Method for preparing biogenic guanidine complex, method for preparing polyethylene terephthalate (PET), and method for preparing poly (ethylene isophthalate-co-terephthalate) (PEIT)

    公开(公告)号:US11525030B2

    公开(公告)日:2022-12-13

    申请号:US17033787

    申请日:2020-09-26

    发明人: Hong Li Dubin Wang

    摘要: A method for preparing a biogenic guanidine complex, the method including: mixing dimethyl sulfoxide (DMSO) with water in a volume ratio thereof of 1:1 to yield a solvent DMSO-H2O; adding organic guanidine (G) and a compound MX2 in a molar ratio G/MX2=1:1 or 2:1 to the solvent DMSO-H2O, where the organic guanidine (G) is selected from arginine (Arg), guanidinoacetic acid (Gaa), creatine (Cra), creatinine (Cran), guanine (Gua), and agmatine (Agm); M represents Fe2+, Mg2+, or Zn2+; and X represents Cl−, CH3COO−, or CH3CH(OH)COO−; stirring the solvent DMSO-H2O containing the organic guanidine and the compound MX2; recycling the solvent DMSO-H2O through vacuum distillation and obtaining a solid; transferring the solid to a Buchner funnel, and washing the solid with deionized water and ethanol consecutively; and removing the deionized water and ethanol through vacuum filtration, and drying the solid. Biogenic guanidine complex can be used for production of Polyethylene terephthalate or Poly(ethylene isophthalate-co-terephthalate).

    PROCESS OF MANUFACTURING BIODEGRADABLE PET CHIPS

    公开(公告)号:US20220153926A1

    公开(公告)日:2022-05-19

    申请号:US17441015

    申请日:2020-03-13

    申请人: Ashok CHATURVEDI

    发明人: Ashok CHATURVEDI

    摘要: The present invention describes a process of manufacturing biodegradable PET chips, comprising the steps of providing a purified terephthalic acid (PTA) in a predetermined quantity in a slurry tank; providing virgin monoethylene glycol (MEG) in a predetermined quantity in the slurry tank; transferring the combination of the slurry tank to an esterification reactor for esterification of the combination in the reactor at above 250° C. temperature which releases monomers; transferring the monomers from the esterification reactor to a polymerisation reactor; providing poly-catalysts such as, but not limited, to Ti-based catalyst, sb2O3 or any other suitable catalysts or combination thereof into the polymerisation reactor; and polymerization of the monomers in the polymerisation reactor at above 280° C. temperature, wherein an enzyme based composition is provided either at PTA/MEG stage or poly-catalyst stage or at other stages or combination thereof.