公开(公告)号：US20240301306A1

公开(公告)日：2024-09-12

申请号：US18598320

申请日：2024-03-07

申请人： Barry Liss

发明人： Barry Liss

IPC分类号： C10J3/54 ,  C10B1/10 ,  C10B53/02 ,  C10L1/04 ,  C25B1/04 ,  C25B15/08

CPC分类号： C10J3/54 ,  C10B1/10 ,  C10B53/02 ,  C10L1/04 ,  C25B1/04 ,  C25B15/081 ,  C10J2200/158 ,  C10J2300/0946

摘要： A system and method of thermally processing carbonaceous materials, and especially sustainably cultivated woody biomass or cellulosic biomass sorted from municipal solid waste, to produce green fuel, such as diesel, sustainable aviation fuel and other beneficial by-products, including biochar. Synthesis gas is made by gasifying sustainably grown biomass, the thermal energy from which is used to create steam for treatment of biochar by-product to produce higher value activated carbon. Oxygen for the gasifier and hydrogen for a Fischer Tropsch (FT) or other catalytic synthesis stage of the process are generated by electrolysis of water using sustainably produced electricity. The gasification and electrolysis processes are operated to produce a 2:1 ratio of hydrogen to carbon monoxide needed for FT or other catalytic synthesis. The hydrocarbon product is distilled as required to produce either green alcohols or green diesel fuel and sustainable aviation fuel.

公开(公告)号：US20220106528A1

公开(公告)日：2022-04-07

申请号：US17538854

申请日：2021-11-30

申请人： The Texas A&M University System

发明人： Sergio C. Capareda ,  Calvin B. Parnell, JR. ,  David B. Carney

IPC分类号： C10B53/00 ,  C10J3/48 ,  C10K1/02 ,  B04C5/26 ,  F23C10/20 ,  F23C10/10 ,  C10J3/84 ,  C10J3/50 ,  F23G5/027 ,  B01J8/44 ,  F23G5/30 ,  F23G7/10 ,  C10B53/02 ,  C10B49/22 ,  C10J3/46 ,  C10J3/54 ,  F16L41/02 ,  G01F1/76

摘要： A pyrolysis and gasification system produce a synthesis gas and bio-char from a biomass feedstock. The system includes a feed hopper that has a flow measurement device. The system also includes a reactor that is operable in a gasification mode or a pyrolysis mode. The reactor is configured to receive the biomass feedstock from the feed hopper. The reactor is operable to provide heat to the biomass feedstock from the feed hopper to produce the synthesis gas and bio-char. The system also includes a cyclone assembly. The produced synthesis gas including the bio-char is fed to the cyclone assembly. The cyclone assembly removes a portion of the bio-char from the synthesis gas.

公开(公告)号：US11230677B2

公开(公告)日：2022-01-25

申请号：US17028957

申请日：2020-09-22

申请人： CHINA UNIVERSITY OF PETROLEUM-BEIJING

发明人： Jinsen Gao ,  Yuming Zhang ,  Xingying Lan ,  Chengxiu Wang ,  Xiaogang Shi

IPC分类号： C10J3/56 ,  C10G1/00 ,  C10G1/04 ,  C10J3/54 ,  C10B55/00 ,  B01D3/14 ,  C10J3/84

摘要： A method for heavy oil lightening and synthesis gas production and a device thereof are provided, where the method uses a cracking/gasification coupled reactor, which internally has a cracking section and a gasification section that communicate with each other, and includes the following steps: feeding a heavy oil material into the cracking section to implement a cracking reaction, to produce a light oil gas and a coke; the coke being carried by the coke powders and descending into the gasification section to implement a gasification reaction, to produce a synthesis gas; at least performing a first stage gas-solid separation, collecting coke powder particles and dividing them into two parts; performing an oil and gas fractionation on a purified oil and gas product output by the gas-solid separation system, and collecting a light oil product and a synthesis gas product.

