公开(公告)号：US20160304692A1

公开(公告)日：2016-10-20

申请号：US15100956

申请日：2013-12-27

Applicant: Yudong QI ,  Yan LI ,  Shana P. BUNKER ,  Stephane COSTEUX ,  Ted A. MORGAN ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： Yudong Qi ,  Yan Li ,  Shana P. Bunker ,  Stephane Costeux ,  Ted A. Morgan

IPC: C08J9/12 ,  C09K21/14 ,  C08J9/00 ,  C08F220/14

CPC classification number: C08J9/122 ,  C08F220/14 ,  C08F230/02 ,  C08J9/0061 ,  C08J9/12 ,  C08J2201/032 ,  C08J2203/06 ,  C08J2203/08 ,  C08J2205/042 ,  C08J2205/044 ,  C08J2325/12 ,  C08J2333/04 ,  C08J2333/10 ,  C08J2333/12 ,  C08J2343/00 ,  C08J2343/02 ,  C08J2425/12 ,  C08J2433/04 ,  C08J2433/12 ,  C08J2443/02 ,  C08L33/12 ,  C09K21/14 ,  C08L43/02

Abstract: Polymer foam bodies are made from phosphorus-containing thermoplastic random copolymers of a dialkyl (meth)acryloyloxyalkyl phosph(on)ate. Foam bodies made from these copolymers exhibit increased limiting oxygen indices and surprisingly have good properties. In certain embodiments, the phosphorus-containing thermoplastic copolymer is blended with one or more other polymers and formed into nanofoams.

Abstract translation: 聚合物泡沫体由（a）二烷基（甲基）丙烯酰氧基烷基磷酸酯的含磷热塑性无规共聚物制成。 由这些共聚物制成的泡沫体显示出增加的极限氧指数，令人惊奇地具有良好的性能。 在某些实施方案中，含磷热塑性共聚物与一种或多种其它聚合物共混并形成纳米电子烟。

公开(公告)号：US20090306280A1

公开(公告)日：2009-12-10

申请号：US12162913

申请日：2007-02-07

Applicant: Shih-Yaw Lai ,  Yuen-Yuen D. Chiu ,  Ashish Sen ,  Stephane Costeux

Inventor： Shih-Yaw Lai ,  Yuen-Yuen D. Chiu ,  Ashish Sen ,  Stephane Costeux

IPC: C08L23/00 ,  C08F210/00 ,  C08L23/06 ,  C08F110/02

CPC classification number: D01F6/46 ,  D01F8/06

Abstract: The present invention relates to crosslinked, olefin elastic fibers where the olefin materials are specifically selected to provide a more robust fiber with higher tenacity and greater temperature stability. Such fibers will be less subject to breakage during fiber spinning and post-spinning (downstream processing) operations including spool formation and unwinding. The specific olefin material used is a blend having an overall melt index (I2) of less than 2.5 g/10 min before crosslinking with a density in the range of 0.865 to 0.885 g/cm3. One component of the blend will be characterized as having either a density in the range of from 0.855 to 0.88 g/cm3 or a residual crystallinity at 80° C. of greater than 9 percent but not both. The at least one other component will meet at least whichever characteristic the first component does not meet.

Abstract translation: 本发明涉及交联的烯烃弹性纤维，其中烯烃材料被特别选择以提供具有更高韧性和更高温度稳定性的更坚固的纤维。 在纤维纺丝和后纺（下游处理）操作中，这种纤维将不会发生断裂，包括卷筒的形成和展开。 使用的特定烯烃材料是在0.865至0.885g / cm 3的密度交联之前具有小于2.5g / 10min的总体熔体指数（I 2）的共混物。 共混物的一种组分将被表征为具有在0.855至0.88g / cm 3范围内的密度或在80℃下的残余结晶度大于9％但不是均为二者。 至少一个其他组件将至少满足第一个组件不符合的特征。

公开(公告)号：US20090246433A1

公开(公告)日：2009-10-01

申请号：US11721388

申请日：2005-12-09

Applicant: William J. Michie ,  Dane Chang ,  Anthony C. Neubauer ,  Mridula Kapur ,  Todd A. Hogan ,  Felipe B. Martinez ,  Stephane Costeux

Inventor： William J. Michie ,  Dane Chang ,  Anthony C. Neubauer ,  Mridula Kapur ,  Todd A. Hogan ,  Felipe B. Martinez ,  Stephane Costeux

IPC: C08L23/04 ,  B29C47/00 ,  B29D22/00 ,  B29D23/00 ,  B32B1/08 ,  C08L81/06

CPC classification number: C08K5/43 ,  C08L23/0807 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L23/08 ,  C08L2666/06

Abstract: A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component coupled with a polysulfonyl azide. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (LTD) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolymer or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same, or different, composition (that is, with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described. Compositions comprising a chromium-catalyzed ethylene polymer, coupled with a polysulfonyl azide are also described herein.

