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公开(公告)号：US06656877B2
公开(公告)日：2003-12-02
申请号：US10120672
申请日：2002-04-11
申请人： Edward L. Sughrue , Marvin J. Johnson , Glenn W. Dodwell , Larry E. Reed , Joseph E. Bares , Jason J. Gislason , Robert W. Morton , James L. Malandra
发明人： Edward L. Sughrue , Marvin J. Johnson , Glenn W. Dodwell , Larry E. Reed , Joseph E. Bares , Jason J. Gislason , Robert W. Morton , James L. Malandra
IPC分类号： B01J2000
CPC分类号： B01J20/106 , B01J20/02 , B01J20/0203 , B01J20/06 , B01J20/08 , B01J20/103 , B01J2220/42 , C10G25/003 , C10G2300/202 , C10G2300/207 , C10G2300/305 , C10G2400/02 , C10G2400/04 , C10L1/06 , C10L1/08
摘要： Attrition resistant, sorbent compositions for the removal of elemental sulfur and sulfur compounds, such as hydrogen sulfide and organic sulfides, from cracked-gasoline and diesel fuels are prepared by the impregnation of a sorbent support comprising zinc oxide, expanded perlite, and alumina with a promoter such as nickel, nickel oxide or a precursor of nickel oxide followed by reduction of the valence of the promoter metal in the resulting promoter metal sorbent support composition.
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公开(公告)号：US07241929B2
公开(公告)日：2007-07-10
申请号：US10660138
申请日：2003-09-11
申请人： Edward L. Sughrue , Marvin J. Johnson , Glen W. Dodwell , Larry E. Reed , Joseph E. Bares , Jason J. Gislason , Robert W. Morton , James L. Malandra
发明人： Edward L. Sughrue , Marvin J. Johnson , Glen W. Dodwell , Larry E. Reed , Joseph E. Bares , Jason J. Gislason , Robert W. Morton , James L. Malandra
IPC分类号： C10L1/16
CPC分类号： B01J20/106 , B01J20/02 , B01J20/0203 , B01J20/06 , B01J20/08 , B01J20/103 , B01J2220/42 , C10G25/003 , C10G2300/202 , C10G2300/207 , C10G2300/305 , C10G2400/02 , C10G2400/04 , C10L1/06 , C10L1/08
摘要： Attrition resistant, sorbent compositions for the removal of elemental sulfur and sulfur compounds, such as hydrogen sulfide and organic sulfides, from cracked-gasoline and diesel fuels are prepared by the impregnation of a sorbent support comprising zinc oxide, expanded perlite, and alumina with a promoter such as nickel, nickel oxide or a precursor of nickel oxide followed by reduction of the valence of the promoter metal in the resulting promoter metal sorbent support composition. Also disclosed is a composition comprising desulfurized, cracked-gasoline wherein the desulfurized cracked-gasoline comprises less than about 1 ppmw thiol compounds and less than about 1 ppmw tetrahydrothiophene compounds.
摘要翻译： 通过将包含氧化锌，膨胀珍珠岩和氧化铝的吸附剂载体浸渍在一起，可以制备用于从裂化汽油和柴油燃料中去除元素硫和硫化合物如硫化氢和有机硫化物的吸附剂组合物 促进剂如镍，氧化镍或氧化镍的前体，随后在所得助催化剂金属吸附剂载体组合物中降低助催化剂金属的价态。 还公开了包含脱硫的裂化汽油的组合物，其中脱硫裂化汽油包含小于约1ppmw的硫醇化合物和小于约1ppmw的四氢噻吩化合物。
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3.发明授权Process for selective oxidation of carbon monoxide in a hydrogen containing stream 有权在含氢气流中选择性氧化一氧化碳的方法公开(公告)号：US07514057B2
公开(公告)日：2009-04-07
申请号：US12195105
申请日：2008-08-20
申请人： M. Bruce Welch , Roland Schmidt , Jianhua Yao , Glenn W. Dodwell , Robert W. Morton , Jason J. Gislason , James B. Kimble , David E. Simon , Marvin M. Johnson
发明人： M. Bruce Welch , Roland Schmidt , Jianhua Yao , Glenn W. Dodwell , Robert W. Morton , Jason J. Gislason , James B. Kimble , David E. Simon , Marvin M. Johnson
CPC分类号： B01J37/0018 , B01J21/04 , B01J23/8906 , B01J37/0203 , B01J37/0205 , B01J37/20 , C01B3/583 , C01B2203/044 , C01B2203/047 , H01M2008/1095
摘要： A method of making a composition, said method comprising, spraying a substance comprising platinum and iron into or onto an alumina-containing compound is disclosed. The resulting composition can then be used in a process for oxidizing carbon monoxide with free oxygen.
