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公开(公告)号：US4397994A
公开(公告)日：1983-08-09
申请号：US303518
申请日：1981-09-18
IPC分类号： B65H75/40 , C08C19/44 , C08F2/06 , C08F4/46 , C08F8/42 , C08F8/44 , C08F30/04 , C08F30/10 , C08F36/06 , C08F212/08 , C08G81/02 , C08L9/00 , C08L9/06 , C08L25/04 , D21H13/44 , C08F8/18
CPC分类号： D21H13/44 , C08C19/44 , C08G81/022 , D21H5/186
摘要： High vinyl polybutadiene or styrene-butadiene copolymer obtained by polymerizing 1,3-butadiene alone or with styrene in a hydrocarbon solvent using an organolithium compound as an initiator and coupling the resulting polymer, characterized in that(1) the polybutadiene or styrene-butadiene copolymer comprises at least 20% by weight of a polymer having in its molecular chain a linkage between butadienyl and at least one metal selected from the group consisting of silicon, germanium, tin and lead,(2) the styrene content of said copolymer is 40% by weight or less, and(3) the polybutadiene or the butadiene portion of the styrene-butadiene copolymer has a vinyl content of 50 to 95%.Said polybutadiene or styrene-butadiene copolymer has low rolling resistance, high wet skid resistance, highly improved fracture property and, an excellent processability.
摘要翻译： 通过使用有机锂化合物作为引发剂在烃溶剂中单独或与苯乙烯聚合而获得的高乙烯基聚丁二烯或苯乙烯 - 丁二烯共聚物，并将所得聚合物偶联，其特征在于（1）聚丁二烯或苯乙烯 - 丁二烯共聚物 包含至少20重量％的聚合物，其分子链中是丁二烯基与选自硅，锗，锡和铅中的至少一种金属之间的连接，（2）所述共聚物的苯乙烯含量为40％ 以下，（3）苯乙烯 - 丁二烯共聚物的聚丁二烯或丁二烯部分的乙烯基含量为50〜95％。 所述聚丁二烯或苯乙烯 - 丁二烯共聚物具有低滚动阻力，高抗湿滑性，高度改善的断裂性能和优异的加工性能。
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2.发明授权
公开(公告)号：US4367325A
公开(公告)日：1983-01-04
申请号：US254517
申请日：1981-04-15
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F4/00 , C08F4/42 , C08F4/48 , C08F236/00 , C08F236/10
CPC分类号： C08F236/10
摘要： Styrene-butadiene random copolymers having an average vinyl content of at least 70%, a breadth of the distribution of vinyl contents of at least 20%, a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 150, and a styrene content of about 3 to 30% by weight. They are prepared by copolymerizing styrene and butadiene in a hydrocarbon solvent in the presence of an organolithium initiator and a Lewis base and, if necessary, an anionic surface active agent containing --SO.sub.3 M or --OSO.sub.3 M (wherein M is Na, K, Rb or Cs) under temperature-raising conditions. They are rubber materials having low rolling resistance and high wet skid resistance.
摘要翻译： 平均乙烯基含量至少为70％，乙烯基含量分布宽度至少为20％，门尼粘度（ML1 + 4,100℃）为10至150的苯乙烯 - 丁二烯无规共聚物和 苯乙烯含量为约3至30重量％。 它们是通过在有机锂引发剂和路易斯碱存在下在烃溶剂中共聚合苯乙烯和丁二烯而制备的，如果需要，可以使用含有-SO 3 M或-OSO 3 M的阴离子表面活性剂（其中M是Na，K，Rb或Cs ）在升温条件下。 它们是具有低滚动阻力和高抗湿滑性的橡胶材料。
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公开(公告)号：US4533711A
公开(公告)日：1985-08-06
申请号：US530169
申请日：1983-09-07
申请人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Nobuo Tagata , Masaki Ogawa , Yasushi Hirata , Shigeru Tomihira
发明人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Nobuo Tagata , Masaki Ogawa , Yasushi Hirata , Shigeru Tomihira
CPC分类号： C08F136/06
摘要： A polybutadiene rubber composition having an improved green strength is disclosed, which comprises a polybutadiene having a content of cis-1,4 bond of at least 70%, an average chain length of 1,4-bond of 110.about.450 and a molecular weight distribution represented by a ratio of weight-average molecular weight to number-average molecular weight of not less than 5.0.
