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    PREPARATION OF ISOCOUMARIN DERIVATIVES AND INTERMEDIATES FOR THE SYNTHESIS THEREOF
    32.
    发明公开
    PREPARATION OF ISOCOUMARIN DERIVATIVES AND INTERMEDIATES FOR THE SYNTHESIS THEREOF 审中-公开
    ZWISCHENPRODUKTEFÜRDEREN SYNTHESE的HERSTELLUNG VON ISOCUMARINDERIVATEN

    公开(公告)号：EP1364947A1

    公开(公告)日：2003-11-26

    申请号：EP02710457.9

    申请日：2002-02-01

    申请人： Mercian Corporation

    发明人： NAKATA, Masaya

    IPC分类号： C07D311/76 ,  C07C69/92 ,  C07C67/313 ,  C07C67/343

    CPC分类号： C07D407/12 ,  C07B2200/07 ,  C07C67/307 ,  C07C67/313 ,  C07C67/343 ,  C07C69/92 ,  C07D311/76

    摘要： A method of preparing optically active isocoumarin-3-yl-acetic acid derivatives represented by Formula (I):
    wherein a specific isocoumarin-ketene derivative is subjected to an addition reaction with an optically active alcohol, and then the ester thus obtained is subjected to a hydrolysis reaction. An intermediate for synthesis used therein. A method of preparing isocoumarin-3-yl-acetic acid derivatives represented by Formula (III):
    wherein a specific isocoumarin derivative is subjected to an addition reaction with carbon monoxide and oxygen in the presence of a transition metal catalyst. An intermediate for synthesis used therein.

    摘要翻译： 制备由式（I）表示的光学活性异香豆素-3-基 - 乙酸衍生物的方法：其中特异性异香豆素 - 乙烯酮衍生物与光学活性醇进行加成反应，然后由此获得酯 进行水解反应。 其中使用的合成中间体。 制备由式（III）表示的异香豆素-3-基 - 乙酸衍生物的方法：其中特异性异香豆素衍生物在过渡金属催化剂存在下与一氧化碳和氧进行加成反应。 其中使用的合成中间体。

    COMPOUND
    36.
    发明公开
    COMPOUND 有权
    复合

    公开(公告)号：EP1200494A1

    公开(公告)日：2002-05-02

    申请号：EP00945920.7

    申请日：2000-07-17

    申请人： Rolic AG

    发明人： MARCK, Guy ,  SCHUSTER, Andreas

    IPC分类号： C08F246/00 ,  C09K19/38 ,  C07C69/92

    CPC分类号： C08F246/00 ,  C07C69/92 ,  G02F1/133711 ,  G02F1/133788

    摘要： The present invention relates to new photoactive polymers, their use as liquid crystal (LC) orientation layers and their use in the construction of unstructured and structured optical and electro-optical elements and multi-layer systems. The new photoactive polymers are crosslinkable polymers that can be readily cross linked over a relatively short irradiation time.

    摘要翻译： 本发明涉及新的光敏聚合物，它们作为液晶（LC）取向层的用途以及它们在非结构化和结构化的光学和电光学元件以及多层系统的构造中的用途。 新的光敏聚合物是可交联的聚合物，其可以在相对较短的照射时间内容易地交联。

    LIQUID CRYSTAL COMPOUNDS
    37.
    发明公开
    LIQUID CRYSTAL COMPOUNDS 有权
    液晶化合物

