摘要:
Described is a metal oxide support material nanoscaled iron-platinum group metal particles having a particle size in the range of 0.5 to 10 nm, wherein at least 70% of all nanoscaled iron-platinum group metal particles are located on an outside surface layer of the metal oxide support material, and wherein the outside surface layer has an average volume of less than 50% based on the total volume of the metal oxide support material.Additionally, described is a process for the preparation of such metal oxide support material comprising nanoscaled iron-platinum group metal particles. Furthermore, described is the use of metal oxides containing nanoscaled iron-platinum group metal particles as catalysts, for example as a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine.
摘要:
The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bQ1-cM2cPd-eM3eOx (l), wherein Q has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: Q: Fe, Mn, Co, Ni, M1: Na, K, Rb and/or Cs, M2: Mg, Al, Ca, Ti, Co, Ni, Cr, V, Fe, Mn, wherein Q and M2 are different from each other, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one Q-comprising compound, in which Q has at least partially an oxidation state higher than +2, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C. and at an autogeneous pressure to reduce Q to oxidation state +2 and to obtain a compound of general formula (I).
摘要:
The present invention relates to a process for preparing lithium vanadium oxides and also a process for producing mixtures of a lithium vanadium oxide and at least one electrically conductive material. Furthermore, the invention relates to the use of lithium vanadium oxides or of mixtures of a lithium vanadium oxide and at least one electrically conductive material for producing cathodes for batteries and in electrochemical cells. In addition, the invention relates to cathodes which comprise a lithium vanadium oxide or a mixture of a lithium vanadium oxide and at least one electrically conductive material.
摘要:
In a device and a method for extracting non-magnetic ores from a pulp comprising non-magnetic ore particles and having a solid fraction of at least 30 mass percent, the pulp flows continuously through a reactor in the direction of flow and magnetic or magnetizable magnet particles that form ore magnetic particle agglomerations with the non-magnetic ore particles are added to said pulp. The ore magnetic particle agglomerations are moved by a magnetic field into an accumulation range of the reactor, and are then discharged out of reactor range and separated into ore and magnetic particles. In a device and a method, the separated magnetic particles are treated, in particular hydrophobized, such that during a new interaction with non-magnetic ore particles, new ore magnetic particle agglomerations are formed. Accordingly, a high yield of ores can be obtained and the mine can be operated in an economical and environmentally friendly manner.
摘要:
The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bV2-cM2c(PO4)x (I) with M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5-4.5, b: 0-0.6, c: 0-1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a−b is >0, by providing an essentially aqueous mixture comprising at least one lithium-comprising compound, at least one vanadium-comprising compound in which vanadium has the oxidation state +5 and/or +4, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, drying and calcining.
摘要:
The present invention relates to a process for separating at least one hydrophobic material from a mixture comprising this at least one hydrophobic material and at least one hydrophilic material, which comprises the steps: (A) preparation of a slurry or dispersion of the mixture to be treated in at least one suitable dispersion medium, (B) contacting of the slurry or dispersion from step (A) with at least one solid, hydrophobic surface to bind the at least one hydrophobic material to be separated off to this, (C) removal of the at least one solid, hydrophobic surface to which the at least one hydrophobic material is bound from step (B) from the slurry or dispersion in which the at least one hydrophilic material is comprised and (D) separation of the at least one hydrophobic material from the solid, hydrophobic surface.
摘要:
A novel polynary vanadyl pyrophosphate of the general formula I (VO)a(M1-bVb)2(P2O7)c is described, in which M is one or more metals selected from Ti, Zr, Hf, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, B, Al, Ga and In, a is from 0.5 to 1.5, b is from 0 to 0.9, c is from 1.5 to 2.5, having a crystal structure whose powder X-ray diffractogram is characterized by defined reflections. A preferred representative is (VO)Fe2(P2O7)2. The vanadyl pyrophosphates are suitable as gas phase oxidation catalysts, for example for preparing maleic anhydride from a hydrocarbon having at least four carbon atoms.
摘要翻译:描述了通式I(VO)a(M1-bVb)2(P2O7)c的新型多价氧钒焦磷酸盐,其中M是选自Ti,Zr,Hf,Cr,Fe,Co,Ni中的一种或多种金属 ,Ru,Rh,Pd,Cu,Zn,B,Al,Ga和In,a为0.5〜1.5,b为0〜0.9,c为1.5〜2.5,具有粉末X射线衍射图 其特征在于定义的反射。 优选的代表是(VO)Fe 2(P 2 O 7)2。 焦磷酸氧钒可适用作气相氧化催化剂,例如从具有至少四个碳原子的烃制备马来酸酐。
摘要:
A novel polynary metal oxide phosphate of the general formula I MaV4-aOb(PO4)c is described, in which M is one or more metals selected from Ti, Zr, Hf, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, B, Al, Ga and In, a is from 0 to 2.0, b is from 2.0 to 4.0, c is from 2.0 to 4.0, having a crystal structure whose powder X-ray diffractogram is characterized by defined reflections. Preferred representatives are V4O3(PO4)3, CrV3O3(PO4)3, FeV3O3(PO4)3 and TiV3O3(PO4)3. The metal oxide phosphates are suitable as gas phase oxidation catalysts, for example for preparing maleic anhydride from a hydrocarbon having at least four carbon atoms.
摘要:
A multimetal oxide of the formula I Aga−bMbV2Ox*c H2O, I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
摘要:
A process is proposed for preparing polymers filled with nanoscale metal oxides and comprises the following steps: a) preparing a nanosuspension of one or more crystalline metal oxides, hydroxides or oxide hydroxides by heating a suspension of one or more compounds comprising the corresponding metals in a first polymerizable compound to a temperature greater than the boiling point of water under process pressure and less than the boiling temperature of the first polymerizable compound and also less than the temperature at which the polymerization of the first polymerizable compound commences, in the presence of water in an amount corresponding to 1 to 10 oxygen atoms per metal atom of the compound or compounds comprising the corresponding metals, and b) polymerizing the first polymerizable compound under pressure and temperature conditions typical for the first polymerizable compound.