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公开(公告)号：US10994268B2
公开(公告)日：2021-05-04
申请号：US15947986
申请日：2018-04-09
发明人： Larry L. Iaccino , Xiaoying Bao , Jeremy W. Bedard
IPC分类号： B01J29/90 , B01J29/44 , B01J29/40 , C07C5/41 , C07C5/32 , C07C5/333 , B01J38/02 , C07C5/373 , B01J38/18 , B01J38/14
摘要： Disclosed are processes for rejuvenating catalysts comprising at least one Group 10 metal and a microporous crystalline metallosilicate, and hydrocarbon conversion processes including such rejuvenation processes. In an aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250° C. to about 375° C. and a pressure of up to about 100 bar. In a further aspect, the rejuvenation process comprises contacting a deactivated catalyst comprising at least one Group 10 metal, at least one rare earth metal, and a microporous crystalline metallosilicate with an oxygen-containing gaseous stream under conditions comprising a temperature ranging from about 250° C. to about 500° C. and a pressure of up to about 100 bar.
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公开(公告)号：US10662126B2
公开(公告)日：2020-05-26
申请号：US16246462
申请日：2019-01-12
申请人： Exelus Inc.
IPC分类号： C07C1/20 , C07C4/06 , C07C2/86 , C07C2/58 , B01J29/89 , B01J23/80 , B01J29/70 , B01J29/40 , B01J21/04 , B01J21/08 , B01J29/18 , B01J29/08 , B01J35/10 , B01J8/04 , C07C5/373 , C10G29/20 , C10G3/00 , B01J21/12 , B01J35/02
摘要： Methods of simultaneously converting butanes and methanol to olefins over Ti-containing zeolite catalysts are described. The exothermicity of the alcohols to olefins reaction is matched by endothermicity of dehydrogenation reaction of butane(s) to light olefins resulting in a thermo-neutral process. The Ti-containing zeolites provide excellent selectivity to light olefins as well as exceptionally high hydrothermal stability. The coupled reaction may advantageously be conducted in a staged reactor with methanol/DME conversion zones alternating with zones for butane(s) dehydrogenation. The resulting light olefins can then be reacted with iso-butane to produce high-octane alkylate. The net result is a highly efficient and low cost method for converting methanol and butanes to alkylate.
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公开(公告)号：US10364200B2
公开(公告)日：2019-07-30
申请号：US15892832
申请日：2018-02-09
摘要： This invention relates to processes and systems for converting acyclic hydrocarbons to alkenes, cyclic hydrocarbons and/or aromatics, for example converting acyclic C5 hydrocarbons to cyclopentadiene in a reactor system. The process includes contacting a feedstock comprising acyclic hydrocarbons with a catalyst material in at least one reaction zone to convert at least a portion of the acyclic hydrocarbons to a first effluent comprising alkenes, cyclic hydrocarbons and/or aromatics. A co-feed comprising H2, C1-C4 alkanes and/or C1-C4 alkenes may also be provided to the at least one reaction zone.
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公开(公告)号：US10179753B2
公开(公告)日：2019-01-15
申请号：US15331727
申请日：2016-10-21
申请人： Exelus Inc.
IPC分类号： C07C1/20 , C07C1/24 , C07C5/333 , C07C2/58 , C07C2/86 , B01J29/89 , B01J23/80 , B01J29/70 , B01J29/40 , B01J21/04 , B01J21/08 , B01J29/18 , B01J29/08 , B01J35/10 , B01J8/04 , C07C5/373 , C10G29/20 , C10G3/00
摘要： Methods of simultaneously converting butanes and methanol to olefins over Ti-containing zeolite catalysts are described. The exothermicity of the alcohols to olefins reaction is matched by endothermicity of dehydrogenation reaction of butane(s) to light olefins resulting in a thermo-neutral process. The Ti-containing zeolites provide excellent selectivity to light olefins as well as exceptionally high hydrothermal stability. The coupled reaction may advantageously be conducted in a staged reactor with methanol/DME conversion zones alternating with zones for butane(s) dehydrogenation. The resulting light olefins can then be reacted with iso-butane to produce high-octane alkylate. The net result is a highly efficient and low cost method for converting methanol and butanes to alkylate.
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公开(公告)号：US09988324B2
公开(公告)日：2018-06-05
申请号：US15288343
申请日：2016-10-07
IPC分类号： C07C5/32 , C07C5/333 , C07C5/373 , B01J8/02 , B01J29/44 , C07C2/76 , C07C5/03 , C07C7/04 , C07C4/22 , C07C2/40 , C07C2/52 , C01B3/26
CPC分类号： C07C5/373 , B01J8/02 , B01J8/0278 , B01J29/40 , B01J29/44 , B01J29/7038 , B01J2208/02 , B01J2229/186 , B01J2229/40 , C01B3/26 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C07C2/403 , C07C2/52 , C07C2/76 , C07C4/22 , C07C5/03 , C07C5/333 , C07C7/04 , C07C2101/10 , C07C2103/68 , C07C2529/44 , C07C2601/10 , C07C2603/68 , Y02P20/582 , C07C13/15 , C07C13/61
摘要： Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor to obtain a product mixture, separating the product mixture in a separation sub-system such as compression train to obtain a C5-rich fraction comprising CPD and essentially depleted of hydrogen and C1-C4 hydrocarbons, dimerizing the C5-rich fraction in a dimerization reactor to obtain a product effluent comprising DCPD, followed by separating the product effluent to obtain a DCPD-rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.