摘要翻译： 公开了一种制备组合物的方法，所述方法包括将包含铂和铁的物质喷涂到含氧化铝的化合物中或其上。 所得组合物然后可以用于用游离氧氧化一氧化碳的方法。
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4.发明授权Process for selective oxidation of carbon monoxide in a hydrogen containing stream 有权在含氢气流中选择性氧化一氧化碳的方法公开(公告)号：US07439206B2
公开(公告)日：2008-10-21
申请号：US11458149
申请日：2006-07-18
申请人： M. Bruce Welch , Roland Schmidt , Jianhua Yao , Glenn W. Dodwell , Robert W. Morton , Jason J. Gislason , James B. Kimble , David E. Simon , Marvin M. Johnson
发明人： M. Bruce Welch , Roland Schmidt , Jianhua Yao , Glenn W. Dodwell , Robert W. Morton , Jason J. Gislason , James B. Kimble , David E. Simon , Marvin M. Johnson
IPC分类号： B01J27/02 , B01J27/045 , B01J27/049
CPC分类号： B01J37/0018 , B01J21/04 , B01J23/8906 , B01J37/0203 , B01J37/0205 , B01J37/20 , C01B3/583 , C01B2203/044 , C01B2203/047 , H01M2008/1095
摘要： A method of making a composition, said method comprising, spraying a substance comprising platinum and iron into or onto an alumina-containing compound is disclosed. The resulting composition can then be used in a process for oxidizing carbon monoxide with free oxygen.
摘要翻译： 公开了一种制备组合物的方法，所述方法包括将包含铂和铁的物质喷涂到含氧化铝的化合物中或其上。 所得组合物然后可以用于用游离氧氧化一氧化碳的方法。
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公开(公告)号：US20080019895A1
公开(公告)日：2008-01-24
申请号：US11458149
申请日：2006-07-18
申请人： M. Bruce Welch , Roland Schmidt , Jianhua Yao , Glenn W. Dodwell , Robert W. Morton , Jason J. Gislason , James B. Kimble , David E. Simon , Marvin M. Johnson
发明人： M. Bruce Welch , Roland Schmidt , Jianhua Yao , Glenn W. Dodwell , Robert W. Morton , Jason J. Gislason , James B. Kimble , David E. Simon , Marvin M. Johnson
IPC分类号： B01J27/02
CPC分类号： B01J37/0018 , B01J21/04 , B01J23/8906 , B01J37/0203 , B01J37/0205 , B01J37/20 , C01B3/583 , C01B2203/044 , C01B2203/047 , H01M2008/1095
摘要： A method of making a composition, said method comprising, spraying a substance comprising platinum and iron into or onto an alumina-containing compound is disclosed. The resulting composition can then be used in a process for oxidizing carbon monoxide with free oxygen.
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公开(公告)号：US06649555B2
公开(公告)日：2003-11-18
申请号：US10025344
申请日：2001-12-19
IPC分类号： B01J3810
CPC分类号： B01J20/3458 , B01J20/06 , B01J20/3433 , C10G25/003 , C10G25/12 , Y10S502/514 , Y10S502/517
摘要： A deactivated sorbent composition is reactivated by contacting the deactivated sorbent with a reducing stream under activation conditions sufficient to reduce the amount of sulfates associated with the sorbent composition.
摘要翻译： 通过在足以减少与吸附剂组合物相关的硫酸盐的量的活化条件下使失活的吸附剂与还原物流接触来使活化的吸附剂组合物再活化。
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公开(公告)号：US06878669B2
公开(公告)日：2005-04-12
申请号：US10329236
申请日：2002-12-23
CPC分类号： B01J20/3234 , B01J20/0244 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/106 , B01J20/3078 , C10G25/003
摘要： The attrition resistance of sorbent compositions are enhanced by acid-treating the perlite component of the sorbent. The efficiency of making a promoter metal-containing sorbent composition is enhanced using a novel method for incorporating the promoter metal into the sorbent.