公开(公告)号：US10787620B2

公开(公告)日：2020-09-29

申请号：US16293314

申请日：2019-03-05

申请人： China University of Petroleum (East China)

发明人： Yingyun Qiao ,  Yuanyu Tian ,  Youqing Wu ,  Huawei Zhang ,  Peijie Zong ,  Jie Li ,  Xue Ming ,  Yuan Jiang

IPC分类号： C10J3/54 ,  C10J3/56 ,  C10J3/84 ,  C10J3/66

摘要： The invention provides a method of biomass grading pyrolysis gasification in a circulating fluidized bed comprising: feeding biomass into the lower-middle part of a carrying fluidized bed, mixing with high temperature synthesis gas and heat carrier from a turbulent fluidized bed, heating the biomass to carry out a pyrolysis reaction, and carrying the pyrolysis product upward; subjecting the cracked oil and gas to a gaseous phase catalytic cracking in an upper-middle part of the carrying fluidized bed, cracking the tar into methane, ethane and the like; subjecting the heat carrier, semi-coke and fuel gas after the reaction to the multi-stage of gas-solid separation, a large particle carrier and semi-coke following a first-level separation are used as the fuel gas cracking catalyst and the filter material for filtering and removing dust, and enter into a moving bed filter to separate out an ultra-fine ash and subsequently return to the turbulent fluidized bed so as to perform gasification reaction, the ultra-fine ash is delivered to the outside as a silicon-potash fertilizer product; the medium and small particle carrier and semi-coke separated from a second-level separation are directly recycled to the turbulent fluidized bed, the fine particles separated from a third-level separation is discharged to the outside as a silicon-potash fertilizer product, the moving bed filter further catalytically cracks a small amount of tar in the fuel gas into methane and ethane and removes the ultra-fine ash simultaneously, the purified fuel gas is delivered to the outside as a product.

公开(公告)号：US20190322942A1

公开(公告)日：2019-10-24

申请号：US16502941

申请日：2019-07-03

申请人： The Texas A&M University System

发明人： Sergio C. Capareda ,  Calvin B. Parnell, JR. ,  David B. Carney

IPC分类号： C10B53/00 ,  G01F1/76 ,  C10J3/48 ,  B01J8/44 ,  C10J3/50 ,  C10J3/84 ,  C10K1/02 ,  B04C5/26 ,  F23C10/20 ,  F16L41/02 ,  F23G7/10 ,  F23G5/30 ,  F23G5/027 ,  F23C10/10 ,  C10J3/54

摘要： A pyrolysis and gasification system produce a synthesis gas and bio-char from a biomass feedstock. The system includes a feed hopper that has a flow measurement device. The system also includes a reactor that is operable in a gasification mode or a pyrolysis mode. The reactor is configured to receive the biomass feedstock from the feed hopper. The reactor is operable to provide heat to the biomass feedstock from the feed hopper to produce the synthesis gas and bio-char. The system also includes a cyclone assembly. The produced synthesis gas including the bio-char is fed to the cyclone assembly. The cyclone assembly removes a portion of the bio-char from the synthesis gas.

公开(公告)号：US10208948B2

公开(公告)日：2019-02-19

申请号：US14900985

申请日：2015-02-04

申请人： SHANGHAI BOILER WORKS CO., LTD.

发明人： Jianjun Ni ,  Zhen Yang ,  Nan Chen ,  Jie Xiong

IPC分类号： F23C10/10 ,  C10J3/54 ,  C10J3/84 ,  F23C10/00

摘要： The present invention demonstrates a solid fuel grade gasification-combustion dual bed poly-generation system, comprising a combustion system, a gasification system, a synthesized gas cooling and purifying system and a synthesized gas methanation system. The combustion system is connected with the gasification system through a circulating material return system. The gasification system mainly adapts the circulating fluidized-bed combustion mode. The gasification system adapts the fluidized-bed incomplete gasification method and the generated semi-coke is returned to the combustion system for re-utilization. The synthesized gas purifying and cooling unit adapts water cycling and combustible recycling. The by-products, CO2 and steam, in the methanation unit can be recovered, so the maximum utilization rate of energy in this system is realized.

