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    Production of organic vanadates
    2.
    发明授权
    Production of organic vanadates 失效
    生产有机钒酸盐

    公开(公告)号：US4739086A

    公开(公告)日：1988-04-19

    申请号：US913256

    申请日：1986-09-30

    Applicant: Robert N. DePriest

    Inventor： Robert N. DePriest

    IPC: C07C29/68 ,  C07F9/00

    CPC classification number: C07F9/005 ,  C07C29/685

    Abstract: Vanadium oxytrihalide (e.g., VOCl.sub.3) is reacted with alkali metal alkoxide (e.g., NaOEt) in the presence of a diluent (e.g., EtOH) that boils below the boiling point of the organic vanadate being produced. The diluent is then distilled from the reaction mixture and thereafter the organic vanadate is distilled from a suspension of the reaction products in an inert liquid hydrocarbon (e.g., mineral oil) that boils above the boiling point of the organic vanadate produced. This higher boiling hydrocarbon is preferably added to the reaction mixture after the diluent has been distilled off. The process avoids hydrogen halide evolution and consequent need for gaseous ammonia. Solvent extractions are not required, the process may be conducted in a single reactor, and the products are readily formed in high yields.

    Abstract translation: 氧化三卤化物（例如VOCl 3）与碱金属醇盐（例如NaOEt）在稀释剂（例如EtOH）的存在下反应，稀释剂（例如EtOH）沸点低于所生产的有机钒酸盐的沸点。 然后将稀释剂从反应混合物中蒸馏出来，然后将有机钒酸盐从反应产物的悬浮液中蒸发到沸点高于所生成的有机钒酸盐的沸点的惰性液体烃（例如矿物油）中。 在蒸馏出稀释剂之后，优选将该较高沸点的烃加入到反应混合物中。 该方法避免了卤化氢的逸出，并因此需要气态氨。 不需要溶剂萃取，该方法可以在单个反应器中进行，并且产物容易以高产率形成。

    Process for synthesizing alkoxyalanates of alkaline earth metals
    3.
    发明授权
    Process for synthesizing alkoxyalanates of alkaline earth metals 失效
    合成碱土金属烷氧基化物的方法

    公开(公告)号：US4278611A

    公开(公告)日：1981-07-14

    申请号：US108225

    申请日：1979-12-28

    Applicant: Salvatore Cucinella ,  Giovanni Dozzi

    Inventor： Salvatore Cucinella ,  Giovanni Dozzi

    IPC: C07C29/68 ,  C07C27/00 ,  C07C29/70 ,  C07C31/32 ,  C07C67/00 ,  C07F5/06

    CPC classification number: C07F5/069 ,  C07C29/685 ,  C07C29/70 ,  C07C31/32

    Abstract: A method for the preparation of alkoxyalanates of alkaline earth metals is disclosed, which comprises the step of reacting an alcoholate of an alkaline earth metal and an alkaline earth metal alanate and an aluminum alcoholate, the reaction being of the additive type.The products thus obtained are effective catalysts for reactions of reduction, more particularly of hydrogenation of a number of organic compounds.

    Abstract translation: 公开了一种制备碱土金属烷氧基化物的方法，其包括使碱土金属的醇化物与碱土金属铝酸盐和醇铝的反应的步骤，该反应为添加剂型。 由此获得的产物是还原反应的有效催化剂，更特别是许多有机化合物的氢化反应。

    Synthesis of gallium and indium alkoxides
    6.
    发明授权
    Synthesis of gallium and indium alkoxides 失效

    公开(公告)号：US07585992B2

    公开(公告)日：2009-09-08

    申请号：US12230472

    申请日：2008-08-29

    Applicant: Timothy Leedham

    Inventor： Timothy Leedham

    IPC: C07F5/00

    CPC classification number: C07C29/685 ,  C07C31/28 ,  C07C31/30

    Abstract: A method of synthesising gallium or indium alkoxide from the corresponding gallium or indium halide, the method comprising the step of reacting the gallium or indium metal halide with the alkoxide of an alkali earth metal, to produce the desired metal alkoxide essentially free of chlorine contamination. The method provides a composition comprising a solution of gallium or indium alkoxide of high purity, the composition having a chloride content of less than 30 ppm, a barium or strontium content of less than 30 ppm, and a sodium or potassium content of less than 30 ppm, without requiring any additional steps.

    Simultaneous production of alcoholates and trivalent titanium complexes of beta-diketones
    8.
    发明授权
    Simultaneous production of alcoholates and trivalent titanium complexes of beta-diketones 失效
    乙醇酸盐的同时生产和BETA-DIKETONES的多晶钛复合物

    公开(公告)号：US3716567A

    公开(公告)日：1973-02-13

    申请号：US3716567D

    申请日：1970-09-08

    Applicant: DYNAMIT NOBEL AG

    Inventor： TERMIN E ,  HAUCK G

    IPC: C07C29/68 ,  C07C31/28 ,  C07C31/30 ,  C07F7/00 ,  C08F4/16 ,  C07F7/28

    CPC classification number: C07C29/685 ,  C07C31/28 ,  C07C31/30 ,  C07F7/006

    Abstract: Tetravalent titanium alcoholate-beta diketone complexes, e.g. titanium isopropylate-triacetylacetonate, are reacted with an alkali metal amalgam in a non-polar solvent to reduce the titanium to trivalent state, forming, for example, titanium triacetylacetonate and sodium isopropylate. The sodium isopropylate is a crystalline precipitate which can be removed by filtration; the amalgam can be decanted off and reused, as in alkali metal chloride electrolysis, to restore its alkali metal content so as to be ready for re-cycling.

    Abstract translation: 四价钛醇化物-β二酮络合物，例如 异丙酯 - 三乙酰丙酮钛与非极性溶剂中的碱金属汞齐反应以将钛还原成三价态，形成例如三乙酰丙酮钛和异丙醇钠。 异丙醇钠是结晶沉淀物，可通过过滤除去; 可以将碱金属氯化物电解中的汞齐滗析并重复使用，以恢复其碱金属含量，以准备重新循环。

    Synthesis of gallium and indium alkoxides
    9.
    发明申请
    Synthesis of gallium and indium alkoxides 失效
    镓和铟醇盐的合成

    公开(公告)号：US20090112012A1

    公开(公告)日：2009-04-30

    申请号：US12230472

    申请日：2008-08-29

    Applicant: Timothy Leedham

    Inventor： Timothy Leedham

    IPC: C07F7/00 ,  C07F17/00

    CPC classification number: C07C29/685 ,  C07C31/28 ,  C07C31/30

    Abstract: A method of synthesising gallium or indium alkoxide from the corresponding gallium or indium halide, the method comprising the step of reacting the gallium or indium metal halide with the alkoxide of an alkali earth metal, to produce the desired metal alkoxide essentially free of chlorine contamination. The method provides a composition comprising a solution of gallium or indium alkoxide of high purity, the composition having a chloride content of less than 30 ppm, a barium or strontium content of less than 30 ppm, and a sodium or potassium content of less than 30 ppm, without requiring any additional steps.

    Abstract translation: 从相应的镓或铟卤化物合成镓或铟醇盐的方法，该方法包括使镓或铟金属卤化物与碱土金属的醇盐反应的步骤，以产生基本上不含氯污染物的所需金属醇盐。 该方法提供包含高纯度的镓或铟醇盐溶液的组合物，该组合物的氯化物含量小于30ppm，钡或锶含量小于30ppm，钠或钾含量小于30 ppm，而不需要任何额外的步骤。

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