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    Process for production of clay nanocomposite
    2.
    发明申请
    Process for production of clay nanocomposite 失效
    粘土纳米复合材料生产工艺

    公开(公告)号：US20080146719A1

    公开(公告)日：2008-06-19

    申请号：US11641513

    申请日：2006-12-19

    申请人： Xiaoping Yang ,  Joseph John Kulig ,  Dane Kenton Parker

    发明人： Xiaoping Yang ,  Joseph John Kulig ,  Dane Kenton Parker

    IPC分类号： C08K3/00

    CPC分类号： B60C1/0025 ,  B60C1/0008 ,  B60C1/0016 ,  C08K3/346 ,  C08L9/06

    摘要： A process of preparing a nanocomposite comprised of an elastomer and at least partially exfoliated, intercalated water-swellable clay, comprising the steps of (A) forming a first blend of water-swelled clay and anionic polymer particle emulsion by blending: (1) an aqueous mixture comprised of water and a multilayered water-swellable clay, exclusive of an intercalant for said clay, wherein said water-swellable clay is comprised of a plurality of stacked platelets with water-expanded galleries between said platelets, wherein said galleries contain naturally occurring cationic ion exchangeable ions therein, and (2) an emulsion of anionic synthetic vinylpyridine-styrene-butadiene terpolymer (VPSBR) elastomer particles as an aqueous pre-formed elastomer emulsion having a pH in a range of from about 6 to about 11, comprised of anionic elastomer particles (elastomer particles having anions on the surface derived from an anionic surfactant) prepared by aqueous free radical induced polymerization of monomers in the presence of a free radical generating polymerization initiator and non-polymerizable anionic surfactant, wherein said synthetic elastomer particles are derived from an aqueous polymerization of said monomers comprising from about 0.1 to about 40 weight percent of styrene, from about 60 to about 100 weight percent of 1,3-butadiene, and from about 0.1 to about 8 percent by weight of vinylpyridine monomers which have the structural formula: wherein R1 represents a hydrogen atom or a straight chain or branched alkyl group containing 1 to 4 carbon atoms; and (B) blending with said first blend an aqueous mixture comprised of water and inorganic acid having a pH in a range of about 1 to about 4.

    摘要翻译： 一种制备由弹性体和至少部分剥离的插层的水溶胀性粘土组成的纳米复合材料的方法，包括以下步骤：（A）通过以下步骤形成水溶胀粘土和阴离子聚合物颗粒乳液的第一共混物：（1） 由水和多层水溶胀性粘土组成的水性混合物，不包括用于所述粘土的插入剂，其中所述水溶胀性粘土由在所述血小板之间的多个具有水膨胀图案的层叠血小板组成，其中所述画廊含有天然存在的 阳离子可离子交换离子，和（2）阴离子合成乙烯基吡啶 - 苯乙烯 - 丁二烯三元共聚物（VPSBR）弹性体颗粒的乳液，其为具有约6至约11范围内的pH的水性预形成弹性体乳液，包含 阴离子弹性体颗粒（由阴离子表面活性剂衍生的表面上具有阴离子的弹性体颗粒）通过自由基水溶液聚合制备 在产生自由基的聚合引发剂和非可聚合阴离子表面活性剂的存在下，单体的聚合反应，其中所述合成弹性体颗粒衍生自所述单体的水聚合，所述单体包含约0.1至约40重量％的苯乙烯，约60至 约100重量％的1,3-丁二烯和约0.1至约8重量％的具有以下结构式的乙烯基吡啶单体：其中R 1表示氢原子或直链或支链 含有1至4个碳原子的烷基; 和（B）与所述第一共混物混合由水和无机酸组成的含水混合物，其pH在约1至约4的范围内。

    Pneumatic tire
    3.
    发明申请
    Pneumatic tire 审中-公开
    气动轮胎

    公开(公告)号：US20080142131A1

    公开(公告)日：2008-06-19

    申请号：US11641335

    申请日：2006-12-19

    申请人： Xiaoping Yang ,  Joseph John Kulig ,  Dane Kenton Parker

    发明人： Xiaoping Yang ,  Joseph John Kulig ,  Dane Kenton Parker

    IPC分类号： C08K3/34 ,  B60C1/00

    CPC分类号： B60C1/0016 ,  B60C1/0008 ,  B60C1/0025 ,  B60C17/0009 ,  C08K3/346 ,  C08L9/06

    摘要： A pneumatic tire comprising at least one component, the at least one component comprising a rubber composition comprising:an vinylpyridine-styrene-butadiene (VPSBR) elastomer derived from monomers comprising vinylpyridine, styrene, and butadiene, wherein the VPSBR comprises from about 0.1 to about 8 percent by weight of vinylpyridine; andfrom about 5 to about 15 parts by weight, per 100 parts by weight of VPSBR, of an at least partially exfoliated clay.

