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1.发明授权Aqueous dispersions that are free or substantially free from volatile organic compounds, and method for their production and use thereof 有权游离或基本上不含挥发性有机化合物的水分散体及其生产和使用方法公开(公告)号：US06916878B2
公开(公告)日：2005-07-12
申请号：US10468446
申请日：2002-03-08
IPC分类号： C09K3/10 , C08F293/00 , C08K3/00 , C08L53/00 , C09D5/02 , C09D5/46 , C09D7/12 , C09D153/00 , C09J11/00 , C09J153/00 , C08K13/08
CPC分类号： B82Y30/00 , C08K3/01 , C08K2201/011 , C08L53/00
摘要： Aqueous dispersions entirely or substantially free from volatile organic compounds, comprising (A) at least one block copolymer preparable by two-stage or multistage free-radical copolymerization in an aqueous medium of a) at least one olefinically unsaturated monomer selected from the group consisting of hydrophilic and hydrophobic olefinically unsaturated monomers, and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C═CR3R4 (I) in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and (B) hydrophilic nanoparticles; processes for preparing them, and their use as or to prepare coating materials, adhesives, and sealing compounds.
摘要翻译： 完全或基本上不含挥发性有机化合物的水性分散体，其包含（A）至少一种嵌段共聚物，其可通过在a）至少一种选自以下的烯属不饱和单体的水性介质中进行两步或多步自由基共聚制备： 亲水和疏水的烯属不饱和单体，和b）至少一种不同于烯属不饱和单体（a）的烯属不饱和单体和通式I <？in-line-formula description =“In-Line Formulas”end =“lead （I） 公式描述=“在线公式”end =“tail”？>其中基团R 1，R 2，R 3和R 3， R 4彼此独立地为氢原子或取代或未取代的烷基，环烷基，烷基环烷基，环烷基烷基，芳基，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基， 使得变量R 1，R 2，R 3和R 4中的至少两个被取代或 未取代的芳基，芳基烷基或芳基环烷基，特别是取代或未取代的芳基; 和（B）亲水性纳米颗粒; 制备它们的方法，以及它们作为或用于制备涂料，粘合剂和密封化合物的方法。
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公开(公告)号：US06946512B2
公开(公告)日：2005-09-20
申请号：US10257119
申请日：2001-04-03
CPC分类号： C08F12/32
摘要： Use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C═CR3R4 (I), in which the radicals R1, R2, R3 and R4, in each case independently of one another, are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; in an aqueous medium for producing molding compounds and moldings.
摘要翻译： 使用可通过a）至少一种烯属不饱和单体的自由基聚合制备的共聚物（A）和b）至少一种不同于烯属不饱和单体（a）的烯属不饱和单体和通式I < line-formula description =“In-line Formulas”end =“lead”？R＆lt; 1＆lt; 2＆gt; 2＆lt; C-CR 3＆lt; （I），<？in-line-formula description =“在线公式”end =“tail”？>其中基团R 1，R 2， R 2，R 3和R 4在每种情况下彼此独立地是氢原子或取代或未取代的烷基，环烷基，烷基环烷基，环烷基烷基，芳基 ，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基，条件是至少两个变量R 1，R 2，R 3和 R 4是取代或未取代的芳基，芳基烷基或芳基环烷基，特别是取代或未取代的芳基; 在用于生产模塑料和模制品的水性介质中。
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3.发明授权Dispersion product for producting an electrophoretically precipitable dipping varnish 有权用于产生电泳可沉淀浸渍清漆的分散产物公开(公告)号：US06201043B1
公开(公告)日：2001-03-13
申请号：US09242146
申请日：1999-04-27
IPC分类号： C08K320
CPC分类号： C09D151/08 , C08F283/10 , C09D5/4473
摘要： The invention relates to aqueous dispersions. They are obtainable by polymerizing an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monmers [sic] in an aqueous solution of an at least partially protonated epoxide-amine adduct. It is characterized in that the epoxide-amine adduct is for its part obtainable by reacting (A) a glycidyl ether of a polyphenol that contains on statistical average at least one epoxide group in the molecule, or a mixture of such glycidyl ethers, (B) a polygycidyl [sic] ether of a polyol that contains on statistical average more than 1.0 epoxide groups in the molecule, or a mixture of such polyglycidyl ethers, and (C) a compound that contains a primary amino group in the molecule, or a mixture of such compounds, to give the epoxide-amine adduct, components (A) and (B) being employed in a ratio of equivalents of from 1.0:0.5 to 1.0:8.0 and from 0.3 to 0.7 mol of component (C) being employed per equivalent of epoxide groups of (A) and (B).
