Porous, molecularly imprinted polymer and a process for the preparation thereof
    1.
    发明授权
    Porous, molecularly imprinted polymer and a process for the preparation thereof 有权
    多孔分子印迹聚合物及其制备方法

    公开(公告)号:US07393909B2

    公开(公告)日:2008-07-01

    申请号:US11051508

    申请日:2005-02-07

    IPC分类号: C08F12/02 C08F112/02

    摘要: A porous, molecularly imprinted polymer and a process for its preparation are described. The porous, molecularly imprinted polymer is characterized in that it is obtainable by providing a porous silica; attaching a molecular template to the surface of the porous silica; filling the pores of the porous silica with a polymer, removing the silica and the molecular template, thereby leaving a porous, molecularly imprinted polymer. The process is characterized by the above defined process steps. Also described are a porous polymer vesicle and its preparation with the same features as defined for the porous, molecularly imprinted polymer and its preparation, except for the lack of the molecular template and thus the lack of the molecular imprint in the porous polymer.

    摘要翻译: 描述了多孔的分子印迹聚合物及其制备方法。 多孔分子印迹聚合物的特征在于可通过提供多孔二氧化硅获得; 将分子模板附着到多孔二氧化硅的表面; 用聚合物填充多孔二氧化硅的孔,除去二氧化硅和分子模板,从而留下多孔的分子印迹聚合物。 该过程的特征在于上述定义的工艺步骤。 还描述了多孔聚合物囊泡及其具有与多孔分子印迹聚合物及其制备所定义相同特征的制剂,不同之处在于缺少分子模板,因此在多孔聚合物中缺少分子印迹。

    Monodisperse Molecularly Imprinted Polymer Beads
    2.
    发明申请
    Monodisperse Molecularly Imprinted Polymer Beads 审中-公开
    单分散分子印迹聚合物珠

    公开(公告)号:US20090281272A1

    公开(公告)日:2009-11-12

    申请号:US12086137

    申请日:2006-12-06

    IPC分类号: C08G69/26

    摘要: The invention relates to a molecularly imprinted polymer resin characterized by a monodisperse size distribution prepared by forming monomer droplets via a membrane, polymerizing said droplets in an appropriate continuous phase, and harvesting the resulting polymer particles. The invention also relates to a method for producing a molecularly imprinted polymer resin, wherein a monomer solution is forced through a dispersing device capable of forming small droplets, the droplets are projected into a continuous phase in which a polymerization is initiated leading to solidification of the droplets into beads.

    摘要翻译: 本发明涉及一种分子印迹聚合物树脂,其特征在于通过经由膜形成单体液滴,以合适的连续相聚合所述液滴并收获所得聚合物颗粒而制备的单分散尺寸分布。 本发明还涉及一种生产分子印迹聚合物树脂的方法,其中单体溶液被迫通过能够形成小液滴的分散装置,液滴投射到其中开始聚合的连续相,导致固化 液滴成珠。

    Polymer Films
    3.
    发明申请
    Polymer Films 审中-公开
    聚合物膜

    公开(公告)号:US20080033073A1

    公开(公告)日:2008-02-07

    申请号:US11629477

    申请日:2005-07-01

    IPC分类号: C08F265/02 C08K5/16

    摘要: This invention relates to a non-supported (or free standing) cross linked polymer film obtainable by initiating the polymerization of one or several monomers at an interphase. The interphase may be between two immiscible liquids or at a liquid-gas, solid-gas or solid-liquid interphase. The polymer may be used to facilitate chemical reactions, for separation of substances, as a chromatographic stationary phase, as an adsorbent, in sensors or actuators. It may also be used for drug delivery, as a responsive valve or in artificial muscles. The invention also relates to a method for producing thin film polymers, wherein controlled radical polymerization (CRP) is used to produce a thin film cross-linked polymer at an interface where one of the phases (liquid, solid or gas) can be removed after polymerization and be replaced with another phase (liquid, solid or gas).

