摘要:
Disclosed is a permanent magnet which comprises an alloy containing a hard magnetic phase having a ThMn12 type tetragonal structure and a nonmagnetic phase. The alloy is represented by a general formula given below: [R1-a(M1)a][T1-b-c(M2)b(M3)c]dx&agr; where R is at least one rare earth element (including Y), Ml is at least one element selected from the group consisting of Zr and Hf, T is at least one element selected from the group consisting of Fe, Co and Ni, M2 is at least one element selected from the group consisting of Cu, Bi, Sn, Mg, In and Pb, M3 is at least one element selected from the group consisting of Al, Ga, Ge, Zn, B, P and S, X is at least one element selected from the group consisting of Si, Ti, V, Cr, Mn, Nb, Mo, Ta and W, and the atomic ratios of a, b, c, d and &agr; fall within the ranges of 0≦a≦0.6, 0.01≦b≦0.20, 0≦c≦0.05, 6≦d≦11, and 0.5≦&agr;≦2.0.
摘要翻译:公开了一种永磁体,其包含含有ThMn 12型四方晶系的硬磁相和非磁性相的合金。 该合金由以下给出的通式表示:其中R是至少一种稀土元素(包括Y),M1是选自Zr和Hf中的至少一种元素,T是至少一种选自 由Fe,Co和Ni构成的组,M2是选自Cu,Bi,Sn,Mg,In和Pb中的至少一种元素,M3是选自Al,Ga,Ge中的至少一种元素 ,Zn,B,P和S中的至少一种,X是选自由Si,Ti,V,Cr,Mn,Nb,Mo,Ta和W组成的组中的至少一种元素,并且a,b,c, d和α落在0 <= a <= 0.6,0.01 <= b <= 0.20,0 <= c <= 0.05,6 <= d <= 11和0.5 <=α<2.0的范围内。
摘要:
A catalyst layer containing a catalyst material, the catalyst layer having a porosity of 20 to 90% by vol and satisfying a relation: R1≧R0×1.2, wherein R1 is an alignment ratio of the catalyst layer; and R0 is an alignment ratio of the catalyst material in powder form having a random crystalline plane distribution, and each of the alignment ratios is calculated from a X-ray diffraction spectrum having a diffraction angle 2θ range from 10 to 90 degree measured using Cu-Kα-rays.
摘要:
The processes include: a layer superposition step in which the step of sputtering or vapor-depositing a mixture layer including a first pore-forming metal and a catalyst metal on a substrate and the step of forming an interlayer of a second pore-forming metal or a fibrous-carbon interlayer are alternately conducted repeatedly two or more times to thereby form a multilayer structure containing mixture layers and interlayers; and a pore formation step in which after the layer superposition step, the multilayer structure is subjected to a pore formation treatment.
摘要:
There is provided a catalyst for a fuel cell, which simultaneously realizes excellent catalytic activity and catalytic stability. The catalyst for a fuel cell comprises a fine particle of a metal represented by formula: PtxRuySizT1u wherein T1 represents at least one element selected from the group consisting of nickel (Ni), tungsten (W), vanadium (V), and molybdenum (Mo); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %, or comprises a fine particle of a metal represented by formula: PtxRuySizT2u wherein T2 represents at least one element selected from the group consisting of hafnium (Hf), tin (Sn), zirconium (Zr), niobium (Nb), titanium (Ti), tantalum (Ta), chromium (Cr), and aluminum (Al); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %.
摘要翻译:提供了一种用于燃料电池的催化剂,其同时实现优异的催化活性和催化稳定性。 用于燃料电池的催化剂包括由式PtxRuySizT1u表示的金属微粒,其中T1表示选自镍(Ni),钨(W),钒(V)和钼(Mo)中的至少一种元素 ); x = 30〜90原子% y = 0〜50原子% z = 0.5〜20原子% 并且u = 0.5〜40原子%,或者包含由式PtxRuySizT2u表示的金属微粒,其中,T2表示选自铪(Hf),锡(Sn),锆(Zr), 铌(Nb),钛(Ti),钽(Ta),铬(Cr)和铝(Al); x = 30〜90原子% y = 0〜50原子% z = 0.5〜20原子% u = 0.5〜40原子%。
摘要:
A supporting method for supporting a metal particle including at least two elements on a surface of a plurality of granular supports in a decompression device, the supporting method supporting the metal particle whose particle diameter being smaller than a grain size of the granular support comprises holding the plurality of granular supports in a container and rotating a stirring device and/or the container, a stirring period in which the relative position among the plurality of granular supports are changed and a non-stirring period in which the relative position among the plurality of granular supports are not changed being altered by the rotating, wherein the decompression device comprises, an evaporation source for evaporating elements to form an alloy particle, the container for holding the plurality of granular supports in the decompression device so that a relative position among granular supports is able to be changed, a rotating device for rotating the container and the stirring device disposed in the container.