摘要翻译： 公开了具有改善的生坯强度的聚丁二烯橡胶组合物，其包含具有至少70％的顺式-1,4-键的聚丁二烯，110分子的450的平均链长度以及分子量 由重均分子量与数均分子量的比率表示的分布不小于5.0。
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公开(公告)号：US4433109A
公开(公告)日：1984-02-21
申请号：US330862
申请日：1981-12-15
IPC分类号： C08F297/04 , C08G81/02
CPC分类号： C08G81/022 , C08F297/04
摘要： A styrene-butadiene block copolymer having a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 150 comprising two specific random styrene-butadiene copolymer blocks different in bound styrene content and in vinyl content in the butadiene portion, and optionally polybutadiene blocks, wherein the total vinyl content in the whole bound butadiene is 30 to 70% and the total bound styrene content is 10 to 40% by weight. Said block copolymer is excellent in wet skid resistance and rolling resistance, well-balanced in fracture and wear characteristics and also satisfactory in processability and cold flow property.
摘要翻译： 具有10至150的门尼粘度（ML1 + 4,100℃）的苯乙烯 - 丁二烯嵌段共聚物，其包含在结合的苯乙烯含量中不同的两种特定的无规苯乙烯 - 丁二烯共聚物嵌段和丁二烯部分中的乙烯基含量，以及任选的聚丁二烯 嵌段，其中整个结合的丁二烯中的总乙烯基含量为30〜70％，总结合苯乙烯含量为10〜40重量％。 所述嵌段共聚物的耐湿滑性和滚动阻力优异，断裂和磨损特性平衡，加工性和冷流动性也令人满意。
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公开(公告)号：US06451458B1
公开(公告)日：2002-09-17
申请号：US09450127
申请日：1999-11-26
IPC分类号： H05B3314
CPC分类号： H01L51/004 , H01L51/0042 , H01L51/0043 , H01L51/005 , H01L51/5012
摘要： An electroluminescent cell which exhibits a high luminous efficiency and excellent durability is provided. The electroluminescent material comprises a unit (AB) which is formed by alternate copolymerization of hole transfer monomers and electron transfer monomers, and a unit (A) which is formed by the polymerization of hole transfer monomers, wherein the molar ratio of the total of the structural units originating from the hole transfer monomers and the structural units originating from the electron transfer monomers in the unit (AB) and the structural units originating from the hole transfer monomers in the unit (A) is from 50:50 to 5:95. The electroluminescent cell has an anode layer 2, an electroluminescent material layer 3 made from the electroluminescent material, an electron transfer luminous layer 4, and a cathode layer 5.
摘要翻译： 提供了具有高发光效率和优异的耐久性的电致发光单元。 电致发光材料包括通过空穴转移单体和电子转移单体的交替共聚而形成的单元（AB）和通过空穴转移单体的聚合形成的单元（A），其中总共的摩尔比 源自空穴转移单体的结构单元和源自单元（AB）中的电子转移单体的结构单元和源自单元（A）中的空穴转移单体的结构单元的比例为50:50至5:95。 电致发光单元具有阳极层2，由电致发光材料制成的电致发光材料层3，电子转移发光层4和阴极层5。
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公开(公告)号：US4468496A
公开(公告)日：1984-08-28
申请号：US401509
申请日：1982-07-26
申请人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Nobuo Tagata , Masaki Ogawa , Yasushi Hirata , Shigeru Tomihira
发明人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Nobuo Tagata , Masaki Ogawa , Yasushi Hirata , Shigeru Tomihira
IPC分类号： C08L7/00 , C08F36/00 , C08F136/06 , C08K3/00 , C08L1/00 , C08L9/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08L9/02 , C08L47/00
摘要： A rubber composition having excellent fracture properties and cut growth resistance is disclosed, which consists of 10-95 parts by weight of polybutadiene having a content of cis-1,4 bond of at least 70% and an average chain length of 1,4-sequence of 110-450 and 90-5 parts by weight of at least one diene rubber.
