公开(公告)号：US20180044564A1

公开(公告)日：2018-02-15

申请号：US15541067

申请日：2015-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Eumi Pyun ,  Dennis E. Vogel ,  Thu-Van Tran ,  Tabitha A. Clem ,  Haohao Lin ,  William H. Moser ,  Anthony R. Plepys ,  Richard B. Ross

IPC: C09J143/02 ,  C09K21/14 ,  C08F220/12 ,  C08F230/02 ,  C09J133/08 ,  C09J7/02

CPC classification number: C09J143/02 ,  C08F220/12 ,  C08F230/02 ,  C08F265/06 ,  C09D143/02 ,  C09J7/385 ,  C09J133/08 ,  C09J2203/326 ,  C09J2433/00 ,  C09K21/14 ,  C08F2220/1858 ,  C08F220/06 ,  C08F220/56

Abstract: A halogen-free flame retardant adhesive comprises an acrylic copolymer preparable by polymerization of monomers comprising a first monomer which comprises a low glass transition temperature (Tg) monomer, a second monomer which comprises a high Tg monomer, wherein at least one of the first and second monomers comprises a (meth)acrylate, and a phosphinate containing monomer.

公开(公告)号：US10526515B2

公开(公告)日：2020-01-07

申请号：US15541067

申请日：2015-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Eumi Pyun ,  Dennis E. Vogel ,  Thu-Van Tran ,  Tabitha A. Clem ,  Haohao Lin ,  William H. Moser ,  Anthony R. Plepys ,  Richard B. Ross

IPC: C09J143/02 ,  C09J7/38 ,  C09J133/08 ,  C09J133/10 ,  C08F265/06 ,  C08F220/12 ,  C08F220/18 ,  C08F230/02 ,  C09K21/14 ,  C09D143/02

Abstract: A halogen-free flame retardant adhesive comprises an acrylic copolymer preparable by polymerization of monomers comprising a first monomer which comprises a low glass transition temperature (Tg) monomer, a second monomer which comprises a high Tg monomer, wherein at least one of the first and second monomers comprises a (meth)acrylate, and a phosphinate containing monomer.

公开(公告)号：US09908837B2

公开(公告)日：2018-03-06

申请号：US14769850

申请日：2014-03-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joshua L. Colby ,  Aaron E. Hutt ,  Terence D. Spawn ,  Jason D. Clapper ,  Tabitha A. Clem

IPC: C07C1/24 ,  C07C11/02 ,  C07C67/04 ,  C07C69/54 ,  C08F220/06 ,  C08F220/18 ,  C09J133/08

CPC classification number: C07C67/04 ,  C07C1/24 ,  C07C2531/08 ,  C07C2531/10 ,  C08F220/18 ,  C09J133/08 ,  C07C69/54 ,  C07C11/02 ,  C08F2220/1825 ,  C08F220/06

Abstract: Polymers, particularly those used in pressure-sensitive adhesives, are prepared from a mixture of structural isomers of a secondary alkyl (meth)acrylate monomer. The mixture is made by dehydrating a biobased C2-C22 alcohol with a first acid catalyst using a continuous process to form a mixture of olefins, and reacting (meth)acrylic acid with at least some of the mixture of olefins in the presence of a second acid catalyst. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics, and containing biobased material.

公开(公告)号：US20160002140A1

公开(公告)日：2016-01-07

申请号：US14769875

申请日：2014-03-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joshua L. Colby ,  Tabitha A. Clem ,  Terence D. Spawn ,  Aaron E. Hutt ,  Wade T. Teply

IPC: C07C67/08 ,  C07C57/02 ,  C09J133/08

CPC classification number: C07C67/08 ,  C07C57/02 ,  C08F220/18 ,  C09J133/08 ,  Y02P20/582 ,  C07C69/54 ,  C08F2220/1858 ,  C08F220/06

Abstract: A method of making 2-octyl acrylate comprising reacting 2-octanol with acrylic acid in the presence of an acid catalyst and added water is described. The 2-octanol may be derived from renewable resources, such as castor oil. The method is efficient and provides selectivity for 2-octyl acrylate.

