Silicone-acrylic impact modifier having improved colorability and thermoplastic resin composition comprising the same
    5.
    发明申请
    Silicone-acrylic impact modifier having improved colorability and thermoplastic resin composition comprising the same 有权
    具有改进着色性的硅氧烷 - 丙烯酸类抗冲击改性剂和包含其的热塑性树脂组合物

    公开(公告)号:US20060089456A1

    公开(公告)日:2006-04-27

    申请号:US11257692

    申请日:2005-10-25

    Abstract: The present invention relates to a silicone-acrylic impact modifier having multi-layer structure and a thermoplastic resin composition containing the same, more precisely a silicone-acrylic impact modifier which is composed of i) silicone rubber seed containing one or more vinyl copolymers; ii) acrylic rubber core covering the seed; and iii) a shell containing one or more vinyl copolymers covering the acrylic rubber core, and a thermoplastic resin composition containing the same. The thermoplastic resin having the silicone-acrylic impact modifier of the present invention has improved impact resistance and colorability.

    Abstract translation: 本发明涉及具有多层结构的有机硅 - 丙烯酸类抗冲击改性剂和含有该聚丙烯类抗冲改性剂的热塑性树脂组合物,更具体地说,涉及含有一种或多种乙烯基共聚物的硅橡胶种子组成的有机硅 - 丙烯酸类抗冲改性剂。 ii)覆盖种子的丙烯酸橡胶芯; 和iii)包含一种或多种覆盖丙烯酸橡胶芯的乙烯基共聚物的壳和含有该丙烯酸橡胶芯的热塑性树脂组合物。 具有本发明的有机硅 - 丙烯酸类抗冲改性剂的热塑性树脂具有改善的耐冲击性和着色性。

    SHAPED ARTICLE HAVING FINE SURFACE IRREGULARITIES AND METHOD FOR PRODUCING THE SHAPED ARTICLE
    7.
    发明申请
    SHAPED ARTICLE HAVING FINE SURFACE IRREGULARITIES AND METHOD FOR PRODUCING THE SHAPED ARTICLE 审中-公开
    具有精细表面不规则形状的制品和生产形状文章的方法

    公开(公告)号:US20130146138A1

    公开(公告)日:2013-06-13

    申请号:US13702793

    申请日:2011-05-31

    Abstract: Provided is a shaped article having surface irregularities, including a fine structure including projections and a recess formed between the projections, the fine structure formed by curing a curable resin composition, wherein the curable resin composition contains a composite resin (A) in which a polysiloxane segment (a1) having a structural unit represented by a general formula (1) and/or a general formula (2) and a silanol group and/or a hydrolyzable silyl group is bonded to a vinyl-based polymer segment (a2) having an alcoholic hydroxy group through a bond represented by a general formula (3), and polyisocyanate (B); a content of the polysiloxane segment (a1) with respect to total solids weight of the curable resin composition is 10% to 60% by weight; and a content of the polyisocyanate (B) with respect to total solids weight of the curable resin composition is 5% to 50% by weight.

    Abstract translation: 提供一种具有表面凹凸的成形制品,其包括具有突起的细微结构和形成在突起之间的凹部,通过固化固化性树脂组合物而形成的微细结构,其中,所述固化性树脂组合物含有复合树脂(A),其中,聚硅氧烷 具有由通式(1)和/或通式(2)表示的结构单元和/或硅烷醇基和/或可水解甲硅烷基的链段(a1)键合到具有 通过由通式(3)表示的键的醇羟基和多异氰酸酯(B); 相对于固化性树脂组合物的总固体重量,聚硅氧烷链段(a1)的含量为10〜60重量% 相对于固化性树脂组合物的总固体重量,多异氰酸酯(B)的含量为5〜50重量%。

    GRAFTED OPHTHALMIC DEVICES CONTAINING DEACTIVATED REGIONS AND PROCESSES FOR THEIR PREPARATION AND USE

    公开(公告)号:US20240325597A1

    公开(公告)日:2024-10-03

    申请号:US18426780

    申请日:2024-01-30

    Abstract: Disclosed are ophthalmic devices formed by a process comprising: (a) providing a reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the reactive composition to a first activation step such that the reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator; (c) deactivating at least a portion of the covalently bound activatable free radical initiator at one or more selective regions of the crosslinked substrate network such that the crosslinked substrate network contains retained covalently bound activatable free radical initiator outside of the one or more selective regions and optionally within the one or more selective regions; (d) contacting the crosslinked substrate network with a grafting composition containing one or more ethylenically unsaturated compounds, wherein the contacting is conducted under conditions such that the grafting composition penetrates into the crosslinked substrate network; and (e) activating the retained covalently bound activatable free radical initiator such that the grafting composition polymerizes with the crosslinked substrate network, thereby forming grafted polymeric networks, outside of the selective regions and optionally partially within the selective regions.

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