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    Two-step process for sulfiding a catalyst containing an S-containing additive
    2.
    发明申请
    Two-step process for sulfiding a catalyst containing an S-containing additive 有权
    用于硫化含有S的添加剂的催化剂的两步法

    公开(公告)号：US20010046939A1

    公开(公告)日：2001-11-29

    申请号：US09829626

    申请日：2001-04-10

    Inventor： Sonja Eijsbouts

    IPC: B01J031/00 ,  C10G045/00 ,  C10G025/00 ,  C10G045/04 ,  C10G045/60 ,  B01J027/02 ,  B01J027/053 ,  B01J027/047 ,  B01J027/051 ,  B01J027/049 ,  B01J027/043

    CPC classification number: B01J31/04 ,  B01J23/85 ,  B01J23/88 ,  B01J27/188 ,  B01J31/0217 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    Abstract: The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an S-containing organic additive wherein the catalyst composition is contacted in two steps with hydrogen and a sulfur-containing compound in the gaseous phase, with the first step being performed at a temperature which is lower than that of the second step. Catalysts sulfided by the process according to the invention show a higher activity than the same catalysts which have been sulfided in a one-step process. It is preferred to carry out the process according to the invention ex situ, where it solves the problem of difficult start-up and the formation of undesirable side products in the hydrotreating unit. The S-containing organic additive preferably is a mercapto-compound, more preferably a mercaptocarboxylic acid represented by the general formula HSnullR1-COOR, wherein R1 stands for a divalent hydrocarbon group with 1null about 10 carbon atoms and R stands for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched alkyl group having 1 to about 10 carbon atoms. The invention also pertains to the catalyst made by the above process and a process for hydrotreating a hydrocarbon feed by contacting the feed with the catalyst at hydrotreating conditions.

    Abstract translation: 本发明涉及一种硫化催化剂组合物的方法，所述催化剂组合物包含至少一种元素周期表第Ⅵ族和/或Ⅷ族的氢化金属组分和含S的有机添加剂，其中催化剂组合物分两步接触氢气 和在气相中的含硫化合物，其中第一步在低于第二步的温度下进行。 通过本发明方法硫化的催化剂表现出比在一步法中硫化的相同催化剂更高的活性。 优选非原位地进行根据本发明的方法，其中解决了加氢处理单元中难以启动和形成不期望的副产物的问题。 含S的有机添加剂优选为巯基化合物，更优选由通式HS-R1-COOR表示的巯基羧酸，其中R1表示具有1〜10个碳原子的二价烃基，R表示氢 原子，碱金属，碱土金属，铵或具有1至约10个碳原子的直链或支链烷基。 本发明还涉及通过上述方法制备的催化剂和通过在加氢处理条件下使进料与催化剂接触来加氢烃化进料的方法。

    Catalyst for purification of diesel engine exhaust gas
    4.
    发明申请
    Catalyst for purification of diesel engine exhaust gas 失效
    用于净化柴油机废气的催化剂

    公开(公告)号：US20030104932A1

    公开(公告)日：2003-06-05

    申请号：US09958069

    申请日：2002-07-16

    Inventor： Young-Nam Kim

    IPC: B01J027/02

    CPC classification number: B01D53/945 ,  B01D2255/1021 ,  B01D2255/40 ,  B01D2257/404 ,  B01D2257/50 ,  B01D2257/702 ,  B01J23/6527 ,  B01J27/053 ,  B01J37/036 ,  Y02T10/22

    Abstract: This invention provides a new catalyst for purification of diesel engine exhaust gas comprising a carrier of at least one sulfur-resistant refractory oxide and at least one catalytic metal, wherein at least one solid acid and/or sulfuric acid is carried on the carrier by adding at least one precursor of said solid acid and/or sulfuric acid during the preparation of the carrier, and preparation thereof. The catalyst of this invention is thermally and chemically durable and can effectively remove particulate matters, hydrocarbons and nitrogen oxides contained in the diesel engine exhaust gas at low temperatures.