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公开(公告)号：US09926242B2
公开(公告)日：2018-03-27
申请号：US15288403
申请日：2016-10-07
CPC分类号： C07C5/373 , B01J8/02 , B01J8/062 , B01J29/44 , B01J29/63 , B01J29/90 , B01J2208/06 , C07C2101/10 , C07C2529/44 , C07C2601/10 , Y02P20/125 , Y02P20/584 , C07C13/15
摘要： Disclosed is an integrated process and system to generate power and convert acyclic C5 feedstock to non-aromatic, cyclic C5 hydrocarbon. A combustion device, such as a turbine, and reactor tubes containing catalyst compound are disclosed. A process involving contacting acyclic C5 feedstock with catalyst composition and obtaining cyclic C5 hydrocarbon is also disclosed.
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公开(公告)号：US20170121255A1
公开(公告)日：2017-05-04
申请号：US15288459
申请日：2016-10-07
发明人： Larry L. Iaccino
CPC分类号： C07C5/373 , B01J29/44 , B01J29/63 , B01J29/90 , C07C2101/10 , C07C2529/44 , C07C2601/10 , Y02P20/584 , Y02P20/588 , C07C13/15
摘要： This invention relates to a process for converting acyclic C5 hydrocarbons to cyclopentadiene including: providing to the at least one adiabatic reaction zone a feedstock comprising acyclic C5 hydrocarbons at a temperature, T1, wherein the at least one adiabatic reaction zone comprises a first particulate material comprising catalyst material; contacting the feedstock and the first particulate material in the at least one adiabatic reaction zone under reaction conditions to convert at least a portion of the acyclic C5 hydrocarbons to a first effluent comprising cyclopentadiene intermediates, unconverted acyclic C5 hydrocarbons, and, optionally, cyclopentadiene; heating the first effluent to a temperature, T2; providing the first effluent to the at least one diabatic reaction zone; and contacting the first effluent and a second particulate material comprising catalyst material in the at least one diabatic reaction zone under reaction conditions to convert at least a portion of the cyclopentadiene intermediates and the unconverted acyclic C5 hydrocarbons to a second effluent comprising cyclopentadiene.
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公开(公告)号：US20170121254A1
公开(公告)日：2017-05-04
申请号：US15288452
申请日：2016-10-07
CPC分类号： C07C5/373 , B01J29/44 , B01J29/46 , B01J29/62 , C07C5/42 , C07C2101/10 , C07C2529/44 , C07C2529/46 , C07C2529/62 , C07C2601/06 , C07C2601/10 , C07C13/10 , C07C13/12 , C07C13/15
摘要： Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline ferrosilicate, a Group 10 metal, and, optionally, a Group 11 metal, in combination with an optional Group 1 alkali metal and/or an optional Group 2 alkaline earth metal.
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9.发明申请公开(公告)号：US20170121245A1
公开(公告)日：2017-05-04
申请号：US15288364
申请日：2016-10-07
发明人： Larry L. Iaccino , Jeremy W. Bedard , Karl G. Strohmaier , Machteld M.W. Mertens , Robert T. Carr , Jane C. Cheng
CPC分类号： C07C5/373 , B01J29/44 , B01J29/46 , B01J29/62 , C07C5/42 , C07C2529/44 , C07C2529/46 , C07C2529/62 , C07C2601/06 , C07C2601/10 , C07C13/10 , C07C13/12 , C07C13/15
摘要： Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a crystalline aluminosilicate having a constraint index of less than or equal to 5, and a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.
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公开(公告)号：US09040762B2
公开(公告)日：2015-05-26
申请号：US14517524
申请日：2014-10-17
发明人： Joel M. Cizeron , Erik C. Scher , Fabio R. Zurcher , Wayne P. Schammel , Greg Nyce , Anja Rumplecker , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
IPC分类号： C07C1/00 , C07C2/00 , C07C4/00 , C07C5/00 , C07C6/00 , C07C5/327 , C07C5/373 , B01J23/00 , B01J23/10 , C07C2/84
CPC分类号： C07C2/84 , B01J19/0046 , B01J21/066 , B01J21/08 , B01J23/002 , B01J23/10 , B01J23/34 , B01J23/54 , B01J23/63 , B01J23/76 , B01J23/83 , B01J23/8892 , B01J27/16 , B01J35/0006 , B01J37/031 , B01J37/035 , B01J2219/00527 , B01J2219/00536 , B01J2219/00702 , B01J2219/00747 , B01J2523/00 , C07C2521/10 , C07C2521/14 , C07C2523/10 , C07C2523/18 , C07C2523/34 , C07C2529/072 , C07C2529/076 , C07C2529/89 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/3725 , B01J2523/3712 , B01J2523/54 , B01J2523/23 , B01J2523/11 , B01J2523/22 , B01J2523/305 , B01J2523/72 , B01J2523/845 , B01J2523/12 , B01J2523/69 , C07C11/04
摘要： Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.
摘要翻译： 提供了包含各种掺杂剂的金属氧化物催化剂。 催化剂可用作各种催化反应中的异质催化剂，例如甲烷与C 2烃如乙烷和乙烯的氧化偶联。 还公开了相关的使用和制造方法。
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