摘要翻译： 本发明涉及水性分散体。 它们可通过在至少部分质子化的环氧化物 - 胺加合物的水溶液中聚合烯属不饱和单体或烯属不饱和单体的混合物而获得。 其特征在于环氧 - 胺加合物部分可通过使（A）分子中含有至少一个环氧基的统计平均数的多酚的缩水甘油醚或这种缩水甘油醚的混合物（B ）多元醇的聚环己烷基醚，其在分子中统计平均含有超过1.0个环氧基，或这些多缩水甘油醚的混合物，和（C）在分子中含有伯氨基的化合物，或 这些化合物的混合物得到环氧化物 - 胺加合物，组分（A）和（B）以当量为1.0:0.5至1.0:8.0和0.3-0.7mol的组分（C）的使用量使用 （A）和（B）的每当量的环氧基团。
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公开(公告)号：US06506836B1
公开(公告)日：2003-01-14
申请号：US09868095
申请日：2001-07-30
申请人： Wolfgang Bremser , Frank Strickmann , Maximilian Bendix , Wolfgang Paulus , Roman Benedikt Raether , David Christie
发明人： Wolfgang Bremser , Frank Strickmann , Maximilian Bendix , Wolfgang Paulus , Roman Benedikt Raether , David Christie
IPC分类号： C08F1800
CPC分类号： C08F212/32 , C08F293/00 , C08F293/005
摘要： A process for preparing a reaction product (A), comprising the following stage (i): (i) reacting under free-radical conditions a reaction mixture comprising at least one free-radically reactable monomer (a) in the presence of at least one free-radical initiator and of a compound (I) of the formula: in which R1 to R4 each independently of one another are hydrogen, a substituted or unsubstituted alkyl radical, cycloalkyl radical or arakyl radical, or an unsubstituted or a substituted aromatic hydrocarbon radical, with the proviso that at least two of R1 to R4 are an unsubstituted or a substituted aromatic hydrocarbon radical in aqueous phase.
摘要翻译： 一种制备反应产物（A）的方法，包括以下步骤（i）：（i）在自由基条件下使包含至少一种可自由基反应的单体（a）的反应混合物在至少一种 自由基引发剂和下式化合物（I）：其中R 1至R 4彼此独立地为氢，取代或未取代的烷基，环烷基或芳烷基，或未取代或取代的芳族烃基 条件是R 1至R 4中的至少两个是水相中的未取代的或取代的芳族烃基。
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公开(公告)号：US06716905B1
公开(公告)日：2004-04-06
申请号：US09868769
申请日：2001-06-21
申请人： Wolfgang Bremser , Frank Strickmann , Maximilian Bendix , Wolfgang Paulus , Roman Benedikt Raether , David Christie
发明人： Wolfgang Bremser , Frank Strickmann , Maximilian Bendix , Wolfgang Paulus , Roman Benedikt Raether , David Christie
IPC分类号： C08K320
CPC分类号： C09D151/06 , C08F291/00 , C08F293/005 , C09D133/062 , C09D153/00 , C08L2666/02 , C08L2666/24
摘要： The invention relates to a coating agent, containing at least one conversion product (A) and at least one suitable additive (C), (A) being produced according to a method comprising the following step (i): (iv) reacting a reaction mixture comprising at least one radically convertible monomer in radical conditions, (a) in the presence of at least one radical initiator and a compound (I) of formula (II) wherein R1 to R4 each represent, independently of each other, hydrogen, an unsubstituted or substituted alkyl radical, cycloalkyl radical or aralkyl radical or an unsubstituted or a substituted aromatic hydrocarbon radical, on the condition that at least two of R1 to R4 represent an unsubstituted or a substituted aromatic hydrocarbon radical, in an aqueous phase
摘要翻译： 本发明涉及包含至少一种转化产物（A）和至少一种合适的添加剂（C）的包衣剂，（A）根据包括以下步骤（i）的方法生产：（ⅳ）使反应 在（a）在至少一种自由基引发剂和式（II）化合物（I）的存在下，其中R 1至R 4各自独立地表示氢，氢， 未取代或取代的烷基，环烷基或芳烷基或未取代或取代的芳族烃基，其中R 1至R 4中的至少两个表示未取代或取代的芳族烃基，在水相中
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6.发明申请公开(公告)号：US20140004266A1
公开(公告)日：2014-01-02
申请号：US13820591
申请日：2011-09-12
申请人： Daniel Wasserfallen , Michael Schwamb , Cindy Ettrich , Vera Sotke , Martin Droll , Oliver Seewald , Wolfgang Bremser , Aliaksandr Frankel