摘要翻译： 吸附剂组合物的耐磨性通过酸处理吸附剂的珍珠岩组分得到增强。 使用将助催化剂金属掺入吸附剂的新方法，提高了制备含助催化剂金属的吸附剂组合物的效率。
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公开(公告)号：US06864215B2
公开(公告)日：2005-03-08
申请号：US10072209
申请日：2002-02-06
IPC分类号： B01J20/06 , B01J20/02 , B01J20/08 , B01J20/10 , B01J20/16 , B01J20/30 , B01J23/80 , C10G25/00 , C10G29/04 , C10G29/16 , C10L1/08 , B01J20/00
CPC分类号： B01J20/06 , B01J20/02 , B01J20/08 , B01J20/103 , B01J20/106 , B01J20/28019 , B01J20/28042 , B01J20/3021 , B01J20/3204 , B01J20/3236 , B01J23/06 , B01J23/16 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/50 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/80 , B01J27/1853 , B01J35/023 , B01J35/026 , B01J37/0009 , B01J37/0045 , B01J37/0201 , B01J37/18 , B01J2220/42 , C10G25/003 , C10G2300/104 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/4093 , C10G2300/703 , C10G2400/02 , C10G2400/04 , Y10S502/514 , Y10S502/517
摘要： Attrition resistant, sorbent compositions for the removal of elemental sulfur and sulfur compounds, such as hydrogen sulfide and organic sulfides, from cracked-gasoline and diesel fuels are prepared by the impregnation of a sorbent support comprising zinc oxide, expanded perlite, and alumina with a promoter such as nickel, nickel oxide or a precursor of nickel oxide followed by reduction of the valence of the promoter metal in the resulting promoter metal sorbent support composition.
摘要翻译： 通过将包含氧化锌，膨胀珍珠岩和氧化铝的吸附剂载体浸渍在包含氧化锌，膨胀珍珠岩和氧化铝的吸附剂载体上来制备用于从裂化汽油和柴油燃料中除去元素硫和硫化合物如硫化氢和有机硫化物的吸附剂组合物 促进剂如镍，氧化镍或氧化镍的前体，随后在所得助催化剂金属吸附剂载体组合物中降低助催化剂金属的价态。
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公开(公告)号：US06635795B2
公开(公告)日：2003-10-21
申请号：US10025343
申请日：2001-12-19
IPC分类号： C10G2904
CPC分类号： C10G25/12 , B01J20/06 , B01J20/3433 , B01J20/3458 , C10G25/003
摘要： While contacting under regeneration conditions an oxygen-containing stream with a sorbent comprising a promoter metal and zinc sulfide which has been sulfurized by contact with sulfur-containing hydrocarbons such as cracked-gasolines and diesel fuel, the oxygen partial pressure is controlled in a range of 0.5 to 2.0 psig to minimize sulfation of the sorbent.
摘要翻译： 当在再生条件下接触含氧流与包含助催化剂金属和硫化锌的吸附剂，其通过与含硫烃如裂化汽油和柴油燃料接触而被硫化时，将氧分压控制在 0.5至2.0psig以使吸附剂的硫酸化最小化。
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公开(公告)号：US06544410B1
公开(公告)日：2003-04-08
申请号：US10025345
申请日：2001-12-19
IPC分类号： B01J3804
CPC分类号： C10G25/12 , B01J20/0244 , B01J20/06 , B01J20/08 , B01J20/3433 , B01J20/3458 , C10G25/003
摘要： During the regeneration of a sulfurized sorbent comprising zinc aluminate, a promoter metal and zinc sulfide by contact with an oxygen-containing stream to convert at least a portion of said zinc sulfide to zinc oxide the average sulfur dioxide partial pressure in the regeneration zone is controlled within the range of from about 0.1 to about 10 psig to minimize sulfation of the sorbent.
摘要翻译： 在通过与含氧流接触以将至少一部分所述硫化锌转化为氧化锌的含铝酸锌，助催化剂金属和硫化锌的硫化吸附剂的再生期间，控制再生区中的平均二氧化硫分压 在约0.1至约10psig的范围内，以使吸附剂的硫酸化最小化。
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