯烷基化乙苯以选择性地在催化剂上生产对二乙苯的方法，所述催化剂已经通过用硅质材料进行多次处理而选择。
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公开(公告)号：US06878654B2
公开(公告)日：2005-04-12
申请号：US10243572
申请日：2002-09-13
IPC分类号： B01J29/70 , B01J29/90 , B01J38/12 , B01J38/60 , B01J38/62 , B01J38/64 , B01J38/66 , C07B61/00 , C07C2/66 , C07C6/12 , C07C15/073 , C07C15/085 , B01J20/34 , B01J21/08
CPC分类号： C07C2/66 , B01J29/90 , B01J38/12 , B01J38/60 , B01J38/64 , B01J38/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/085 , C07C15/073 , C07C15/02
摘要： The present invention provides a process for regenerating a spent aromatics alkylation or transalkylation catalyst comprising a molecular sieve by contacting the spent catalyst with an oxygen-containing gas at a temperature of about 120 to about 600° C. and then contacting the catalyst with an aqueous medium, such as an ammonium nitrate solution, an ammonium carbonate solution or an acid solution.
摘要翻译： 本发明提供了一种通过在约120至约600℃的温度下使废催化剂与含氧气体接触而使含有分子筛的废芳烃烷基化或烷基转移催化剂再生的方法，然后使催化剂与水 介质，如硝酸铵溶液，碳酸铵溶液或酸溶液。
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