摘要翻译： 公开了一种具有优异的断裂性能和抗切削生长性的橡胶组合物，其由10-95重量份具有至少70％的顺式-1,4键的平均链长度为1,4-丁二烯的聚丁二烯组成， 序列为110-450和90-5重量份的至少一种二烯橡胶。
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公开(公告)号：US6007928A
公开(公告)日：1999-12-28
申请号：US131691
申请日：1998-08-10
IPC分类号： C08F297/00 , C09K11/06 , H01L51/50 , H05B33/00
CPC分类号： H01L51/5012 , Y10S428/917
摘要： An EL cell exhibiting high luminous efficiency and excellent durability is disclosed. The EL cell comprises a layer of a block copolymer comprising a block component (A) of the following formula (1) having a positive hole transfer capability and a block component (B) of the following formula (2) having an electron transfer capability at molar ratio of the block component (A) to the block (B) between 0.1:99.9 and 99.9:0.1. ##STR1##
摘要翻译： 公开了具有高发光效率和优异耐久性的EL电池。 EL电池包括含有具有空穴转移能力的下式（1）的嵌段组分（A）和下式（2）的具有电子转移能力的下式（2）的嵌段组分（A）的嵌段共聚物层： 嵌段组分（A）与嵌段（B）的摩尔比在0.1:99.9和99.9:0.1之间。
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公开(公告)号：US4463133A
公开(公告)日：1984-07-31
申请号：US384371
申请日：1982-06-02
申请人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Fumio Tsutsumi , Akio Takashima , Tatsuo Fujimaki , Shinsuke Yamaguchi , Seisuke Tomita
发明人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Fumio Tsutsumi , Akio Takashima , Tatsuo Fujimaki , Shinsuke Yamaguchi , Seisuke Tomita
IPC分类号： C08F8/00 , B60C1/00 , C08F8/42 , C08F297/00 , C08F297/02 , C08F297/04 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L53/00 , C08L53/02 , C08L77/00 , C08L101/00 , C08L9/00 , C08L9/06
CPC分类号： C08L9/06 , B60C1/0016 , C08F297/04 , C08L21/00 , C08L7/00 , C08L53/02 , C08L53/025 , Y10S525/914
摘要： A rubber composition suitable for use in tire tread is disclosed, which contains at least 20 parts by weight of a block copolymer per 100 parts by weight of total rubber content. This block copolymer comprises (A) a polymer segment obtained by starting from conjugated diolefin and monovinyl aromatic hydrocarbon and having a content of monovinyl aromatic hydrocarbon bond of not more than 10% by weight and (B) a copolymer segment obtained by copolymerization of conjugated diolefin and monovinyl aromatic hydrocarbon and having a content of monovinyl aromatic hydrocarbon bond of 15-50% by weight. Further, the block copolymer satisfies the following conditions:(i) the block copolymer contains at least 10% by weight of each of the segments (A) and (B);(ii) a total content of monovinyl aromatic hydrocarbon bond in the block copolymer is 10-40% by weight;(iii) an average content of vinyl bond in conjugated diolefin portion of the block copolymer is 20-70% by weight; and(iv) the block copolymer includes at least 20% by weight of a polymer having a metal-carbon bond in its molecular chain.