公开(公告)号：US09644152B2

公开(公告)日：2017-05-09

申请号：US14486021

申请日：2014-09-15

申请人： SHELL OIL COMPANY

发明人： Andries Quirin Maria Boon ,  Joseph Broun Powell ,  Lamar Lane Joffrion ,  Kimberly Ann Johnson ,  Hubert Willem Schenck

IPC分类号： C10G1/06 ,  C10G1/00 ,  C10L1/04 ,  C10K3/04 ,  C10G3/00 ,  C10J3/54 ,  C10J3/74 ,  C10L1/02 ,  C10G1/08 ,  C01B3/16

CPC分类号： C10G1/06 ,  C01B3/16 ,  C01B2203/0288 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/046 ,  C01B2203/0475 ,  C01B2203/148 ,  C01B2210/0009 ,  C01B2210/001 ,  C01B2210/0014 ,  C01B2210/0025 ,  C10G1/002 ,  C10G1/08 ,  C10G1/083 ,  C10G3/42 ,  C10G3/52 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/42 ,  C10J3/54 ,  C10J3/74 ,  C10J2300/1223 ,  C10J2300/1823 ,  C10K3/04 ,  C10L1/02 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  C10L2290/10 ,  Y02E50/32 ,  Y02P20/145 ,  Y02P30/20

摘要： A bottom fraction of a product of a hydrocatalytic reaction is gasified to generate hydrogen for use in further hydrocatalytic reactions. In one embodiment, an overhead fraction of the hydrocatalytic reaction is further processed to generate higher molecular weight compounds. In another embodiment, a product of the further processing is separated into a bottom fraction and an overhead fraction, where the bottom fraction is also gasified to generate hydrogen for use in further hydrocatalytic reactions.

公开(公告)号：US20160194568A1

公开(公告)日：2016-07-07

申请号：US14905103

申请日：2014-01-22

申请人： PYRONEER A/S

发明人： Rasmus Glar Nielsen ,  Peder Christian Stoholm

IPC分类号： C10J3/56 ,  C10J3/66 ,  C10J3/84 ,  C10J3/54

CPC分类号： C10J3/56 ,  C01B32/05 ,  C10J3/482 ,  C10J3/54 ,  C10J3/66 ,  C10J3/84 ,  C10J2300/094 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/0976

摘要： Provided are apparatus and methods of gasification using a circulating fluidized bed reactor comprising a separate pyrolysis reaction chamber, one or more primary char gasification chambers, and one or more secondary char gasification chambers which comprise an internal vertical reaction volume suitable for containing a particle bed fluidized by a predominantly vertical upwards gas flow. The vertical reaction volume is advantageous in that this provides the possibility for increased retention time of particles, facilitating comparatively slow “productive” temperature moderation based on endothermic char conversion.

摘要翻译： 提供了使用循环流化床反应器的循环流化床反应器的装置和方法，该循环流化床反应器包括单独的热解反应室，一个或多个主焦化气化室和一个或多个二次炭气化室，其包含适于容纳颗粒床流化的内部垂直反应体积 主要是垂直向上的气流。 垂直反应体积是有利的，因为这提供了增加颗粒的保留时间的可能性，促进基于吸热焦炭转化的相对缓慢的“生产”温度调节。