Abstract translation: 聚合物组合物包含与聚磺酰叠氮基偶联的低分子量（LMW）乙烯聚合物组分和高分子量（HMW）乙烯聚合物组分。 优选地，LMW聚乙烯组分和HMW聚乙烯组分在组合物中共结晶，使得其在薄片厚度分布（LTD）曲线中表现出单一或基本上单峰。 用于LMW和HMW聚乙烯组分的乙烯聚合物可以是均聚物或乙烯共聚物。 优选地，两种组分都是相同或不同组成（即相同或不同的共聚单体）的乙烯共聚物。 描述了制造管道的方法，其包括选择在LTD曲线中具有基本单峰的聚合物组合物。 本文还描述了包含铬催化的乙烯聚合物与聚磺酰叠氮化物偶联的组合物。

公开(公告)号：US09840605B2

公开(公告)日：2017-12-12

申请号：US15100956

申请日：2013-12-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  Yudong Qi ,  Yan Li ,  Shana P. Bunker ,  Stephane Costeux ,  Ted A. Morgan

Inventor： Yudong Qi ,  Yan Li ,  Shana P. Bunker ,  Stephane Costeux ,  Ted A. Morgan

IPC: C08J9/12 ,  C09K21/14 ,  C08F220/14 ,  C08J9/00 ,  C08F220/00

CPC classification number: C08J9/122 ,  C08F220/14 ,  C08F230/02 ,  C08J9/0061 ,  C08J9/12 ,  C08J2201/032 ,  C08J2203/06 ,  C08J2203/08 ,  C08J2205/042 ,  C08J2205/044 ,  C08J2325/12 ,  C08J2333/04 ,  C08J2333/10 ,  C08J2333/12 ,  C08J2343/00 ,  C08J2343/02 ,  C08J2425/12 ,  C08J2433/04 ,  C08J2433/12 ,  C08J2443/02 ,  C08L33/12 ,  C09K21/14 ,  C08L43/02

Abstract: Polymer foam bodies are made from phosphorus-containing thermoplastic random copolymers of a dialkyl (meth)acryloyloxyalkyl phosph(on)ate. Foam bodies made from these copolymers exhibit increased limiting oxygen indices and surprisingly have good properties. In certain embodiments, the phosphorus-containing thermoplastic copolymer is blended with one or more other polymers and formed into nanofoams.

公开(公告)号：US20090197983A1

公开(公告)日：2009-08-06

申请号：US12334877

申请日：2008-12-15

Applicant: Chau Van Vo ,  David J. Frankowski ,  Stephane Costeux

Inventor： Chau Van Vo ,  David J. Frankowski ,  Stephane Costeux

IPC: C08J9/00 ,  C08L25/12

CPC classification number: C08J9/122 ,  C08J9/0061 ,  C08J2201/03 ,  C08J2205/052 ,  C08J2325/04 ,  C08J2325/12 ,  C08J2423/00

Abstract: An extruded polymeric foam comprising a styrenic polymer and an olefinic polymer, the olefinic polymer in an amount less than the amount of the styrenic polymer. The styrenic polymer and the olefinic polymer are present as a blend, preferably free of an interpolymer or compatiblizer. The foam has a density below about 36 kg/m3 (as measured by ASTM D1622-03), a vertical compressive strength greater than about 100 kPa (as measured by ASTM D1621-04) and a compressive strength ratio greater than about 0.35.