摘要翻译： 公开了一种适用于轮胎胎面的橡胶组合物，每100重量份总橡胶含量含有至少20重量份的嵌段共聚物。 该嵌段共聚物包括（A）通过共轭二烯烃和单乙烯基芳族烃起始并且单乙烯基芳族烃键含量不超过10重量％获得的聚合物链段，和（B）通过共轭二烯烃 和单乙烯基芳烃，并且具有15-50重量％的单乙烯基芳族烃键的含量。 此外，嵌段共聚物满足以下条件：（i）嵌段共聚物含有至少10重量％的各段（A）和（B）; （ii）嵌段共聚物中单乙烯基芳烃键的总含量为10〜40重量％ （iii）嵌段共聚物的共轭二烯烃部分中的乙烯基键的平均含量为20〜70重量％ 和（iv）嵌段共聚物包括至少20重量％的在其分子链中具有金属 - 碳键的聚合物。
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公开(公告)号：US4433107A
公开(公告)日：1984-02-21
申请号：US404750
申请日：1982-08-03
申请人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Nobuo Tagata , Masaki Ogawa , Yasushi Hirata , Shigeru Tomihira
发明人： Yasumasa Takeuchi , Mitsuhiko Sakakibara , Nobuo Tagata , Masaki Ogawa , Yasushi Hirata , Shigeru Tomihira
IPC分类号： C08L7/00 , C08F4/54 , C08F4/60 , C08F136/08 , C08L1/00 , C08L9/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00
CPC分类号： C08L21/00
摘要： A rubber composition having improved cut growth resistance, processability and dimensional stability is disclosed, which comprises not less than 20 parts by weight of polyisoprene having a melting point of not less than 10.degree. C. and a content of cis-1,4 bond of not less than 88% and the balance of at least one diene rubber.
摘要翻译： 公开了具有提高的切割生长性，加工性和尺寸稳定性的橡胶组合物，其包含不少于20重量份的熔点不低于10℃的聚异戊二烯和顺式-1,4键的含量 不少于88％，余量为至少一种二烯橡胶。
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10.发明授权Process for producing conjugated diene polymer using a solubilized lanthanum carboxylate catalyst 失效使用溶解的镧羧酸盐催化剂制备共轭二烯聚合物的方法
公开(公告)号：US4461883A
公开(公告)日：1984-07-24
申请号：US387780
申请日：1982-06-14
CPC分类号： C08F36/04
摘要： A process for producing a conjugated diene polymer, characterized by polymerizing at least one conjugated diene with a catalyst consisting of (A) a reaction product of a Lewis base and a carboxylate of a rare earth element of the lanthanum series represented by Ln(R.sup.1 CO.sub.2).sub.3 wherein Ln is a rare earth element of the lanthanum series having an atomic number of 57 to 71 and R.sup.1 is a hydrocarbon substituent having 1 to 20 carbon atoms, (B) an organic aluminum compound represented by AlR.sup.2 R.sup.3 R.sup.4 wherein R.sup.2, R.sup.3 and R.sup.4, which may be identical or different, represent hydrogen atoms or hydrocarbon substituents having 1 to 8 carbon atoms, excluding the case where all of R.sup.2, R.sup.3 and R.sup.4 are hydrogen atoms at the same time, and (C) an (alkyl)aluminum halide represented by AlX.sub.n R.sup.5.sub.3-n wherein X is Cl, Br, F or I; R.sup.5 is a hydrocarbon substituent having 1 to 8 carbon atoms; and n has a value of 1, 1.5, 2 or 3, or consisting of these (A), (B) and (C) components and (D) a conjugated diene. A polymer obtained by said process has a high cis-1,4-configuration content and is excellent in physical properties of vulcanizate.
摘要翻译： 一种共轭二烯聚合物的制备方法，其特征在于，将由（L）（R 1 CO 2）表示的镧系稀土元素的路易斯碱与羧酸酯的反应产物与（A） 3其中Ln是原子序数为57〜71的镧系稀土元素，R1为碳原子数1〜20的烃取代基，（B）由AlR2R3R4表示的有机铝化合物，其中R2，R3和R4， 可以相同或不同，表示氢原子或具有1至8个碳原子的烃取代基，不包括所有R 2，R 3和R 4同时为氢原子的情况，（C）（烷基）卤化铝代表 通过AlXnR53-n，其中X是Cl，Br，F或I; R5是具有1-8个碳原子的烃取代基; 并且n具有1,1.5,2或3的值，或由这些（A），（B）和（C）组分组成，和（D）共轭二烯。 通过所述方法获得的聚合物具有高顺式-1,4-构型含量，并且硫化橡胶的物理性能优异。
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