    摘要翻译： 一种包含至少一种组分的充气轮胎，所述至少一种组分包含橡胶组合物，其包含：衍生自包含乙烯基吡啶，苯乙烯和丁二烯的单体的乙烯基吡啶 - 苯乙烯 - 丁二烯（VPSBR）弹性体，其中所述VPSBR包含约0.1至约 8重量％的乙烯基吡啶; 和约5至约15重量份，相对于100重量份的VPSBR为至少部分剥离的粘土。

    Nanocomposite formed in situ within an elastomer and article having component comprised thereof
    5.
    发明授权
    Nanocomposite formed in situ within an elastomer and article having component comprised thereof 失效
    在弹性体内原位形成的纳米复合材料及其组成的组分

    公开(公告)号：US06861462B2

    公开(公告)日：2005-03-01

    申请号：US10037539

    申请日：2001-12-21

    申请人： Dane Kenton Parker ,  Brent Kevin Larson ,  Xiaoping Yang

    发明人： Dane Kenton Parker ,  Brent Kevin Larson ,  Xiaoping Yang

    IPC分类号： B82B3/00 ,  B60C1/00 ,  C08J3/215 ,  C08K3/34 ,  C08L9/00

    CPC分类号： C08J3/215 ,  B60C1/00 ,  B60C1/0008 ,  C08J2321/00 ,  C08K3/346 ,  C08L21/00

    摘要： This invention relates to preparation and use of nanocomposites formed in situ within an elastomer host wherein the nanocomposite is comprised of an elastomer matrix and a dispersion therein of at least partially exfoliated clay platelets. Rubber composites can be prepared by blending such nanocomposite with additional elastomer(s), additional reinforcing filler(s) and/or a coupling agent. The invention further relates to the preparation of articles of manufacture, including tires, having at least one component comprised of said nanocomposite or said rubber composite. Such a tire component may be selected from, for example, tire tread and tire innerliner.

    摘要翻译： 本发明涉及在弹性体主体内原位形成的纳米复合材料的制备和用途，其中纳米复合材料由弹性体基质和至少部分剥离的粘土片晶的分散体组成。 橡胶复合材料可以通过将这样的纳米复合材料与另外的弹性体，另外的增强填料和/或偶联剂共混来制备。 本发明进一步涉及具有至少一种由所述纳米复合材料或所述橡胶复合材料组成的组分的轮胎制造制品。 这种轮胎部件可以选自例如轮胎胎面和轮胎内衬。

    PNEUMATIC TIRE
    7.
    发明申请
    PNEUMATIC TIRE 审中-公开
    气动轮胎

    公开(公告)号：US20100078110A1

    公开(公告)日：2010-04-01

    申请号：US12241472

    申请日：2008-09-30

    申请人： Paul Harry Sandstrom ,  Ping Zhang ,  Xiaoping Yang ,  Joseph John Kulig ,  Aaron Scott Puhala ,  Rebecca Lee Dando

    发明人： Paul Harry Sandstrom ,  Ping Zhang ,  Xiaoping Yang ,  Joseph John Kulig ,  Aaron Scott Puhala ,  Rebecca Lee Dando

    IPC分类号： B60C1/00 ,  C08K3/34

    CPC分类号： B60C1/0016 ,  B60C1/00 ,  C08K3/346 ,  C08K5/548 ,  C08L9/06 ,  C08L23/18 ,  C08L65/00 ,  C08L91/06 ,  Y10T152/10846 ,  C08L2666/14

    摘要： The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising from about 50 to about 100 parts by weight, per 100 parts by weight of elastomer, of a vinylpyridine-styrene-butadiene (VPSBR) elastomer comprising units derived from monomers comprising styrene, 1,3-butadiene, and vinylpyridine monomers which have the structural formula: wherein R1 represents a hydrogen atom or a straight chain or branched alkyl group containing 1 to 4 carbon atoms, wherein the VPSBR comprises from about 0.1 to about 8 percent by weight of vinylpyridine monomer; from 0 to about 50 phr of at least one additional diene-based elastomer; from about 5 to about 15 phr of an at least partially exfoliated clay; and from about 1 to about 40 phr of a polyoctenamer.