Abstract translation: 包含苯乙烯聚合物和烯烃聚合物的挤出聚合物泡沫体，该烯烃聚合物的量小于苯乙烯聚合物的量。 苯乙烯聚合物和烯烃聚合物作为共混物存在，优选不含互聚物或增容剂。 泡沫的密度低于约36kg / m 3（通过ASTM D1622-03测量），大于约100kPa的垂直压缩强度（通过ASTM D1621-04测量），抗压强度比大于约0.35。

公开(公告)号：US20080125547A1

公开(公告)日：2008-05-29

申请号：US11816970

申请日：2006-03-03

Applicant: Kurt Swogger ,  Pak-Wing S. Chum ,  Thomas Oswald ,  Stephane Costeux

Inventor： Kurt Swogger ,  Pak-Wing S. Chum ,  Thomas Oswald ,  Stephane Costeux

IPC: C08L23/00

CPC classification number: C08L23/04 ,  C08L2205/02 ,  C08L2666/06 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/11 ,  C08F2500/12

Abstract: Ethylene polymer compositions comprising a high molecular weight high density polyethylene resin and a low density polyethylene resin are disclosed, where the polymer composition has a comparatively high melt strength for a given melt index. The compositions comprise from 25 to 99 percent by weight of the composition of a linear or substantially linear polyethylene polymer having a density of at least about 0.90 g/cc, and an I21 of less than about 20; and from 1 to 25 percent by weight of the composition of a high pressure low density type polyethylene resin having a melt index (I2) less than about 5, a molecular weight distribution greater than about 10, a Mw_abs/Mw_gpc ratio (“Gr”) of at least 2.7, and a melt strength at 190° C. greater than 19.0−12.6*log10(Mi). The compositions of the present invention are particularly well suited for blown film and thermoforming applications.

Abstract translation: 公开了包含高分子量高密度聚乙烯树脂和低密度聚乙烯树脂的乙烯聚合物组合物，其中聚合物组合物对于给定的熔体指数具有相对较高的熔体强度。 该组合物包含25至99重量％的组合物，其密度为至少约0.90g / cc，I21小于约20的直链或基本上线性的聚乙烯聚合物; 和组合物的1至25重量％的熔体指数（I 2）小于约5，分子量分布大于约10，Mw_abs / Mw_gpc比（“Gr”）的高压低密度型聚乙烯树脂， ）至少为2.7，熔体强度为190℃，大于19.0-12.6 * log10（Mi）。 本发明的组合物特别适用于吹塑薄膜和热成型应用。

公开(公告)号：US20070149711A1

公开(公告)日：2007-06-28

申请号：US10583294

申请日：2004-12-24

Applicant: Bharat Chaudhary ,  Stephane Costeux ,  John Klier ,  Thomas Peterson ,  Eric Wasserman

Inventor： Bharat Chaudhary ,  Stephane Costeux ,  John Klier ,  Thomas Peterson ,  Eric Wasserman

IPC: C08F263/00

CPC classification number: C08F8/00 ,  C08K5/14 ,  C08K5/3435 ,  C08F14/00 ,  C08F12/00 ,  C08F10/00

Abstract: The present invention is a rheology-modifiable polymeric composition or a free-radical crosslinkable polymeric composition, wherein the resulting rheologymodifying bond or crosslinking bond is a thermally-reversible bond. The resulting polymer is prepared from at least one polymer which upon forming free radicals preferentially degrades or carbon-carbon crosslinks. The present invention permits suppression of the preferential reaction while permitting the polymer to be coupled or crosslinked through a thermally-reversible bond. Suppressing the undesirable degradation or carbon-carbon crosslinking reaction and permitting the desirable reaction yield a rheology-modified polymer or a free-radical thermally-reversibly crosslinked polymer.

Abstract translation: 本发明是可流变改性的聚合物组合物或自由基可交联聚合物组合物，其中所得的流变改性键或交联键是热可逆键。 所得聚合物由至少一种聚合物制备，其在形成自由基时优先降解或碳 - 碳交联。 本发明允许抑制优选反应，同时允许聚合物通过热可逆键结合或交联。 抑制不期望的降解或碳 - 碳交联反应并允许所需的反应产生流变改性聚合物或自由基热可逆交联的聚合物。

公开(公告)号：US20120100357A1

公开(公告)日：2012-04-26

申请号：US12282223

申请日：2007-03-09

Applicant: William J. Michie, JR. ,  Todd A. Hogan ,  Felipe Martinez Barreneche ,  Anthony C. Neubauer ,  Stephane Costeux

Inventor： William J. Michie, JR. ,  Todd A. Hogan ,  Felipe Martinez Barreneche ,  Anthony C. Neubauer ,  Stephane Costeux

IPC: B32B3/00 ,  D01F1/02 ,  B29C47/92 ,  C08F110/02

CPC classification number: B29C47/0869 ,  B29C47/0004 ,  B29C47/1072 ,  B29C47/92 ,  B29C2947/922 ,  B29C2947/92266 ,  B29C2947/92485 ,  B29C2947/92761 ,  B29C2947/92933 ,  B29K2023/065 ,  C08J5/18 ,  C08J2323/08

Abstract: This invention relates to coupling of polyethylene resins, more specifically coupling of polyethylene resins for use in extruded profiles, especially extruded profiles for sheet extrusion and cut sheet thermoforming applications and geomembranes. The process involves conveying a HDPE resin through an extruder, wherein the extruder comprises a feed zone, a first melt zone downstream of the feed zone, a second melt zone downstream of the first melt zone, and a third melt zone downstream of the second melt zone. The resin is melted in the first zone, contacted with oxygen in the second melt zone, and contacted antioxidant in the third melt zone.