    摘要翻译: 本发明涉及通过在相间引发一种或几种单体的聚合而获得的非支撑(或自由置换)交联聚合物膜。 相间可以在两种不混溶的液体之间或在液体气体,固体气体或固液相间。 该聚合物可用于促进化学反应,用于分离物质,作为色谱固定相,作为吸附剂,在传感器或致动器中。 它也可以用作药物递送,作为响应阀或人造肌肉。 本发明还涉及一种生产薄膜聚合物的方法,其中使用受控自由基聚合(CRP)在界面处制备薄膜交联聚合物,其中可以在其中一个相(液体,固体或气体) 聚合并被另一相(液体,固体或气体)代替。

    Porous, molecularly imprinted polymer and a process for the preparation thereof
    4.
    发明授权
    Porous, molecularly imprinted polymer and a process for the preparation thereof 有权
    多孔分子印迹聚合物及其制备方法

    公开(公告)号:US06881804B1

    公开(公告)日:2005-04-19

    申请号:US10111816

    申请日:2000-10-26

    摘要: A porous, molecularly imprinted polymer and a process for its preparation are described. The porous, molecularly imprinted polymer is characterised in that it is obtainable by providing a porous silica; attaching a molecular template to the surface of the porous silica; filling the pores of the porous silica with a polymer, removing the silica and the molecular template, thereby leaving a porous, molecularly imprinted polymer. The process is characterised by the above defined process steps. Also described are a porous polymer vesicle and its preparation with the same features as defined for the porous, molecularly imprinted polymer and its preparation, except for the lack of the molecular template and thus the lack of the molecular imprint in the porous polymer.

    摘要翻译: 描述了多孔的分子印迹聚合物及其制备方法。 多孔分子印迹聚合物的特征在于可通过提供多孔二氧化硅获得; 将分子模板附着到多孔二氧化硅的表面; 用聚合物填充多孔二氧化硅的孔,除去二氧化硅和分子模板,从而留下多孔的分子印迹聚合物。 该过程的特征在于上述定义的工艺步骤。 还描述了多孔聚合物囊泡及其具有与多孔分子印迹聚合物及其制备所定义相同特征的制剂,不同之处在于缺少分子模板,因此在多孔聚合物中缺少分子印迹。

    Method for Producing Molecularly Imprinted Polymers for the Recognition of Target Molecules
    10.
    发明申请
    Method for Producing Molecularly Imprinted Polymers for the Recognition of Target Molecules 审中-公开
    生产用于识别目标分子的分子印迹聚合物的方法

    公开(公告)号:US20080038832A1

    公开(公告)日:2008-02-14

    申请号:US11665239

    申请日:2005-10-12

    IPC分类号: G01N33/00 C08G73/00

    摘要: The present invention relates to a method of preparing a molecularly imprinted polymer (MIP), which are used for the recognition of target molecules comprising: co-polymerising at least one functional monomer and at least one cross-linking monomer in the presence of at least one template, wherein oxyanions are used as template and the steric and/or electronic structure of the template is at least partly analogous to the target molecule. The target molecules may be nitro-containing compounds, such as nitroaromatic compounds, or lactones. MIPs selective for explosive nitro-aromatic substances may be produced without handling these hazardous compounds. The invention further relates to a method of determining if a sample contains nitro-containing compounds, such as nitroaromatic compounds, or lactones, MIPs selective for nitro-containing compounds and/or lactones, especially nitro-aromatic compounds and a kit, comprising a molecularly imprinted polymer selective for nitro-aromatic compounds and/or lactones. The invention also relates to use of isosteric and/or isoelectronic oxyanions for the production of MIPs for recognition of nitro-containing compounds, especially nitroaromatic compounds, and lactones.

    摘要翻译: 本发明涉及制备分子印迹聚合物(MIP)的方法,其用于识别靶分子,包括:在至少存在下共聚至少一种官能单体和至少一种交联单体 一个模板,其中使用氧阴离子作为模板,并且模板的空间和/或电子结构至少部分类似于靶分子。 靶分子可以是含硝基化合物,例如硝基芳族化合物或内酯。 可以在不处理这些有害化合物的情况下生产对爆炸性硝基芳族物质有选择性的MIP。 本发明还涉及一种确定样品是否含有含硝基化合物如硝基芳族化合物或内酯的方法,对含硝基化合物和/或内酯,特别是硝基芳族化合物和试剂盒有选择性的MIP,包括分子式 对硝基芳族化合物和/或内酯具有选择性的印迹聚合物。 本发明还涉及等熵和/或等电子含氧阴离子用于生产用于识别含硝基化合物,特别是硝基芳族化合物和内酯的MIP。