Powerfeed polymers having improved block resistance performance
    3.
    发明授权
    Powerfeed polymers having improved block resistance performance 有权
    具有改善阻块性能的加电聚合物

    公开(公告)号:US08907005B2

    公开(公告)日:2014-12-09

    申请号:US13889590

    申请日:2013-05-08

    摘要: The present invention provides emulsion copolymers and coating compositions containing the same having improved room temperature and hot block resistance in coatings wherein the copolymers have a broad measured glass transition temperature and are the copolymerization product of a vinyl monomer composition A and a softer vinyl monomer composition B having a Hansch parameter of at least 3.2, and containing one or more vinyl monomer M, such that each of which vinyl monomer(s) M would when homopolymerized provide a homopolymer having a measured Tg of 20° C. or less, such as, for example, 2-ethylhexyl acrylate. In addition, the present invention provides methods for making the emulsion copolymers by a powerfeed process comprising feeding vinyl monomer composition A into a reactor from a feed vessel while feeding, simultaneously or after a delay, vinyl monomer composition B into the feed vessel while polymerizing the monomers in the reactor.

    摘要翻译: 本发明提供了含有该涂料的乳液共聚物和涂料组合物,其具有改进的室温和涂料中的耐热阻性,其中共聚物具有宽的测量玻璃化转变温度,并且是乙烯基单体组合物A和较软的乙烯基单体组合物B的共聚产物 具有至少3.2的Hansch参数,并且含有一种或多种乙烯基单体M,使得当均聚时每种乙烯基单体M将提供具有20℃或更低的测量Tg的均聚物, 例如丙烯酸2-乙基己酯。 此外,本发明提供了通过加电方法制备乳液共聚物的方法,包括将乙烯基单体组合物A从进料容器进料到反应器中,同时或延迟将乙烯基单体组合物B进料到进料容器中,同时聚合 反应器中的单体。

    Aerosol dispensing systems and methods and compositions for repairing interior structure surfaces
    4.
    发明授权
    Aerosol dispensing systems and methods and compositions for repairing interior structure surfaces 有权
    用于修复内部结构表面的气溶胶分配系统和方法和组合物

    公开(公告)号:US08883902B2

    公开(公告)日:2014-11-11

    申请号:US13732274

    申请日:2012-12-31

    摘要: A method of covering an anomaly in a wall substantially to match a pre-existing texture pattern surrounding the anomaly comprises the following steps. A valve is supported on a container assembly to define a main chamber. Contained material comprising wall material concentrate and propellant material is disposed within a main chamber defined by a valve and a container assembly. An actuator relative is arranged relative to the container assembly such that displacement of a button changes the valve from a closed configuration to an open configuration. A first portion of the contained material is applied to the anomaly. A second portion of the contained material is applied to the base coat. The second portion of the contained material forms a desired texture pattern on the base coat that substantially matches the pre-existing texture pattern.

    摘要翻译: 覆盖墙体中的异常的方法基本上与在异常周围的预先存在的纹理图案相匹配包括以下步骤。 阀被支撑在容器组件上以限定主室。 包含壁材料浓缩物和推进剂材料的包含材料设置在由阀和容器组件限定的主室内。 致动器相对于容器组件布置成使得按钮的位移将阀从关闭构型改变为打开构型。 所含材料的第一部分被应用于异常。 将所包含的材料的第二部分施加到底涂层。 包含的材料的第二部分在基底涂层上形成基本上与预先存在的纹理图案相匹配的期望的纹理图案。

    Copolymer latex and method for producing the same
    5.
    发明授权
    Copolymer latex and method for producing the same 有权
    共聚物胶乳及其制备方法

    公开(公告)号:US08557934B2

    公开(公告)日:2013-10-15

    申请号:US13000064

    申请日:2009-07-02

    IPC分类号: C08F246/00 C08L101/14

    摘要: Disclosed is a copolymer latex obtained by emulsion polymerization of a monomer mixture containing (a) 30-70% by mass of a conjugated diene monomer, (b) 0.1-15% by mass of an ethylenically unsaturated carboxylic acid monomer and (c) 15-69.9% by mass of one or more other copolymerizable monomers. The copolymer latex is characterized in that the toluene in-soluble content in the dried product obtained by drying the copolymer latex is 95-100% by mass; the mass ratio of the toluene-swollen toluene insoluble content to the dried toluene insoluble content (the toluene swelling degree) is 3.0-6.5; the number average particle diameter of the copolymer latex is 180-400 nm; and the glass transition starting temperature of the dried copolymer latex is within the range from −70° C. to −20° C. and the glass transition ending temperature thereof is within the range from 10° C. to 100° C. in differential scanning calorimetry.