Abstract translation: 本发明涉及聚乙烯树脂的偶联，更具体地说，用于挤出型材的聚乙烯树脂的偶联，特别是用于片材挤出和切割片材热成型应用的挤出型材以及土工膜。 该方法包括将HDPE树脂输送通过挤出机，其中挤出机包括进料区，进料区下游的第一熔融区，第一熔融区下游的第二熔融区，第二熔体下游的第三熔融区 区。 树脂在第一区域熔化，与第二熔融区域中的氧气接触，并在第三熔融区域中与抗氧化剂接触。

公开(公告)号：US20100056727A1

公开(公告)日：2010-03-04

申请号：US12064308

申请日：2006-08-18

Applicant: Colin LiPiShan ,  Mridula (Babli) Kapur ,  Stephane Costeux ,  David T. Gillespie

Inventor： Colin LiPiShan ,  Mridula (Babli) Kapur ,  Stephane Costeux ,  David T. Gillespie

IPC: C08L23/06

CPC classification number: C08L23/08 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2666/06

Abstract: The invention provides compositions for blow molding applications and other applications, where such compositions comprise a high density ethylene polymer and a high molecular weight ethylene polymer. In these compositions, the high density ethylene polymer has a density greater than the density of the high molecular weight ethylene polymer, and the high molecular weight ethylene polymer has a weight average molecular weight greater than the weight average molecular weight of the high density ethylene polymer, and in addition, the high density ethylene polymer has a density from 0.94 g/cm3 to 0.98 g/cm3, and a molecular weight distribution, Mw/Mn, greater than 8, and the high molecular weight ethylene polymer has a weight average molecular weight greater than 200,000 g/mole, and a molecular weight ratio, Mz/Mw, less than 5.

Abstract translation: 本发明提供用于吹塑应用和其它应用的组合物，其中这种组合物包含高密度乙烯聚合物和高分子量乙烯聚合物。 在这些组合物中，高密度乙烯聚合物的密度大于高分子量乙烯聚合物的密度，高分子量乙烯聚合物的重均分子量大于高密度乙烯聚合物的重均分子量 另外，高密度乙烯聚合物的密度为0.94g / cm 3至0.98g / cm 3，分子量分布Mw / Mn大于8，高分子量乙烯聚合物的重均分子量 重量大于200,000g / mol，分子量比Mz / Mw小于5。

公开(公告)号：US20080188623A1

公开(公告)日：2008-08-07

申请号：US11592524

申请日：2006-11-03

Applicant: Bharat I. Chaudhary ,  Malcolm F. Finlayson ,  Stephen F. Hahn ,  Stephane Costeux ,  John Scott Parent ,  Saurav S. Sengupta

Inventor： Bharat I. Chaudhary ,  Malcolm F. Finlayson ,  Stephen F. Hahn ,  Stephane Costeux ,  John Scott Parent ,  Saurav S. Sengupta

IPC: C08F8/40

CPC classification number: C08F8/40

Abstract: The present invention yields a triallyl phosphate (TAP)-mediated, rheology-modified polymer being prepared in a reaction from a reaction mixture made from or containing (a) a free-radical, chain-scissionable organic polymer and (b) TAP, wherein the TAP-mediated, rheology-modified polymer has extensional viscosity at Hencky strains above one greater than that of the free-radical, chain-scissionable organic polymer and/or a Relaxation Spectra Index (RSI) greater than that of the free-radical, chain-scissionable organic polymer.

Abstract translation: 本发明产生了一种由烯丙基（TAP）介导的流变学改性的聚合物，它是在由（a）自由基，可断开的有机聚合物和（b）TAP制成的反应混合物的反应中制备的，其中 TAP介导的流变改性聚合物在Hencky菌株具有比自由基，可断开链段的有机聚合物和/或大于自由基的松弛光谱指数（RSI）大一倍以上的拉伸粘度， 可断链的有机聚合物。