    Abstract translation: 本发明提供一种用于净化柴油发动机废气的新型催化剂，其包括至少一种耐硫耐火氧化物和至少一种催化金属的载体，其中至少一种固体酸和/或硫酸通过加入 在制备载体期间所述固体酸和/或硫酸的至少一种前体及其制备。 本发明的催化剂具有耐热和耐化学性能，能够有效地去除低温下柴油发动机废气中所含的颗粒物质，烃类和氮氧化物。

    Method for sulphurizing hydrotreating catalysts
    6.
    发明申请
    Method for sulphurizing hydrotreating catalysts 审中-公开
    加氢处理催化剂硫化方法

    公开(公告)号：US20040112795A1

    公开(公告)日：2004-06-17

    申请号：US10468936

    申请日：2004-01-13

    Inventor： Claude Brun ,  Georges Fremy

    IPC: C10G045/02 ,  B01J027/02 ,  B01J027/047 ,  B01J027/051 ,  B01J027/049

    CPC classification number: B01J37/20 ,  B01J23/882 ,  B01J27/0515 ,  C10G45/08

    Abstract: The invention concerns a method for sulphurizing catalysts for hydrotreating of hydrocarbon feedstocks. The invention is characterised in that it consists in sulphurizing the catalyst in two steps: the first step consisting in sulphurization with tertiary mercaptan in the absence of hydrogen, and the second step, carried out consecutively in the same reactor, consisting of sulphurization with another sulphurizing agent in the presence of hydrogen. The catalysts thus sulphurized prove to be more active than those sulphurized by only the second step.

    Abstract translation: 本发明涉及用于硫化用于烃原料加氢处理的催化剂的方法。 本发明的特征在于其包括在两个步骤中对催化剂进行硫化：第一步是在不存在氢的情况下与三硫醇进行硫化，第二步在相同的反应器中连续进行，其中包括硫化与另一种硫化 在氢的存在下。 因此如此硫化的催化剂比仅通过第二步骤硫化的催化剂更有活性。

    Solid acid catalyst containing plantinum group metal component and method for preparation thereof
    7.
    发明申请
    Solid acid catalyst containing plantinum group metal component and method for preparation thereof 失效
    含有植物金属组分的固体酸催化剂及其制备方法

    公开(公告)号：US20040067845A1

    公开(公告)日：2004-04-08

    申请号：US10468925

    申请日：2003-08-21

    Inventor： Satoshi Furuta ,  Minoru Ogawa

    IPC: B01J023/42 ,  B01J027/053 ,  B01J027/02

    CPC classification number: B01J27/053 ,  B01J23/42 ,  B01J29/068 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061

    Abstract: The present invention provides a concentration distribution for a platinum group metal component in a catalyst with which catalyst activity can be increased, and to provide a method for supporting a platinum group metal with which this concentration distribution can be achieved. The present invention is a solid acid catalyst that comprises porous catalyst pellets exhibiting solid acid characteristics, and a platinum group metal component supported by these catalyst pellets, and that is used in an acid-catalyzed reaction, in which a quotient of dividing the standard deviation of concentration in a platinum group metal component concentration distribution in the catalyst by an average concentration is 0.4 or less. The method for preparing. this catalyst comprises a step of preparing a support solution containing a platinum group metal as a cation, and a step of impregnating crystalline, porous catalyst pellets exhibiting solid acid characteristics with this support solution. The present invention also provides a method for isomerizing a hydrocarbon, wherein a solid acid catalyst is brought into contact with a hydrocarbon including at least 70 wt % of a saturated hydrocarbon component having 4 to 10 carbon atoms.