发明人： Daniel Wasserfallen , Michael Schwamb , Cindy Ettrich , Vera Sotke , Martin Droll , Oliver Seewald , Wolfgang Bremser , Aliaksandr Frankel
IPC分类号： B05D3/00
CPC分类号： B05D3/002 , B05D1/18 , B05D7/142 , B05D7/16 , B05D7/51 , B05D7/54 , C09D5/088 , C23C18/54 , C25D13/00 , Y10T428/24975 , Y10T428/265
摘要： A method for electroless coating of a substrate by applying an activating coat of polyelectrolyte or salt with a first aqueous composition, rinsing of the activating coat such that the activating coat is not entirely removed The activated surface that has remained after rinsing is then contacted with an aqueous composition in the form of a solution, emulsion or suspension to form an organic secondary coat (precipitation coat), and drying. The activating coat contains at least one cationic polyelectrolyte or at least one cationic salt in solution in water. The aqueous composition which forms the secondary coat contains constituents which can be precipitated, deposited and/or salted out and which are anionically, zwitterionically, sterically or cationically stabilized. The dry film formed in the process, which is made of the activating coat and the secondary coat, has a thickness of at least 1 μm.
摘要翻译： 一种通过用第一水性组合物施加聚电解质或盐的活化涂层来对基材进行无电涂覆的方法，冲洗活化涂层，使得活化涂层不被完全除去。然后冲洗后保留的活化表面与 水溶液形式的溶液，乳液或悬浮液形成有机二次涂层（沉淀涂层），并干燥。 活化涂层在水溶液中含有至少一种阳离子聚电解质或至少一种阳离子盐。 形成第二层的水性组合物含有可沉淀，沉积和/或盐析的组分，阴离子，两性离子，空间或阳离子稳定。 在该工艺中形成的由活化涂层和第二涂层制成的干膜具有至少1um的厚度。
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7.发明授权Coating material and its use for producing filler coats and stone impact protection primers 失效涂料及其用于生产填料外壳和石材冲击保护底漆的用途公开(公告)号：US06727316B1
公开(公告)日：2004-04-27
申请号：US10018703
申请日：2001-12-13
申请人： Wolfgang Bremser
发明人： Wolfgang Bremser
IPC分类号： C08F1232
CPC分类号： B05D7/546 , B05D7/577 , C08F212/32 , C08F220/06 , C08F2220/281 , C08L51/003 , C08L53/00 , C09D151/003 , C09D153/00 , C08L2666/02 , C08F220/14 , C08F2220/1825 , C08F212/08 , C08F2220/1858
摘要： The use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C═CR3R4 (I), in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; in an aqueous medium, in a coating material used to produce surfacer coats and antistonechip primer coats.
摘要翻译： 使用通过自由基聚合制备的共聚物（A）至少一种烯属不饱和单体和b）至少一种不同于烯属不饱和单体（a）的烯属不饱和单体和通式Iin，其中基团R' R 1，R 2，R 3和R 4各自独立地为氢原子或取代或未取代的烷基，环烷基，烷基环烷基，环烷基烷基，芳基，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基， 条件是至少两个变量R 1，R 2，R 3和R 4是取代或未取代的芳基，芳基烷基或芳基环烷基，特别是取代或未取代的芳基;在水性介质中， 在用于生产表面涂层和抗静电芯片底漆的涂料中。
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公开(公告)号：US20130237619A1
公开(公告)日：2013-09-12
申请号：US13821390
申请日：2011-09-07
IPC分类号： C08G73/06
CPC分类号： C08G73/18 , C08G73/0677
摘要： The present invention relates to a method for modifying and cross-linking polybenzimidazoles, PBI. The polybenzimidazole reacts with a compound, which has a halogen and a double bond functionality and which comprises a halogen and an organic group to form modified polymers by means of a nucleophilic substitution of the amine proton of the benzimidazole functionality in a solution, and a functional group is connected via each resulting free double bond and/or the polymers that are thus modified are cross-linked.