    摘要翻译: 公开了通过将(a)30〜70质量%的共轭二烯单体,(b)0.1〜15质量%的烯属不饱和羧酸单体和(c)15 -69.9质量%的一种或多种其它可共聚单体。 共聚物胶乳的特征在于,通过干燥该共聚物胶乳获得的干燥产物中的甲苯溶解度为95〜100质量% 甲苯溶胀甲苯不溶成分与干燥甲苯不溶成分质量比(甲苯溶胀度)为3.0-6.5; 共聚物胶乳的数均粒径为180-400nm; 干燥的共聚物胶乳的玻璃化转变起始温度在-70℃至-20℃的范围内,玻璃化转变终止温度在10℃至100℃的范围内 扫描量热法。

    COPOLYMER LATEX AND METHOD FOR PRODUCING THE SAME
    6.
    发明申请
    COPOLYMER LATEX AND METHOD FOR PRODUCING THE SAME 有权
    共聚物及其生产方法

    公开(公告)号:US20110092630A1

    公开(公告)日:2011-04-21

    申请号:US13000064

    申请日:2009-07-02

    IPC分类号: C09D109/10

    摘要: Disclosed is a copolymer latex obtained by emulsion polymerization of a monomer mixture containing (a) 30-70% by mass of a conjugated diene monomer, (b) 0.1-15% by mass of an ethylenically unsaturated carboxylic acid monomer and (c) 15-69.9% by mass of one or more other copolymerizable monomers. The copolymer latex is characterized in that the toluene in-soluble content in the dried product obtained by drying the copolymer latex is 95-100% by mass; the mass ratio of the toluene-swollen toluene insoluble content to the dried toluene insoluble content (the toluene swelling degree) is 3.0-6.5; the number average particle diameter of the copolymer latex is 180-400 nm; and the glass transition starting temperature of the dried copolymer latex is within the range from −70° C. to −20° C. and the glass transition ending temperature thereof is within the range from 10° C. to 100° C. in differential scanning calorimetry.

    摘要翻译: 公开了通过将(a)30〜70质量%的共轭二烯单体,(b)0.1〜15质量%的烯属不饱和羧酸单体和(c)15 -69.9质量%的一种或多种其它可共聚单体。 共聚物胶乳的特征在于,通过干燥该共聚物胶乳获得的干燥产物中的甲苯溶解度为95〜100质量% 甲苯溶胀甲苯不溶成分与干燥甲苯不溶成分质量比(甲苯溶胀度)为3.0-6.5; 共聚物胶乳的数均粒径为180-400nm; 干燥的共聚物胶乳的玻璃化转变起始温度在-70℃至-20℃的范围内,玻璃化转变终止温度在10℃至100℃的范围内 扫描量热法。

    Paper coating composition
    7.
    发明授权
    Paper coating composition 失效
    纸涂料组合物

    公开(公告)号:US5700852A

    公开(公告)日:1997-12-23

    申请号:US414592

    申请日:1995-03-31

    CPC分类号: D21H19/58 C09D113/02

    摘要: A paper coating composition which comprises as a binder a latex of a copolymer (referred to hereinafter the particle A) consisting of (a) 20 to 80% by weight of an aliphatic conjugated diene monomer unit, (b) 0.5 to 10% by weight of an ethylenically unsaturated carboxylic acid monomer unit and (c) 20 to 79.5% by weight of a unit of another monomer copolymerizable with the above components (a) and (b) and having two glass transition points in the range of from -100.degree. C. to 50.degree. C. the difference between the two transition points being at least 5.degree. C.

    摘要翻译: 一种纸涂料组合物,其包含由(a)20至80重量%的脂族共轭二烯单体单元组成的共聚物(以下称为颗粒A)的胶乳,(b)0.5至10重量% 的烯键式不饱和羧酸单体单元和(c)20-79.5重量%的可与上述组分(a)和(b)共聚的另一单体的单元,并且具有-100℃的两个玻璃化转变点 C.至50℃,两个转变点之间的差异至少为5℃。

    Method of weatherproof caulking for the outer surfaces of iron and steel
    10.
    发明授权
    Method of weatherproof caulking for the outer surfaces of iron and steel 失效
    钢铁外墙防水铆接方法

    公开(公告)号:US4025672A

    公开(公告)日:1977-05-24

    申请号:US599486

    申请日:1975-07-28

    IPC分类号: B05D7/14 C09D113/02 B05D3/02

    CPC分类号: C09D113/02 B05D7/14

    摘要: Method of weatherproof caulking the outer surfaces of iron and steel with a synthetic rubber dispersion of copolymers of styrene, butadiene and an unsaturated carboxylic acid and made thixotropic by the addition of organic and/or inorganic thickeners, and inorganic and/or organic fibrous substances.

    摘要翻译: 防风雨方法采用苯乙烯,丁二烯和不饱和羧酸共聚物的合成橡胶分散体,通过加入有机和/或无机增稠剂以及无机和/或有机纤维状物质,使钢铁外表面铆接而形成触变性。