    Abstract translation: 本发明提供催化剂中的铂族金属成分的浓度分布，能够提高催化剂活性，并提供一种能够实现该浓度分布的铂族金属的担载方法。 本发明是一种固体酸催化剂，其包含显示固体酸性特征的多孔催化剂颗粒和由这些催化剂颗粒负载的铂族金属组分，并用于酸催化反应中，其中将标准偏差 浓度在铂族金属成分浓度分布在催化剂中的平均浓度为0.4以下。 准备方法。 该催化剂包括制备包含铂族金属作为阳离子的载体溶液的步骤，以及用该载体溶液浸渍显示出固体酸特性的结晶多孔催化剂颗粒的步骤。 本发明还提供一种烃的异构化方法，其中固体酸催化剂与包含至少70重量％的具有4-10个碳原子的饱和烃组分的烃接触。

    Oxysulfide photocatalyst for decomposition of water by visible light
    8.
    发明申请
    Oxysulfide photocatalyst for decomposition of water by visible light 失效
    用于通过可见光分解水的氧硫化物光催化剂

    公开(公告)号：US20040029726A1

    公开(公告)日：2004-02-12

    申请号：US10433460

    申请日：2003-06-03

    Inventor： Kazunari Domen ,  Michikazu Hara ,  Tsuyoshi Takata ,  Akio Ishikawa

    IPC: B01J027/02

    CPC classification number: B01J35/004 ,  B01J23/63 ,  B01J27/04 ,  B01J27/045 ,  B01J35/002 ,  B01J37/0201 ,  B01J37/04 ,  C01B3/042 ,  C01B13/0207 ,  Y02E60/364

    Abstract: A photocatalyst which comprises an oxysulfide containing at least one transition metal; a preferable photocatalyst which also comprises a rare earth element such as Sm in addition to the above and wherein the transition metal is at least one selected from the group consisting of Ti and Nb; a more preferable photocatalyst which further comprises a promoter comprising a transition metal such as Pt loaded on each of the above photocatalyst; and a catalyst for use in the decomposition of water by a light which comprises one of the above oxysulfide photocatalysts.

    Abstract translation: 包含含有至少一种过渡金属的氧硫化物的光催化剂; 除了上述之外还包含稀土元素如Sm的优选光催化剂，其中过渡金属是选自Ti和Nb中的至少一种; 更优选的光催化剂还包含一种助催化剂，该助催化剂包含负载在上述每种光催化剂上的过渡金属如Pt; 以及用于通过包含上述氧硫化物光催化剂之一的光分解水的催化剂。

    Catalyst for CO shift reaction
    9.
    发明申请
    Catalyst for CO shift reaction 失效
    CO转化反应催化剂

    公开(公告)号：US20020151435A1

    公开(公告)日：2002-10-17

    申请号：US10061288

    申请日：2002-02-04

    Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO

    Inventor： Kiyoshi Yamazaki ,  Akihiko Suda

    IPC: B01J027/02 ,  B01J027/043 ,  B01J027/045

    CPC classification number: B01J27/045 ,  B01J21/063 ,  B01J27/02 ,  C01B3/16 ,  C01B2203/0283 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  Y02P20/52

    Abstract: A practical catalyst exhibiting especially high CO shift reaction activity in a low temperature region where CO is favorably converted to H2 in equilibrium includes a carrier which is composed of titania as a main component, a noble metal which is supported on the carrier, and a sulfur-containing material which adheres to the carrier. The titania carrier to which the sulfur-containing material adheres exhibits high solid acid strength, and accordingly acts to absorb electrons from noble metal so that noble metal becomes partially oxidized. This results in the CO adsorbing ability decreasing to restrain poisoning of noble metal due to CO, whereby the CO shift reaction activity in a low temperature region is improved.

    Abstract translation: 在CO有利地平衡地转化为H 2的低温区域中表现出特别高的CO转化反应活性的实用催化剂包括以二氧化钛为主要成分的载体，负载在载体上的贵金属和硫 含有材料，其粘附于载体。 含硫材料附着在其上的二氧化钛载体表现出高的固体酸强度，因此用于从贵金属吸收电子，使得贵金属部分氧化。 这导致CO吸附能力降低，从而抑制由CO引起的贵金属的中毒，从而提高了低温区域的CO转化反应活性。

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