摘要:
Process for improving the brilliance of color and the stability of a colored polymer system, which is composed of a matrix and of discrete polymer particles distributed in accordance with a defined spatial lattice structure in the matrix, and which is obtained by filming of an emulsion polymer with core/shell structure, which comprises using an emulsion polymer obtainable by polymerizing monomers in at least one first stage (core monomers), then polymerizing monomers in at least one further, second stage (transition stage), and finally polymerizing monomers in a third stage (shell monomers), where, based on the percentage constitution of the monomer mixtures of the three stages, at most 30% by weight of the monomers of the first stage are identical with those of the third stage, and 5% of the monomers of the second stage are identical with, respectively, those of the first and those of the third stage, and not more than 60% by weight of the monomers of the 2nd stage here are monomers absent in the 1st stage and also absent in the 3rd stage.
摘要:
Use of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with polyvalent metal ions and/or cationic surfactants, the particle size of which is 10 nm to 100 μm, as additive to rinse compositions, care compositions, detergents and cleaners, and also rinse compositions, care compositions, detergents and cleaners which comprise the cationically modified, particulate, hydrophobic polymers.
摘要:
The invention relates to the use of cationically-modified, particle-shaped, hydrophobic polymers as addition agents in rinsing, care, detergent, and cleaning products. The surface of said polymers is cationically modified by means of a coating of cationic polymers and the particle size of said polymers ranges from 10 nm to 100 μm.
摘要:
Aqueous polymer dispersions which are obtainable by emulsion polymerization of ethylenically unsaturated monomers in an aqueous medium in the presence of free radical polymerization initiators and stabilizers, amphiphilic polymers which comprise one or more hydrophobic units (A) and one or more hydrophilic units (B) being used as the stabilizer before, during or after the polymerization, and the hydrophobic units (A) being formed from a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged doubled bonds, processes for the preparation of the aqueous polymer dispersions by polymerizing ethylenically unsaturated monomers in the presence of free radical initiators and said amphiphilic polymers, which are used before, during or after the polymerization, and the use of the resulting aqueous polymer dispersions as associative thickeners in paper coating slips, in textile production, as thickeners for textile print pastes, in the pharmaceutical and cosmetics sector, for surface coatings, for detergents and cleaning agents, in foods and as oil field chemicals.
摘要:
Aqueous alkenylsuccinic anhydride-containing polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkenylsuccinic anhydrides, processes for the preparation of such polymer dispersions by polymerizing hydrophobic monomers by a miniemulsion polymerization method in the presence of at least one alkenylsuccinic anhydride and, if appropriate, an alkyldiketene, and use of the resulting aqueous alkenylsuccinic anhydride-containing polymer dispersions as engine and surface sizes for paper and for imparting water repellency to leather, natural and/or synthetic fibers and textiles.
摘要:
A storage-stable aqueous miniemulsion whose disperse phase comprises a cholesteric mixture is prepared and is used for coating and printing on suitable substrates.
摘要:
Hexaarylbisimidazoles I ##STR1## where Ar.sup.1, Ar.sup.2 and Ar.sup.3 are each aryl, of which Ar.sup.2 and Ar.sup.3 can be linked to form an anellated ring system, are prepared by oxidizing the corresponding triarylimidazoles II in an aqueous/organic two-phase system in the presence of active amounts of an onium salt III.
摘要:
In the production of resist images by application of a radiation-sensitive positive-working resist layer based on degradable polymers onto a substrate, imagewise exposure of the resist layer to actinic radiation and removal of the irradiated parts of the layer with development of the resist image, the radiation-sensitive resist layer used is composed of poly(diacetylenes), in particular soluble ones. Preferably, the radiation-sensitive resist layer based on the poly(diacetylenes) contains sensitizers which can be activated by actinic radiation and which, after being activated, induce or accelerate molecular degradation of the poly(diacetylenes). Dry film resists comprise a temporary dimensionally stable base and a radiation-sensitive resist layer which is applied on the base, can be degraded by exposure to actinic radiation and is based on poly(diacetylenes), in particular soluble ones, with or without a cover sheet on top of the said resist layer.
摘要:
The present invention relates to a thickener preparable by a process which comprises obtaining a cationic polymer by inverse emulsion polymerization of a) at least one water-soluble ethylenically unsaturated monomer comprising at least one cationic monomer, optionally at least one anionic monomer and/or optionally at least one nonionic monomer, b) at least one ethylenically unsaturated associative monomer, c) optionally at least one crosslinker, d) optionally at least one chain transfer agent, the temperature being kept constant during the inverse emulsion polymerization and being at least 40° C., preferably 50 to 90° C., and after the inverse emulsion polymerization has ended, activator being added to obtain the thickener.
摘要:
Copolymers, their use as thickeners, and methods for their preparation The present invention relates to copolymers comprising as comonomers in copolymerized form (A) at least one ethylenically unsaturated mono- or dicarboxylic acid, (B) at least one ethylenically unsaturated compound which has at least one structural unit of the general formula (I) per molecule: where the variables are defined as follows: R1 is different or identical and selected from hydrogen, C1-C30-alkyl, C6-C30-aryl and C7-C30-aralkyl, A1 is different or identical and selected from C2-C10-alkylene, C6-C10-arylene and C7-C10-aralkylene, n is different or identical and selected from zero to 200, m is different or identical and selected from 1 to 6, (C) at least one further comonomer.