摘要:
A catalyst is provided and includes fine catalyst particles of a composition represented by formula (1): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Hf, W, Ni, and V; u, x, y, and z are 10 to 98.9 atm %, 0.1 to 50 atm %, 0.5 to 35 atm %, and 0.5 to 35 atm %, respectively, or formula (2): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Ct, Mo, Nb, Zr, and T; u, x, y, and z are 40 to 70 atm %, 0.1 to 50 atm %, 0.5 to 15 atm %, and 0.5 to 15 atm %, respectively
摘要:
Disclosed is a catalyst, including a catalyst particle containing at least one component selected from the group consisting of gold, platinum and an gold alloy, the gold alloy containing gold and at least one element selected from transition metal elements of the fourth period, fifth period and sixth period of the Periodic Table, and a catalyst carrier carrying the catalyst particle and containing a perovskite type oxide represented by general formula (1) given below: A(1-x)BxTiOy (1) where the element A is at least one element selected from the group consisting of Ca, Sr and Ba, the element B is at least one element selected from the group consisting of La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, and Lu, the molar ratio x satisfies 0
摘要:
This invention provides an anode for a fuel cell which can realize stable output for a long period of time, and a fuel cell using the anode for a fuel cell. The anode for a fuel cell comprises an electrode catalyst layer, the electrode catalyst layer comprising a supported catalyst comprising an electroconductive carrier material and catalyst fine particles supported on the electroconductive carrier material, a proton conductive inorganic oxide, and a proton conductive organic polymer binder, the weight ratio between the supported catalyst (C) and the proton conductive inorganic oxide (SA), WSA/WC, being 0.06 to 0.38, the weight ratio between the proton conductive inorganic oxide (SA) and the proton conductive organic polymer binder (P), WP/WSA, being 0.125 to 0.5.
摘要:
This invention provides a process for producing a membrane electrode assembly which has high and stable catalytic activity, and suppressed deterioration in catalytic activity during operation, and can prevent a deterioration in performance attributable to a structural factor of the membrane electrode assembly. The process comprises the step of, after the washing/removing step, drying the catalyst electrode in an atmosphere having a lower oxygen partial pressure than the air. The anode/cathode is a covered catalyst electrode having a structure formed by supporting/depositing a catalytically active material composed mainly of platinum/ruthenium subjected to the potential holding step, the washing/removing step, and the drying step, on a porous electroconductive carrier to cover at least a part of the porous electroconductive carrier with the ion conductive material.
摘要:
A fuel cell, which can supply stable output even at elevated temperatures and can maintain its power generation performance over a long period of time, can be realized by an electrode for a fuel cell comprising a catalyst layer formed of a catalyst composite and a binder, the catalyst composite comprising a proton-conductive inorganic oxide and an oxidation-reduction catalyst phase supported on the proton-conductive inorganic oxide, the proton-conductive inorganic oxide comprising a catalyst carrier selected from tin(Sn)-doped In2O3, fluorine(F)-doped SnO2, and antimony(Sb)-doped SnO2 and an oxide particle phase chemically bonded to the surface of the catalyst carrier. The catalyst composite is manufactured by dispersing a catalyst carrier in a solution containing a material as a starting material for an oxide particle phase, heat treating the dispersion to form a proton-conductive inorganic oxide, further dispersing the proton-conductive inorganic oxide in a catalyst precursor-containing solution, and subjecting the dispersion to heat treatment or pH adjustment to deposit a catalyst phase.
摘要翻译:即使在升高的温度下也可以提供稳定的输出并且可以长时间维持其发电性能的燃料电池可以通过包括由催化剂复合材料和粘合剂形成的催化剂层的燃料电池的电极来实现, 所述催化剂复合体包含质子传导性无机氧化物和负载在所述质子传导性无机氧化物上的氧化还原催化剂相,所述质子传导性无机氧化物包含选自锡(Sn)掺杂的In 2 O 3,氟(F) 掺杂的SnO 2和锑(Sb)掺杂的SnO 2和化学键合到催化剂载体的表面上的氧化物颗粒相。 催化剂复合体是通过将催化剂载体分散在含有作为氧化物粒子相原料的材料的溶液中进行热处理而形成质子传导性无机氧化物,进一步将质子传导性无机氧化物分散在催化剂 含有前体的溶液,并对分散体进行热处理或pH调节以沉积催化剂相。