公开(公告)号：US09187704B2

公开(公告)日：2015-11-17

申请号：US10485608

申请日：2002-07-29

申请人： Hitoshi Inoue ,  Masayuki Horio

发明人： Hitoshi Inoue ,  Masayuki Horio

IPC分类号： C10J3/54 ,  C07C29/151 ,  C10J3/48 ,  C10K3/02 ,  C10K3/04

CPC分类号： C10J3/54 ,  C07C29/1518 ,  C10J3/482 ,  C10J2300/0906 ,  C10J2300/0916 ,  C10J2300/0956 ,  C10J2300/0973 ,  C10J2300/0983 ,  C10J2300/1659 ,  C10J2300/1665 ,  C10K3/023 ,  C10K3/04 ,  Y02E50/18 ,  Y02E50/32 ,  Y02E50/343 ,  Y02P20/129 ,  Y02P20/145 ,  C07C31/04

摘要： The present invention is directed to the provision of a method for efficiently producing a feedstock gas for use in the synthesis of liquid fuels including methanol by gasification of harbaceous plant or woody biomass feedstocks. Specifically, the present invention relates to a method for gasifying biomass to produce a feedstock gas for use in the production of liquid fuels including methanol, characterized by comprising the step of bringing a biomass-containing organic feedstock into fluid contact with a gasification accelerator comprising a clay having a catalytic function and/or a heating medium function in a gasification reaction zone under a raised temperature condition in the presence of a gasifying agent to convert the organic feedstock to gas useful for the production of a liquid fuel.

摘要翻译： 本发明涉及提供一种用于通过气化哈氏植物或木质生物质原料来有效地生产用于合成包含甲醇的液体燃料的原料气体的方法。 具体而言，本发明涉及一种用于气化生物质以生产用于生产包括甲醇的液体燃料的原料气体的方法，其特征在于包括使含生物质的有机原料与气化促进剂流体接触的步骤，所述气化促进剂包括 在气化反应区中在气化反应区中具有催化功能和/或加热介质功能的粘土在气化剂存在下在升高的温度条件下将有机原料转化成用于生产液体燃料的气体。

公开(公告)号：US09174844B2

公开(公告)日：2015-11-03

申请号：US13892681

申请日：2013-05-13

申请人： The Ohio State University Research Foundation

发明人： Shwetha Ramkumar ,  Liang-Shih Fan

IPC分类号： C01B3/58 ,  B01D53/10 ,  C01B3/34 ,  C01B3/48 ,  C10J3/54 ,  C10K3/04 ,  C10K1/00 ,  B01D53/62

CPC分类号： C01B3/583 ,  B01D53/10 ,  B01D53/62 ,  B01D2253/112 ,  B01D2256/16 ,  B01D2257/204 ,  B01D2257/304 ,  B01D2257/504 ,  C01B3/344 ,  C01B3/48 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/062 ,  C01B2203/0827 ,  C01B2203/148 ,  C01B2203/82 ,  C01B2203/84 ,  C01B2203/86 ,  C10G2300/1022 ,  C10J3/54 ,  C10J2300/1612 ,  C10J2300/1646 ,  C10J2300/1653 ,  C10J2300/1659 ,  C10K1/003 ,  C10K1/004 ,  C10K3/04 ,  Y02C10/04 ,  Y02C10/08 ,  Y02E20/16 ,  Y02E20/18 ,  Y02E20/185 ,  Y02P20/152 ,  Y02P30/30

摘要： A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO3, CaS and CaX2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO2, in the presence of synthesis gas, in the presence of H2 and O2, under partial vacuum, and combinations thereof.

摘要翻译： 一种生产氢的方法，包括以下步骤：（i）将燃料气化成包含CO，氢，蒸汽，硫和H 2 S，COS和HX形式的卤化物污染物的原料合成气，其中X是卤化物; （ii）使原始合成气通过注入CaO和蒸汽的水煤气变换反应器（WGSR），CaO与转移的气体反应以除去含CaCO3的固相含钙产物中的CO 2，硫和卤化物 ，CaS和CaX2; （iii）从富集的气态氢产物中分离出固相含钙产物; 和（iv）通过在选自以下的条件下煅烧固相钙含量产物来再生CaO：在蒸气存在下，在CO 2的存在下，在合成气存在下， H2和O2，以及它们的组合。