摘要翻译： 本发明涉及一种改性和交联聚苯并咪唑（PBI）的方法。 聚苯并咪唑与具有卤素和双键官能团的化合物反应，其包含卤素和有机基团，以通过溶液中苯并咪唑官能团的胺质子的亲核取代形成改性聚合物，以及功能性 基团通过每个所得到的自由双键连接和/或被修饰的聚合物交联。
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9.发明授权Aqueous dispersion of inorganic nanoparticles, method for the production and use thereof 失效无机纳米颗粒的水分散体，其生产和使用方法公开(公告)号：US07488769B2
公开(公告)日：2009-02-10
申请号：US10510997
申请日：2003-05-02
IPC分类号： C08K5/05
CPC分类号： B82Y30/00 , C08F293/005 , C08J3/212
摘要： An aqueous dispersion with a pH of from 2 to 7, comprising (A) at least one swellable polymer or oligomer containing anionic and/or potentially anionic functional groups, (B) surface-modified, cationically stabilized, inorganic nanoparticles of at least one kind, and (C) at least one amphiphile; and its use for producing highly scratch-resistant coatings, moldings, and self-supporting films.
摘要翻译： 包含（A）至少一种含有阴离子和/或潜在阴离子官能团的可溶胀聚合物或低聚物的水分散体，（B）表面改性的阳离子稳定的至少一种无机纳米粒子 ，和（C）至少一种两亲物; 以及其用于生产高耐刮擦涂层，模制品和自支撑膜的用途。
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10.发明授权Multilayer systems with at least one layer based on mesonorphic polyelectrolyte complexes method for producing them and their use 失效具有至少一层基于中子聚电解质络合物的多层体系制备它们及其用途公开(公告)号：US06902810B1
公开(公告)日：2005-06-07
申请号：US09869025
申请日：1999-12-21
IPC分类号： B05D1/36 , B05D3/02 , B05D7/06 , B05D7/14 , B05D7/24 , C08L101/02 , C09D201/02 , B32B9/04 , B05D7/00
CPC分类号： C08L101/02 , C09D201/02 , Y10T428/10 , Y10T428/31504 , Y10T428/31551 , Y10T428/31554 , Y10T428/31786 , C08L2666/02
摘要： A multicoat system comprising (I) at least one constituent (IA) comprising mesomorphic polyelectrolyte complexes prepared by reacting, in a liquid phase (IB), at least one polymeric and/or oligomeric, organic, anionic polyelectrolytes (IC) with at least one polymeric and/or oligomeric, organic, cationic polyelectrolytes (ID) and/or at least one cationic surfactant (IE) or at least one polymeric and/or oligomeric, organic, cationic polyelectrolytes (ID) with at least one anionic surfactant (IF) in a stoichiometric or non-stoichiometric ratio, pouring the resulting liquid phase (IG) onto a substrate or into a mold and allowing it to solidify, and heat-treating the resulting solid (IH); and (II) at least one coat (IIA), which is three-dimensionally crosslinked, prepared by applying at least one aqueous, thermally curable coating material (IIB) comprising at least one binder (IIC) and at least one crosslinking agent (IID), to the surface of the constituent (IA), and thermally curing the resulting wet film (IIE).
摘要翻译： 一种多中心系统，其包括（I）至少一种包含介晶聚电解质配合物的组分（IA），其通过在液相（IB），至少一种聚合和/或低聚有机阴离子聚电解质（IC）与至少一种 聚合和/或低聚有机阳离子聚电解质（ID）和/或至少一种阳离子表面活性剂（IE）或至少一种具有至少一种阴离子表面活性剂（IF）的聚合和/或低聚有机阳离子聚电解质（ID） 以化学计量或非化学计量比计，将所得液相（IG）倒入基材或模具中并使其固化并热处理所得固体（I H）; 通过涂覆至少一种包含至少一种粘合剂（IIC）和至少一种交联剂（IID）的水性可热固化涂料（IIB）制备至少一种通过三维交联的涂层（IIA） ）到组分（IA）的表面，并热固化所得湿膜（IIE）。
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