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    Catalyst for CO shift reaction
    2.
    发明申请
    Catalyst for CO shift reaction 失效
    CO转化反应催化剂

    公开(公告)号：US20020151435A1

    公开(公告)日：2002-10-17

    申请号：US10061288

    申请日：2002-02-04

    申请人： KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO

    发明人： Kiyoshi Yamazaki ,  Akihiko Suda

    IPC分类号： B01J027/02 ,  B01J027/043 ,  B01J027/045

    CPC分类号： B01J27/045 ,  B01J21/063 ,  B01J27/02 ,  C01B3/16 ,  C01B2203/0283 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  Y02P20/52

    摘要： A practical catalyst exhibiting especially high CO shift reaction activity in a low temperature region where CO is favorably converted to H2 in equilibrium includes a carrier which is composed of titania as a main component, a noble metal which is supported on the carrier, and a sulfur-containing material which adheres to the carrier. The titania carrier to which the sulfur-containing material adheres exhibits high solid acid strength, and accordingly acts to absorb electrons from noble metal so that noble metal becomes partially oxidized. This results in the CO adsorbing ability decreasing to restrain poisoning of noble metal due to CO, whereby the CO shift reaction activity in a low temperature region is improved.

    摘要翻译： 在CO有利地平衡地转化为H 2的低温区域中表现出特别高的CO转化反应活性的实用催化剂包括以二氧化钛为主要成分的载体，负载在载体上的贵金属和硫 含有材料，其粘附于载体。 含硫材料附着在其上的二氧化钛载体表现出高的固体酸强度，因此用于从贵金属吸收电子，使得贵金属部分氧化。 这导致CO吸附能力降低，从而抑制由CO引起的贵金属的中毒，从而提高了低温区域的CO转化反应活性。

    Process for sulfiding a catalyst containing an S-containing additive
    3.
    发明申请
    Process for sulfiding a catalyst containing an S-containing additive 有权
    硫化含有S添加剂的催化剂的方法

    公开(公告)号：US20020000394A1

    公开(公告)日：2002-01-03

    申请号：US09829624

    申请日：2001-04-10

    发明人： Sonja Eijsbouts

    IPC分类号： C10G045/00 ,  B01J027/045 ,  B01J027/043 ,  B01J027/04

    CPC分类号： B01J31/04 ,  B01J23/85 ,  B01J31/0217 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    摘要： The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an S-containing organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase. The invention also pertains to the sulfided catalyst composition and its use in hydrotreating. Catalysts sulfided by the process according to the invention show a higher activity than the same catalysts which have not been sulfided. It is preferred to carry out the process according to the invention ex situ, where it solves the problem of difficult start-up and the formation of undesirable side products in the hydrotreating unit. The organic liquid may be a hydrocarbon with a boiling range of about 150-500null C., preferably white oil, gasoline, diesel, gas oil, or mineral lube oil. The S-containing organic additive preferably is a mercapto-compound, more preferably a mercaptocarboxylic acid represented by the general formula HSnullR1nullCOOR, wherein R1 stands for a divalent hydrocarbon group with 1- about 10 carbon atoms and R stands for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched alkyl group having 1 to about 10 carbon atoms.

    摘要翻译： 本发明涉及一种用于硫化催化剂组合物的方法，所述催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族的氢化金属组分和含S的有机添加剂，其中催化剂组合物首先与有机液体 然后催化剂与气相中的氢和含硫化合物接触。 本发明还涉及硫化催化剂组合物及其在加氢处理中的用途。 通过根据本发明的方法硫化的催化剂显示出比未硫化的相同催化剂更高的活性。 优选非原位地进行根据本发明的方法，其中解决了加氢处理单元中难以启动和形成不期望的副产物的问题。 有机液体可以是沸程为约150-500℃的烃，优选白油，汽油，柴油，瓦斯油或矿物润滑油。 含S的有机添加剂优选为巯基化合物，更优选由通式HS-R1-COOR表示的巯基羧酸，其中R1表示具有1〜10个碳原子的二价烃基，R表示氢 原子，碱金属，碱土金属，铵或具有1至约10个碳原子的直链或支链烷基。

    Process for ex situ sulfiding catalyst containing an S-containing additive
    7.
    发明申请
    Process for ex situ sulfiding catalyst containing an S-containing additive 审中-公开
    含有S的添加剂的原位硫化催化剂的方法

    公开(公告)号：US20020000395A1

    公开(公告)日：2002-01-03

    申请号：US09829640

    申请日：2001-04-10

    发明人： Sonja Eijsbouts

    IPC分类号： C10G045/00 ,  B01J027/045 ,  B01J027/043 ,  B01J021/04

    CPC分类号： B01J31/04 ,  B01J23/85 ,  B01J23/88 ,  B01J27/188 ,  B01J31/0217 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    摘要： The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an S-containing organic additive wherein the catalyst composition is contacted with hydrogen and a sulfur-containing compound in the gaseous phase, characterized in that the process is carried out ex situ. By carrying out the process ex situ, the formation of undesirable side compounds in the hydrotreating unit is prevented. Additionally, the reactor suffers less downtime, and the start-up of the reactor may be simplified. The S-containing organic additive preferably is a mercapto-compound, more preferably a mercaptocarboxylic acid represented by the general formula HSnullR1-COOR, wherein R1 stands for a divalent hydrocarbon group with 1-about 10 carbon atoms and R stands for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched alkyl group having 1 to about 10 carbon atoms. The invention also pertains to the catalyst made by the above process and a process for hydrotreating a hydrocarbon feed by contacting the feed with the catalyst at hydrotreating conditions.

    摘要翻译： 本发明涉及一种硫化催化剂组合物的方法，所述催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族的氢化金属组分和含S的有机添加剂，其中催化剂组合物与氢和硫接触 在气相中的化合物，其特征在于该方法在原位进行。 通过非原位地进行该方法，可以防止在加氢处理装置中形成不合需要的副化合物。 此外，反应器的停机时间较短，反应器的启动可以简化。 含S的有机添加剂优选为巯基化合物，更优选由通式HS-R1-COOR表示的巯基羧酸，其中R1表示具有1〜约10个碳原子的二价烃基，R表示氢 原子，碱金属，碱土金属，铵或具有1至约10个碳原子的直链或支链烷基。 本发明还涉及通过上述方法制备的催化剂和通过在加氢处理条件下使进料与催化剂接触来加氢烃化进料的方法。