ELECTROLUMINESCENT POLYMERS AND USE THEREOF IN LIGHT-EMITTING DEVICES
    6.
    发明公开
    ELECTROLUMINESCENT POLYMERS AND USE THEREOF IN LIGHT-EMITTING DEVICES 审中-公开
    电致发光聚合物及其用途在发光器件

    公开(公告)号:EP1401916A1

    公开(公告)日:2004-03-31

    申请号:EP02744167.4

    申请日:2002-05-22

    申请人: SRI INTERNATIONAL

    发明人: PEI, Qibing

    IPC分类号: C08G73/00

    摘要: The invention provides conjugated polymers that have good solubility and semiconductivity, and that display high photoluminescent and electroluminescent efficiency. Representative polymers containing monomer units having the general structure of formula (I):wherein: Ar and Ar are independently selected from the group consisting of monocyclic, bicyclic and polycyclic arylene, heteroarylene, substituted arylene and substituted heteroarylene groups; L is alkylene, alkenylene, substituted alkylene, substituted alkenylene, heteroalkylene, heteroalkenylene, substituted heteroalkylene, substituted heteroalkenylene, arylene, heteroarylene, substituted arylene, substituted heteroarylene, or a combination thereof; Q is a heteroatom; m is zero or 1; p is zero or 1, and q is zero or 1, with the proviso that when p is zero, then q is zero; x is zero or 1; Q and Q are independently selected from the group consisting of H, aryl, heteroaryl, substituted aryl, substituted heteroaryl, alkyl, substituted alkyl, heteroalkyl, and substituted heteroalkyl, and Q is selected from the group consisting of alkyl, substituted alkyl, heteroalkyl, and substituted heteroalkyl, with the proviso that when m is 1, Q and Q are other than H; and A is a negatively charged counterion. Electroluminescent and other devices containing a polymer of the invention are also provided.

    Herstellung von Poly-o-hydroxyamiden und Poly-o-mercaptoamiden

    公开(公告)号:EP0761721A2

    公开(公告)日:1997-03-12

    申请号:EP96113308.9

    申请日:1996-08-19

    IPC分类号: C08G73/22 C08G75/32 C08G69/32

    摘要: Bei einem Verfahren zur Herstellung von Poly-o-hydroxyamiden und Poly-o-mercaptoamiden wird ein Bis-o-aminophenol bzw. ein Bis-o-aminothiophenol mit einem Dicarbonsäurederivat folgender Struktur umgesetzt:
    mit D = O, S oder NH
    und wobei R* der Grundkörper der Dicarbonsäure ist und wenigstens einer der Reste R 1 bis R 5 F oder CF 3 .

    摘要翻译: 产品 的聚邻位羟基酰胺或聚-O-巯基 - 酰胺(I)包括使双邻氨基苯酚或双邻氨基苯硫酚(II)与二羧酸衍生物反应。 式(III)的化合物,其中D = O,S或NH; R1-R5 = H,F,CH3或CF3,这些gps中的至少一个。 为F或CF 3,不超过2为CH 3或CF 3; R * =(CR2)m或其中一个gps。 (i) - (xiii),其中R = H,F,CH 3或CF 3; m = 1-10; A =(CH2)n,(CF2)p,CMe2,C(CF3)2,CMePh,C(CF3)Ph,C(CF3)C6F5,CPh2,CF2-CF(CF3),CH = CH,CF = CF ,C标识C,O-C6H4-O,O,S,CO或SO2; n = 0-10; p = 1-10; X = CH或N; T = CH 2,CF 2,CO,O,S,NH或NMe; Z 1 = CH 2或CHMe且Z 2 = CH或CMe或Z 1 = CH 2或CHMe且Z 2 = N或Z 1 = NH或NMe,Z 2 = CH或CMe,或Z 1 = NH或NMe,Z 2 = N; Z 3 = CH,CMe或N; Z 4 = O或S; 并且其中任何芳香族gps中的所有H原子。 可以替换为F.