Abstract translation: 描述了在酸催化剂和加入水的存在下，使2-辛醇与丙烯酸反应制备丙烯酸2-辛酯的方法。 2-辛醇可来自可再生资源，如蓖麻油。 该方法是有效的，并为丙烯酸2-辛酯提供选择性。

公开(公告)号：US20150299354A1

公开(公告)日：2015-10-22

申请号：US14435570

申请日：2013-10-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Miguel A. Guerra ,  Tatsuo Fukushi ,  Zai-Ming Qiu ,  Tabitha A. Clem

IPC: C08F214/18 ,  C08F214/24 ,  C08F214/26 ,  C07C17/093 ,  C07C19/16 ,  C07C17/275 ,  C07C315/04 ,  C08F214/28 ,  C07C21/18

CPC classification number: C08F214/184 ,  C07C17/093 ,  C07C17/25 ,  C07C17/275 ,  C07C19/16 ,  C07C21/17 ,  C07C21/18 ,  C07C313/12 ,  C07C315/04 ,  C08F214/18 ,  C08F214/22 ,  C08F214/24 ,  C08F214/26 ,  C08F214/28 ,  C08F214/00

Abstract: Described herein is a composition comprising a partially fluorinated compound selected from the group consisting of: I(CF2)XCH═CH2 (Formula III); and I(CF2)XCH2CH2I (Formula II) wherein x is an odd integer selected from 3 to 11.

Abstract translation: 本文描述的是包含选自以下的部分氟化化合物的组合物：I（CF 2）X CH = CH 2（式III）; 和I（CF 2）XCH 2 CH 2 I（式II）其中x是选自3至11的奇整数。

公开(公告)号：US20180022967A1

公开(公告)日：2018-01-25

申请号：US15541058

申请日：2015-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Eumi Pyun ,  George W. Griesgraber ,  Thu-Van Tran ,  Tabitha A. Clem ,  Haohao Lin ,  William H. Moser ,  Anthony R. Plepys ,  Richard B. Ross ,  David J. Yarusso ,  Corinne E. Lipscomb

IPC: C09J9/00 ,  C08F230/02 ,  C08F220/18 ,  C09J7/02 ,  C09K21/14

CPC classification number: C09J9/00 ,  C08F220/18 ,  C08F230/02 ,  C08F2220/1858 ,  C09D143/02 ,  C09J7/385 ,  C09J133/14 ,  C09J2201/606 ,  C09J2203/326 ,  C09J2400/163 ,  C09J2433/00 ,  C09K21/14 ,  C08F2220/1875 ,  C08F220/06 ,  C08F2222/1013

Abstract: A halogen-free flame retardant adhesive comprises an acrylic copolymer preparable by polymerization of monomers comprising a first monomer which comprises a low glass transition temperature (Tg) monomer, a second monomer which comprises a high Tg monomer, wherein at least one of the first and second monomers comprises a (meth)acrylate, and a phosphate containing monomer.

公开(公告)号：US09604902B2

公开(公告)日：2017-03-28

申请号：US14769875

申请日：2014-03-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joshua L. Colby ,  Tabitha A. Clem ,  Terence D. Spawn ,  Aaron E. Hutt ,  Wade T. Teply

IPC: C07C67/08 ,  C09J133/08 ,  C08F220/18 ,  C07C57/02

CPC classification number: C07C67/08 ,  C07C57/02 ,  C08F220/18 ,  C09J133/08 ,  Y02P20/582 ,  C07C69/54 ,  C08F2220/1858 ,  C08F220/06

Abstract: A method of making 2-octyl acrylate comprising reacting 2-octanol with acrylic acid in the presence of an acid catalyst and added water is described. The 2-octanol may be derived from renewable resources, such as castor oil. The method is efficient and provides selectivity for 2-octyl acrylate.

公开(公告)号：US20160009628A1

公开(公告)日：2016-01-14

申请号：US14769850

申请日：2014-03-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joshua L. Colby ,  Aaron E. Hutt ,  Terence D. Spawn ,  Jason D. Clapper ,  Tabitha A. Clem

IPC: C07C67/04 ,  C07C1/24

CPC classification number: C07C67/04 ,  C07C1/24 ,  C07C2531/08 ,  C07C2531/10 ,  C08F220/18 ,  C09J133/08 ,  C07C69/54 ,  C07C11/02 ,  C08F2220/1825 ,  C08F220/06

Abstract: Polymers, particularly those used in pressure-sensitive adhesives, are prepared from a mixture of structural isomers of a secondary alkyl (meth)acrylate monomer. The mixture is made by dehydrating a biobased C2-C22 alcohol with a first acid catalyst using a continuous process to form a mixture of olefins, and reacting (meth)acrylic acid with at least some of the mixture of olefins in the presence of a second acid catalyst. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics, and containing biobased material.

Abstract translation: 聚合物，特别是用于压敏粘合剂的聚合物，由（甲基）丙烯酸仲烷基酯单体的结构异构体的混合物制备。 该混合物通过使用连续方法用第一种酸催化剂使生物基C2-C22醇脱水来形成烯烃的混合物，并在第二种存在下使（甲基）丙烯酸与至少一些烯烃混合物反应 酸催化剂。 粘合剂的特征在于显示粘合剂和内聚特性的总体平衡，并且包含生物基材料。