    摘要翻译： 本发明涉及一种充气轮胎，其包括至少一种组分，所述至少一种组分包含橡胶组合物，所述橡胶组合物包含每100重量份弹性体约50至约100重量份的乙烯基吡啶 （VPSBR）弹性体，其包含衍生自包含苯乙烯，1,3-丁二烯和乙烯基吡啶单体的单体的单元，其具有以下结构式：其中R 1表示氢原子或含有1至4个碳的直链或支链烷基 原子，其中VPSBR包含约0.1至约8重量％的乙烯基吡啶单体; 0至约50phr的至少一种另外的二烯类弹性体; 约5至约15phr的至少部分脱落的粘土; 和约1至约40phr的聚辛烯。

    Sensor molecules incorporating a boronic acid sensor group
    8.
    发明授权
    Sensor molecules incorporating a boronic acid sensor group 有权
    掺入硼酸传感器组的传感器分子

    公开(公告)号：US08227254B2

    公开(公告)日：2012-07-24

    申请号：US11814965

    申请日：2006-01-31

    申请人： Christopher Robin Lowe ,  Felicity Kate Sartain ,  Xiaoping Yang

    发明人： Christopher Robin Lowe ,  Felicity Kate Sartain ,  Xiaoping Yang

    IPC分类号： G01N33/00 ,  C07C233/29 ,  C07C63/66 ,  C40B40/04 ,  C08F30/06 ,  B44F1/00 ,  G03F7/00 ,  G02B5/32

    CPC分类号： G01N33/5308 ,  Y10T436/201666

    摘要： The present invention pertains to compounds and polymers which incorporate a boronic acid sensor group (SG) of the formula (I): wherein: J is independently —CH2— or —CH2CH2—; n is independently 0, 1, 2, or 3; and each RR, if present, is independently a ring substituent; and wherein the ring attachment (i.e., where sensor group is attached) is via the 3-, 4-, 5-, or 6-ring position. Such compounds and polymers are useful in the selective chemical detection and/or quantitation of alpha-hydroxy carboxylic acids, such as lactic acid/lactate and malic acid/malate. The present invention also pertains to methods of preparing such compounds and polymers; methods and assays which employ these compounds and polymers; devices (e.g., holographic sensors) and kits for use in such methods and assays, etc.

    摘要翻译： 本发明涉及结合式（I）的硼酸传感器组（SG）的化合物和聚合物：其中：J独立地是-CH 2 - 或-CH 2 CH 2 - ; n独立地为0,1,2或3; 并且每个RR（如果存在的话）独立地是环取代基; 并且其中环附件（即，传感器组附接的位置）经由3-，4-，5-或6-环位置。 这些化合物和聚合物可用于α-羟基羧酸如乳酸/乳酸和苹果酸/苹果酸的选择性化学检测和/或定量。 本发明还涉及制备这种化合物和聚合物的方法; 使用这些化合物和聚合物的方法和测定法; 设备（如全息传感器）和用于此类方法和测定等的试剂盒

    Tire with component comprised of a blend of polybutadiene rubber and composite of styrene/butadiene elastomer which contains exfoliated clay platelets
    9.
    发明授权
    Tire with component comprised of a blend of polybutadiene rubber and composite of styrene/butadiene elastomer which contains exfoliated clay platelets 失效
    轮胎与由聚丁二烯橡胶和苯乙烯/丁二烯弹性体的混合物组成的组合物，其中含有剥离的粘土片晶

    公开(公告)号：US07714055B2

    公开(公告)日：2010-05-11

    申请号：US10923911

    申请日：2004-08-23

    申请人： David John Zanzig ,  Xiaoping Yang ,  Martin Paul Cohen

    发明人： David John Zanzig ,  Xiaoping Yang ,  Martin Paul Cohen

    IPC分类号： B60C1/00 ,  C08K3/34 ,  C08K3/04

    CPC分类号： C08K3/346 ,  B60C1/0016 ,  C08K3/013 ,  C08K5/548 ,  C08K9/04 ,  C08L9/00 ,  C08L9/06 ,  Y10S152/905 ,  C08L2666/08 ,  C08L21/00

    摘要： Pneumatic rubber tire having at least one component of a polybutadiene-rich rubber composition comprised of a blend of a continuous phase of a specialized cis 1,4-polybutadiene rubber and a dispersed phase comprised of a composite of styrene/butadiene elastomer which contains a dispersion of at least partially exfoliated, intercalated, clay platelets, wherein said cis 1,4-polybutadiene rubber and styrene/butadiene elastomer have spatially defined glass transition temperatures, wherein said blend contains amorphous silica and carbon black reinforcement. Such tire component may be, for example, a circumferential tread having a running surface intended to be ground-contacting or a sidewall insert.

    摘要翻译： 气动橡胶轮胎具有至少一种含聚丁二烯的橡胶组合物的组分，其由特殊的顺式1,4-聚丁二烯橡胶的连续相的共混物和由含有分散体的苯乙烯/丁二烯弹性体的复合物组成的分散相组成 的至少部分剥离的，插入的粘土片晶，其中所述顺式1,4-聚丁二烯橡胶和苯乙烯/丁二烯弹性体具有空间限定的玻璃化转变温度，其中所述共混物包含无定形二氧化硅和炭黑增强物。 这种轮胎部件可以是例如具有旨在被接地的行进面或侧壁插入物的周向胎面。