    公开(公告)号：EP1169293A1

    公开(公告)日：2002-01-09

    申请号：EP00902824.2

    申请日：2000-02-15

    申请人： Rolic AG

    发明人： LUKAC, Teodor ,  BENECKE, Carsten ,  BUCHECKER, Richard

    IPC分类号： C07C69/92 ,  C09K19/20 ,  C09K19/34 ,  C09K19/32 ,  C09K19/38

    CPC分类号： C09K19/32 ,  C07C69/92 ,  C07C255/54 ,  C09K19/2007 ,  C09K19/34 ,  C09K19/38 ,  C09K2019/0448 ,  C09K2019/0481

    摘要： A compound of formula (I), wherein G?1 and G2¿ independently represent a polymerisable mesogenic residue; X represents a group selected from -CH¿2?-, -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO-, -OCONR'; Sp represents a group of the formula -(CH2)p- in which p is an integer of 1 to 18 and in which one or two non adjacent -CH2- groups are optionally replaced by -CH=CH-; or in which one or two -CH2- groups are optionally replaced by one or two groups selected from the group consisting of -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO-, -OCONR' with the proviso that firstly the spacer group does not contain two adjacent heteroatoms and secondly when X is -CH2-, p can also have a value of 0; and M represents an achiral group of formula (II) in which A and B independently represent an optionally substituted six membered isocyclic or heterocyclic group or naphthalenediyl; C is selected from the group consisting of an optionally substituted five and six membered isocyclic or heterocyclic group or naphthalenediyl; n?1 and n2¿ are 0 or 1 with the proviso that firstly 1≤n1+n2≤2 and secondly, when C is naphthalenediyl 0≤n1+n2≤2; Z1 is selected from the group consisting of -O-, -COO-, -OOC-, -CO-, -CONR'-, -NR'CO-, OCOO-, -OCONR'-, -NR'COO- and a single bond; in which R' is selected from the group consisting of hydrogen, a lower achiral alkyl group and a lower achiral alkenyl group; Z?2 and Z3¿ are independently selected from the group consisting of single bond, -COO-, -OOC-, -CH¿2?-CH2-, -CH2O-, -OCH2-, -CH=CH-, -C C-, -(CH2)4- and -(CH2)3O-; and R?1¿ is selected from the group consisting of -CN, -COR, -COOR, -OCOR, -CONR'R, -NR'COR, OCOOR, -OCONR'R, -NR'COOR, -F, -Cl, -CF¿3?, -OCF3, -OR and -R in which R is selected from the group consisting of hydrogen, an achiral C1-18 alkyl group and an achiral C4-18 alkenyl group with the double bond at 3-position or higher; and R' is as defined above; with the proviso that at most one of the rings A, B and C is a naphthalenediyl group is provided as well as liquid crystalline mixtures, films and electro-optical devices comprising the compound.

    摘要翻译： 式（I）化合物，其中G 1和G 2独立地代表可聚合的介晶残基; X代表选自-CH 2， - O - ， - CO - ， - COO - ， - OOC - ， - CONR' - ， - OCOO - ， - OCONR' Sp表示式 - （CH 2）p - 的基团，其中p为1至18的整数，并且其中一个或两个不相邻的-CH 2 - 基团任选被-CH = CH-替代; 或其中一个或两个-CH 2 - 基团任选地被一个或两个选自-O - ， - CO - ， - COO - ， - OOC - ， - CONR'-，-OCOO - ， - OCONR'，条件是首先间隔基团不含有两个相邻的杂原子，其次当X是-CH 2 - 时，p也可以具有0的值; 且M代表式（II）的非手性基团，其中A和B独立地表示任选取代的六元异环或杂环基团或萘二基; C选自任选取代的五元和六元异环或杂环基或萘二基; n1和n2是0或1，条件是首先1≤n1+n2≤2，其次，当C是萘二基0≤n1+n2≤2时; Z 1选自-O - ， - COO - ， - OOC - ， - CO - ， - CONR'-， - NR'CO-，OCOO - ， - OCONR'-， - NR'COO-和 单键; 其中R'选自氢，低级非手性烷基和低级非手性烯基; Z2和Z3独立地选自单键，-COO-，-OOC-，-CH2-，-CH2-，-CH2O-，-OCH2-，-CH = CH-，-C （CH 2）4 - 和 - （CH 2）3 O-; R 1选自-CN，-COR，-COOR，-OCOR，-CONR'R，-NR'COR，OCOOR，-OCONR'R，-NR'COOR，-F， - Cl，-CF 3，-OCF 3，-OR和-R，其中R选自氢，非手性C 1-18烷基和非手性C 4-18烯基， 职位或更高; 和R'如上所定义; 条件是至多环A，B和C中的一个是萘二基，以及包含该化合物的液晶混合物，膜和电光器件。